GB1117755A - Process for the preparation of sulphuric acid solutions of nitrosyl sulphuric acid - Google Patents
Process for the preparation of sulphuric acid solutions of nitrosyl sulphuric acidInfo
- Publication number
- GB1117755A GB1117755A GB5085565A GB5085565A GB1117755A GB 1117755 A GB1117755 A GB 1117755A GB 5085565 A GB5085565 A GB 5085565A GB 5085565 A GB5085565 A GB 5085565A GB 1117755 A GB1117755 A GB 1117755A
- Authority
- GB
- United Kingdom
- Prior art keywords
- sulphuric acid
- sulphuric
- nitrosyl
- acid
- mixture
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 title abstract 7
- 235000011149 sulphuric acid Nutrition 0.000 title abstract 7
- 239000001117 sulphuric acid Substances 0.000 title abstract 7
- VQTGUFBGYOIUFS-UHFFFAOYSA-N nitrosylsulfuric acid Chemical compound OS(=O)(=O)ON=O VQTGUFBGYOIUFS-UHFFFAOYSA-N 0.000 title abstract 5
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 abstract 5
- 239000000203 mixture Substances 0.000 abstract 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 4
- 239000003999 initiator Substances 0.000 abstract 3
- 229910017604 nitric acid Inorganic materials 0.000 abstract 2
- 235000010269 sulphur dioxide Nutrition 0.000 abstract 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 abstract 1
- IOVCWXUNBOPUCH-UHFFFAOYSA-N Nitrous acid Chemical compound ON=O IOVCWXUNBOPUCH-UHFFFAOYSA-N 0.000 abstract 1
- OMBRFUXPXNIUCZ-UHFFFAOYSA-N dioxidonitrogen(1+) Chemical compound O=[N+]=O OMBRFUXPXNIUCZ-UHFFFAOYSA-N 0.000 abstract 1
- 229910001882 dioxygen Inorganic materials 0.000 abstract 1
- 238000011065 in-situ storage Methods 0.000 abstract 1
- 229910052500 inorganic mineral Inorganic materials 0.000 abstract 1
- 239000011707 mineral Chemical class 0.000 abstract 1
- 150000002895 organic esters Chemical class 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B21/00—Nitrogen; Compounds thereof
- C01B21/082—Compounds containing nitrogen and non-metals and optionally metals
- C01B21/086—Compounds containing nitrogen and non-metals and optionally metals containing one or more sulfur atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/16—Esters of thiophosphoric acids or thiophosphorous acids
- C07F9/165—Esters of thiophosphoric acids
- C07F9/18—Esters of thiophosphoric acids with hydroxyaryl compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Inorganic Chemistry (AREA)
- Cleaning Or Drying Semiconductors (AREA)
Abstract
A sulphuric acid solution of nitrosyl-sulphuric acid is produced by reacting preferably at -15 DEG to + 70 DEG C., in stoichiometric quantities, sulphurous anhydride with nitric acid, the reaction being conducted in a medium of sulphuric acid and in the presence of nitrosyl sulphuric acid and water as initiators, the initial quantity of water being such that the weight of sulphuric acid with respect to the sum of the weights of sulphuric acid and water comprises 70-97 per cent. The initiator nitrosyl sulphuric acid may be formed in situ by the addition of NO2, a mixture of NO2 and NO or a mixture of NO and molecular oxygen to a mixture of sulphuric and nitric acids. Alternatively the initiator may be formed by the addition to a mixture of sulphuric and nitric acids, mineral salts or organic esters of nitrous acid or sulphurous anhydride in the presence of air. In place of mixing sulphuric and nitric acids, a mixture containing the reaction components: sulphuric acid, nitric acid, water and nitrosyl sulphuric acid, may be obtained by the action of nitrogen peroxide on excess sulphuric acid.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR996752A FR1431704A (en) | 1964-11-30 | 1964-11-30 | Manufacturing process of nitrosyl sulfuric acid |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1117755A true GB1117755A (en) | 1968-06-26 |
Family
ID=8843637
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB5085565A Expired GB1117755A (en) | 1964-11-30 | 1965-11-30 | Process for the preparation of sulphuric acid solutions of nitrosyl sulphuric acid |
Country Status (7)
| Country | Link |
|---|---|
| BE (1) | BE672508A (en) |
| CH (1) | CH442252A (en) |
| DE (1) | DE1567734A1 (en) |
| FR (1) | FR1431704A (en) |
| GB (1) | GB1117755A (en) |
| LU (1) | LU49890A1 (en) |
| NL (1) | NL6515527A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5955050A (en) * | 1994-10-25 | 1999-09-21 | Marsulex Inc. | Nox destruction in sulphuric acid |
-
1964
- 1964-11-30 FR FR996752A patent/FR1431704A/en not_active Expired
-
1965
- 1965-11-18 BE BE672508D patent/BE672508A/xx unknown
- 1965-11-22 LU LU49890A patent/LU49890A1/xx unknown
- 1965-11-23 DE DE19651567734 patent/DE1567734A1/en active Pending
- 1965-11-24 CH CH1614765A patent/CH442252A/en unknown
- 1965-11-30 GB GB5085565A patent/GB1117755A/en not_active Expired
- 1965-11-30 NL NL6515527A patent/NL6515527A/xx unknown
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5955050A (en) * | 1994-10-25 | 1999-09-21 | Marsulex Inc. | Nox destruction in sulphuric acid |
Also Published As
| Publication number | Publication date |
|---|---|
| DE1567734A1 (en) | 1970-09-17 |
| FR1431704A (en) | 1966-03-18 |
| CH442252A (en) | 1967-08-31 |
| LU49890A1 (en) | 1966-01-22 |
| BE672508A (en) | 1966-03-16 |
| NL6515527A (en) | 1966-05-31 |
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