GB1112439A - Aminoalkyl esters of ª‡,ª‰-unsaturated acids and method of preparing these compounds - Google Patents

Aminoalkyl esters of ª‡,ª‰-unsaturated acids and method of preparing these compounds

Info

Publication number
GB1112439A
GB1112439A GB161566A GB161566A GB1112439A GB 1112439 A GB1112439 A GB 1112439A GB 161566 A GB161566 A GB 161566A GB 161566 A GB161566 A GB 161566A GB 1112439 A GB1112439 A GB 1112439A
Authority
GB
United Kingdom
Prior art keywords
alkyl
alkenyl
specified
compounds
group
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB161566A
Inventor
Mikhail Alexeevich Korshunov
Frizian Nikolaevich Bodnariuk
Anatoly Mikhailovich Kut
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
NII MONOMEROV DLIA SINT KAUCHU
Original Assignee
NII MONOMEROV DLIA SINT KAUCHU
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by NII MONOMEROV DLIA SINT KAUCHU filed Critical NII MONOMEROV DLIA SINT KAUCHU
Priority to GB161566A priority Critical patent/GB1112439A/en
Publication of GB1112439A publication Critical patent/GB1112439A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
    • C07D211/04—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D211/06—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members
    • C07D211/08—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members with hydrocarbon or substituted hydrocarbon radicals directly attached to ring carbon atoms
    • C07D211/18—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members with hydrocarbon or substituted hydrocarbon radicals directly attached to ring carbon atoms with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D211/20—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members with hydrocarbon or substituted hydrocarbon radicals directly attached to ring carbon atoms with substituted hydrocarbon radicals attached to ring carbon atoms with hydrocarbon radicals, substituted by singly bound oxygen or sulphur atoms
    • C07D211/22—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members with hydrocarbon or substituted hydrocarbon radicals directly attached to ring carbon atoms with substituted hydrocarbon radicals attached to ring carbon atoms with hydrocarbon radicals, substituted by singly bound oxygen or sulphur atoms by oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/10—Esters
    • C08F20/34—Esters containing nitrogen, e.g. N,N-dimethylaminoethyl (meth)acrylate

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Acrylic polymers are obtained by free radical polymerization at elevated temperatures of esters of the formula <FORM:1112439/C3/1> where R is hydrogen or a methyl group, n is 2, 3 or 4 and A is <FORM:1112439/C3/2> or <FORM:1112439/C3/3> where R1 is an alkyl or alkenyl group, R2 is an alkenyl group and R3 and R4 are alkyl groups. A suitable catalyst is bis - (azobutyronitrile). Those monomers in which R2 and/or R1 are alkenyl groups can be polymerized in a first stage under mild conditions to polymerize the acrylyl bond and in a subsequent stage under more severe conditions to obtain a three-dimensional polymer through the alkenyl groups. A number of monomers are specified.ALSO:The invention comprises aminoalkyl esters of the formula <FORM:1112439/C2/1> where R is hydrogen or methyl, n is 2, 3 or 4 and A is <FORM:1112439/C2/2> where R1 is alkyl or alkenyl, R2 is alkenyl, R3 is alkyl and R4 is an alkyl group. The compounds are made by heating a C1- 4 alkyl ester of acrylic or methacrylic acid with an aminoalcohol HO-CnH2n-A in the presence of a transesterification catalyst and a polymerization inhibitor. Specified catalysts are the alkali metals and the alcoholates of the alkali metals, titanium and aluminium. Suitable inhibitors are phenols, alkyl phenols, polyphenols, naphthols, aromatic amines and aminophenols. Specified reaction temperatures are in the range 60-160 DEG C. Numerous compounds are specified.
GB161566A 1966-01-13 1966-01-13 Aminoalkyl esters of ª‡,ª‰-unsaturated acids and method of preparing these compounds Expired GB1112439A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB161566A GB1112439A (en) 1966-01-13 1966-01-13 Aminoalkyl esters of ª‡,ª‰-unsaturated acids and method of preparing these compounds

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB161566A GB1112439A (en) 1966-01-13 1966-01-13 Aminoalkyl esters of ª‡,ª‰-unsaturated acids and method of preparing these compounds

Publications (1)

Publication Number Publication Date
GB1112439A true GB1112439A (en) 1968-05-08

Family

ID=9725014

Family Applications (1)

Application Number Title Priority Date Filing Date
GB161566A Expired GB1112439A (en) 1966-01-13 1966-01-13 Aminoalkyl esters of ª‡,ª‰-unsaturated acids and method of preparing these compounds

Country Status (1)

Country Link
GB (1) GB1112439A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0000496A1 (en) * 1977-07-19 1979-02-07 Ciba-Geigy Ag Acrylic polymers substituted by N-heterocyclic rings and their use as light protection agents
EP0010518A1 (en) * 1978-10-13 1980-04-30 Ciba-Geigy Ag Acrylic copolymers bearing N-heterocyclic side rings, their use, and process for their preparation

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0000496A1 (en) * 1977-07-19 1979-02-07 Ciba-Geigy Ag Acrylic polymers substituted by N-heterocyclic rings and their use as light protection agents
US4210612A (en) 1977-07-19 1980-07-01 Ciba-Geigy Corporation Novel polymeric N-heterocyclic compounds
EP0010518A1 (en) * 1978-10-13 1980-04-30 Ciba-Geigy Ag Acrylic copolymers bearing N-heterocyclic side rings, their use, and process for their preparation
US4276401A (en) 1978-10-13 1981-06-30 Ciba-Geigy Corporation N-Heterocyclic substituted acryloyl polymeric compounds

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