Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3176966A
Inventor
Sango Kunichika
Yasumasa Sakakibara
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Chiyoda Corp
Chiyoda Chemical Engineering and Construction Co Ltd
Original Assignee
Chiyoda Corp
Chiyoda Chemical Engineering and Construction Co Ltd
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Filing date
Publication date
Application filed by Chiyoda Corp, Chiyoda Chemical Engineering and Construction Co LtdfiledCriticalChiyoda Corp
Publication of GB1110565ApublicationCriticalpatent/GB1110565A/en
C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
C07C67/38—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates by addition to an unsaturated carbon-to-carbon bond
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Chemical & Material Sciences
(AREA)
Organic Chemistry
(AREA)
Chemical Kinetics & Catalysis
(AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof
(AREA)
Abstract
Methacrylic acid esters are prepared by reacting allene with carbon monoxide and a saturated aliphatic monohydric alcohol, at a temperature from 100 DEG to 250 DEG C. and a pressure in the range from 50 to 100 atmospheres in the presence of nickel carbonyl and water. The alcohol is preferably a C1-C12 alcohol and examples describe the preparation of methyl methacrylate.
GB3176966A1966-07-121966-07-14Preparation of methacrylic esters
ExpiredGB1110565A
(en)
A procedure for the preparation of new derivatives of alcoxi bottom of 3,7-dimetiloctan-1-al (Machine-translation by Google Translate, not legally binding)