GB1111168A - Process for the production of dispersions of vinyl esters of organic acids and hexene-1 - Google Patents
Process for the production of dispersions of vinyl esters of organic acids and hexene-1Info
- Publication number
- GB1111168A GB1111168A GB1685466A GB1685466A GB1111168A GB 1111168 A GB1111168 A GB 1111168A GB 1685466 A GB1685466 A GB 1685466A GB 1685466 A GB1685466 A GB 1685466A GB 1111168 A GB1111168 A GB 1111168A
- Authority
- GB
- United Kingdom
- Prior art keywords
- hexene
- dispersions
- production
- organic acids
- vinyl esters
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 title abstract 4
- 229920001567 vinyl ester resin Polymers 0.000 title abstract 3
- 239000006185 dispersion Substances 0.000 title abstract 2
- 150000007524 organic acids Chemical class 0.000 title abstract 2
- 235000005985 organic acids Nutrition 0.000 title 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 title 1
- IGFHQQFPSIBGKE-UHFFFAOYSA-N 4-nonylphenol Chemical compound CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 2
- FRQQKWGDKVGLFI-UHFFFAOYSA-N 2-methylundecane-2-thiol Chemical compound CCCCCCCCCC(C)(C)S FRQQKWGDKVGLFI-UHFFFAOYSA-N 0.000 abstract 1
- 239000004160 Ammonium persulphate Substances 0.000 abstract 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 abstract 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 abstract 1
- 239000004141 Sodium laurylsulphate Substances 0.000 abstract 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 abstract 1
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 abstract 1
- 235000019395 ammonium persulphate Nutrition 0.000 abstract 1
- 239000000084 colloidal system Substances 0.000 abstract 1
- 229920001577 copolymer Polymers 0.000 abstract 1
- 239000012153 distilled water Substances 0.000 abstract 1
- 150000002148 esters Chemical class 0.000 abstract 1
- 239000011953 free-radical catalyst Substances 0.000 abstract 1
- 150000002762 monocarboxylic acid derivatives Chemical class 0.000 abstract 1
- 229910000028 potassium bicarbonate Inorganic materials 0.000 abstract 1
- 235000015497 potassium bicarbonate Nutrition 0.000 abstract 1
- 239000011736 potassium bicarbonate Substances 0.000 abstract 1
- TYJJADVDDVDEDZ-UHFFFAOYSA-M potassium hydrogencarbonate Chemical compound [K+].OC([O-])=O TYJJADVDDVDEDZ-UHFFFAOYSA-M 0.000 abstract 1
- 230000001681 protective effect Effects 0.000 abstract 1
- 229920006395 saturated elastomer Polymers 0.000 abstract 1
- HRZFUMHJMZEROT-UHFFFAOYSA-L sodium disulfite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])(=O)=O HRZFUMHJMZEROT-UHFFFAOYSA-L 0.000 abstract 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 abstract 1
- 235000010262 sodium metabisulphite Nutrition 0.000 abstract 1
- 239000004296 sodium metabisulphite Substances 0.000 abstract 1
- 239000004094 surface-active agent Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F218/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
- C08F218/02—Esters of monocarboxylic acids
- C08F218/04—Vinyl esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Film forming aqueous dispersions of a copolymer of a vinyl ester of an organic acid are prepared by dispersing in water a vinyl ester of a saturated monocarboxylic acid and hexene-1 and copolymerizing the ester and hexene-1 in the presence of a free radical catalyst and a surface-active agent and/or a protective colloid. In the example are used: vinyl acetate, hexene-1, sodium lauryl sulphate, two ethylene oxide/nonyl phenol condensates, potassium bicarbonate, distilled water, tertiary dodecyl mercaptan, ammonium persulphate and sodium metabisulphite.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB1685466A GB1111168A (en) | 1966-04-18 | 1966-04-18 | Process for the production of dispersions of vinyl esters of organic acids and hexene-1 |
| FR102996A FR1519270A (en) | 1966-04-18 | 1967-04-17 | Process for the production of film-forming dispersions of copolymers of vinyl esters of organic acids |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB1685466A GB1111168A (en) | 1966-04-18 | 1966-04-18 | Process for the production of dispersions of vinyl esters of organic acids and hexene-1 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1111168A true GB1111168A (en) | 1968-04-24 |
Family
ID=10084876
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB1685466A Expired GB1111168A (en) | 1966-04-18 | 1966-04-18 | Process for the production of dispersions of vinyl esters of organic acids and hexene-1 |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB1111168A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2108662A1 (en) | 2008-04-10 | 2009-10-14 | Hexion Specialty Chemicals Research Belgium S.A. | Process of copolymerization in emulsion of 1-Alkenes and vinyl esters with high conversion |
-
1966
- 1966-04-18 GB GB1685466A patent/GB1111168A/en not_active Expired
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2108662A1 (en) | 2008-04-10 | 2009-10-14 | Hexion Specialty Chemicals Research Belgium S.A. | Process of copolymerization in emulsion of 1-Alkenes and vinyl esters with high conversion |
| WO2009124661A1 (en) | 2008-04-10 | 2009-10-15 | Hexion Specialty Chemicals Research Belgium S.A. | Process of polymerization in emulsion of 1-alkenes and vinyl esters with high conversion and their use |
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