GB1109939A - Hydrocracking process - Google Patents
Hydrocracking processInfo
- Publication number
- GB1109939A GB1109939A GB5713366A GB5713366A GB1109939A GB 1109939 A GB1109939 A GB 1109939A GB 5713366 A GB5713366 A GB 5713366A GB 5713366 A GB5713366 A GB 5713366A GB 1109939 A GB1109939 A GB 1109939A
- Authority
- GB
- United Kingdom
- Prior art keywords
- catalyst
- metal
- hydrocarbon fraction
- sulphided
- hydrocracking
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/28—Regeneration or reactivation
- B01J27/30—Regeneration or reactivation of catalysts comprising compounds of sulfur, selenium or tellurium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/90—Regeneration or reactivation
- B01J23/94—Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides of the iron group metals or copper
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
- C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
- C10G47/06—Sulfides
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
- C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
- C10G47/10—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used with catalysts deposited on a carrier
- C10G47/12—Inorganic carriers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Materials Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Catalysts (AREA)
Abstract
A hydrocracking process comprises contacting a hydrocarbon fraction with a hydrocracking catalyst comprising sulphided nickel under hydrocracking conditions until the catalyst suffers loss in activity, discontinuing the feed of the hydrocarbon fraction while continuing the H2 flow at a temperature of at least 700 DEG F. and a pressure between 0 and 1500 p.s.i.g., displacing H2 from the reaction zone with a non-combustible gas, contacting the catalyst with an oxygen-bearing gas to remove carbon deposits by combustion, displacing the oxygen bearing gas from the reaction zone, sulphiding the catalyst and reinstituting the feed of H2 and hydrocarbon fraction. The hydrogenating component of the catalyst preferably comprises sulphided nickel in amount calculated as metal of 2-10% by wt. of the catalyst, and a sulphide of a Group VI metal, e.g. molybdenum or tungsten, in an amount as metal of 2-35% by wt. of the catalyst. The cracking component may consist of silica, alumina, magnesia or mixtures thereof or preferably a crystalline zeolitic alumino silicate containing less than 6% by wt. Na2O. The oxidative regeneration may be carried out at 700-1100 DEG F. and the catalyst sulphided with H2S, CS2 or t-butyl sulphide at 300-700 DEG F.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US51713465A | 1965-12-28 | 1965-12-28 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1109939A true GB1109939A (en) | 1968-04-18 |
Family
ID=24058504
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB5713366A Expired GB1109939A (en) | 1965-12-28 | 1966-12-21 | Hydrocracking process |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB1109939A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2748674A1 (en) * | 1996-05-20 | 1997-11-21 | Pro Catalyse | PROCESS FOR TREATING A CATALYST HAVING AN ACTIVE SULFUR PHASE CONTAMINATED BY A MERCURY COMPOUND |
-
1966
- 1966-12-21 GB GB5713366A patent/GB1109939A/en not_active Expired
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2748674A1 (en) * | 1996-05-20 | 1997-11-21 | Pro Catalyse | PROCESS FOR TREATING A CATALYST HAVING AN ACTIVE SULFUR PHASE CONTAMINATED BY A MERCURY COMPOUND |
WO1997044131A1 (en) * | 1996-05-20 | 1997-11-27 | Procatalyse | Method for regenerating a catalyst with a sulphurus active phase and contaminated by a mercury compound |
US6100210A (en) * | 1996-05-20 | 2000-08-08 | Procatalyse | Method for regenerating a catalyst with a sulphurus active phase and contaminated by a mercury compound |
Also Published As
Publication number | Publication date |
---|---|
DE1545404A1 (en) | 1969-07-10 |
DE1545404B2 (en) | 1975-08-07 |
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