GB1113638A - Process for modification of cellulose - Google Patents
Process for modification of celluloseInfo
- Publication number
- GB1113638A GB1113638A GB4736964A GB4736964A GB1113638A GB 1113638 A GB1113638 A GB 1113638A GB 4736964 A GB4736964 A GB 4736964A GB 4736964 A GB4736964 A GB 4736964A GB 1113638 A GB1113638 A GB 1113638A
- Authority
- GB
- United Kingdom
- Prior art keywords
- dihydro
- pyran
- acid
- carbonamide
- mixture
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/22—Effecting variation of dye affinity on textile material by chemical means that react with the fibre
- D06P5/225—Aminalization of cellulose; introducing aminogroups into cellulose
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/12—Aldehydes; Ketones
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/39—Aldehyde resins; Ketone resins; Polyacetals
- D06M15/423—Amino-aldehyde resins
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Phenolic Resins Or Amino Resins (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
N - Methylol - 3,4 - dihydro - 2H - pyran - 2 - carbonamide carbonamide is prepared by heating a mixture of 3,4 - dihydro - 2H - pyran - 2 - carbonamide, paraformaldehyde and solid sodium hydroxide to 100-115 DEG C. until molten and then stirring and heating the mixture at 85-90 DEG C. for 4 hours and then cooling it, the resulting product being crystallized from methanol, recrystallized from acetone and further recrystallized from methylated spirits. 2 - N - Stearoylaminomethyl - 3,4 - dihydro-2H-pyran is prepared by heating together a mixture of a solution of stearoyl chloride in benzene and a mixture of 2-aminomethyl-3,4-dihydro-2H-pyran and sodium bicarbonate in benzene under reflux, cooling, filtering, distilling the benzene off the filtrate under vacuum and crystallizing the resulting residue from acetone.ALSO:Cellulosic textile materials and paper may be creaseproofed, waterproofed and given a modified handle, and an affinity for acid dyestuffs by reacting them in the presence as catalyst of a acid or substance capable of generating an acid under the reaction conditions used, with a compound containing at least one 3,4-dihydro - 2H - pyranyl radical. The compound may be 3,4 - dihydro - 2H - pyran itself having the formula <FORM:1113638/D1-D2/1> 2 - aminomethyl - 3,4 - dihydro - 2H - pyran, 2 - NN - dimethylaminomethyl - 3,4 - dihydro - 2H - pyran, 2 - N - stearoyl aminomethyl - 3,4 - dihydro - 2H - pyran, the neopentyl bisester of 3,4 - dihydro - 2H - pyran - 2 - carboxylic acid, benzyl tris - (3,4 dihydro - 2H - pyran - 2 - carboxyethyl) ammonium chloride, quaternary salts of the triethanolamine tris-ester of 3,4 - dihydro - 2H - pyran - 2 - carboxylic acid, an amide derived from a 2 - amino methyl - 3, 4 - dihydro - 2H - pyran and a 3,4 - dihydro - 2H - pyran - 2 - carboxylic acid, or N - methylol - 3,4 - dihydro - 2H - pyran - 2 - carbonamide obtained by the reaction of formaldehyde on 3,4 - dihydro - 2H - pyran - 2 - carbonamide. The material may be impregnated with a solution or dispersion of the 3,4 - dihydro - 2H - pyranyl compound and catalyst in for example water, dried at a temperature not exceeding 120 DEG C and baked at a temperature of 120 DEG -200 DEG C for from 10 seconds to 30 minutes suitable catalysts being ammonium dihydrogen phosphate or ammonium thiocyanate, butanolamine hydrochloride, tartaric, oxalic or maleic acid, zinc chloride or nitrate or magnesium chloride. Alternatively the material may be immersed in a solution or dispersion of the 3,4 - dihydro - 2H - pyranyl compound and a strong acid, e.g. nitric, hydrochloric, phosphoric, sulphuric or trichloro acetic acid, at the ordinary temperature until reaction has taken place or the material may be padded with the solution or dispersion, batched and allowed to stand until reaction has taken place care being taken to ensure that the material does not dry out during this period. The treatment may be combined with the application of a nitrogen resin precondensate, e.g. methylol derivatives of urea, ethylene urea, thiourea, dicyandiamide, amines, amides, carbamates, aminotriazines, urons, ureins, ureides, imidazolidones, pyrimidones and triazones and lower alkyl ethers thereof, or with the application of an aldehyde, e.g. formaldehyde, glyoxal, succindialdehyde or hydroxyadiphaldehyde, Textile materials made from cotton, linen, viscose rayon including polynosic rayons in the form of fibres, rovings, yarns or woven, non-woven or knitted fabrics may be treated. (D1B of Examples 1 and 2).
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB4736964A GB1113638A (en) | 1964-11-20 | 1964-11-20 | Process for modification of cellulose |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB4736964A GB1113638A (en) | 1964-11-20 | 1964-11-20 | Process for modification of cellulose |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1113638A true GB1113638A (en) | 1968-05-15 |
Family
ID=10444713
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB4736964A Expired GB1113638A (en) | 1964-11-20 | 1964-11-20 | Process for modification of cellulose |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB1113638A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2008145656A2 (en) * | 2007-05-30 | 2008-12-04 | Basf Se | Products, the use thereof in the treatment of textiles, and the production thereof |
CN115073264A (en) * | 2022-08-23 | 2022-09-20 | 山东新和成药业有限公司 | Method for pretreating methyl pyran solution in leaf alcohol synthesis reaction and application thereof |
-
1964
- 1964-11-20 GB GB4736964A patent/GB1113638A/en not_active Expired
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2008145656A2 (en) * | 2007-05-30 | 2008-12-04 | Basf Se | Products, the use thereof in the treatment of textiles, and the production thereof |
WO2008145656A3 (en) * | 2007-05-30 | 2009-03-19 | Basf Se | Products, the use thereof in the treatment of textiles, and the production thereof |
CN115073264A (en) * | 2022-08-23 | 2022-09-20 | 山东新和成药业有限公司 | Method for pretreating methyl pyran solution in leaf alcohol synthesis reaction and application thereof |
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