GB1094467A - Catalytic hydrocracking - Google Patents

Catalytic hydrocracking

Info

Publication number
GB1094467A
GB1094467A GB2666/66A GB266666A GB1094467A GB 1094467 A GB1094467 A GB 1094467A GB 2666/66 A GB2666/66 A GB 2666/66A GB 266666 A GB266666 A GB 266666A GB 1094467 A GB1094467 A GB 1094467A
Authority
GB
United Kingdom
Prior art keywords
hydrogenation
hydrogen
component
molybdena
constituent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2666/66A
Inventor
Sylvander Cecil Eastwood
Richard Joseph Kelly
Stephen John Wantuck
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Oil Corp
Original Assignee
Mobil Oil Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mobil Oil Corp filed Critical Mobil Oil Corp
Publication of GB1094467A publication Critical patent/GB1094467A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
    • C10G47/10—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used with catalysts deposited on a carrier
    • C10G47/12—Inorganic carriers
    • C10G47/16—Crystalline alumino-silicate carriers
    • C10G47/20—Crystalline alumino-silicate carriers the catalyst containing other metals or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/061—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing metallic elements added to the zeolite

Landscapes

  • Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)

Abstract

Hydrocarbons may be hydrocracked using a catalyst comprising a physical mixture of particles of a crystalline aluminosilicate component having a sodium content of less than 4% by weight, and optionally carrying a hydrogenation constituent, and a hydrogenation component comprising a major proportion of a porous support and a minor proportion of at least one hydrogenation constituent. Conditions are: temperature between 600 DEG and 950 DEG F.; hydrogen partial pressure in the range 700 to 3000 p.s.i.g.; LHSV of hydrocarbon feed between 0.1 and 10; molar ratio of hydrogen to hydrocarbon feed between 2 and 80. The feedstock may be gas oils, residual stocks, cycle stocks, whole topped crudes, heavy hydrocarbon fractions obtained by destructive hydrogenation of coal, tars, pitches, asphalts. Examples relate to hydrocracking a pretreated 390 DEG F. + gas oil fraction and a 650 DEG - Tar Gas Oil.ALSO:A hydrocracking catalyst comprises a physical mixture of particles of (1) a crystalline aluminosilicate component having a sodium content of less than 4% by weight, and (2) a hydrogenation component comprising a predominant proportion of a porous support and a minor proportion of at least one hydrogenation constituent consisting of a metal of Group VI or VIII or an oxide or sulphide thereof. The crystalline aluminosilicate component (1) may be zeolites X, Y or L, fanjasite or mordenite, and may be cation-exchanged with rare earth hydrogen, hydrogen precursor, calcium, manganese or magnesium ions. It may itself be combined with a hydrogenation constituent, for example Mo, Cr, W, Fe, Co, Ni, Pt, Pd, Os, Ir, Rh, Ru, their oxides or sulphides. The hydrogenation component (2) may comprise sintered metal or glass, asbestos, silicon carbide, pumice, firebrick, diatomaceous earth, activated charcoal, refractory oxides, polyepoxides, polyamines, polyesters, vinyl resins, phenolics, amino resins, melamines, acrylics, alkyd or epoxy resins, inorganic gels, carrying as hydrogenation constituent Mo, Co, Cr, W, Fe, Ni, Pt group metals, their oxides or sulfieds. Components (1) and (2) may be combined in weight ratio from 1:10 to 10:1. Examples relate to catalysts which are mixtures of a cobalt-molybdena on REX crystalline aluminosilicate with silica-promoted cobalt-molybdena an alumina; REX crystalline alumino silicate with cobalt-molybdena on alumina; hydrogen-form aluminosilicate Y with cobalt-molybdena on alumina. The preparation of other components (1) and (2) is described.
GB2666/66A 1965-01-21 1966-01-20 Catalytic hydrocracking Expired GB1094467A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US427133A US3304254A (en) 1965-01-21 1965-01-21 Catalytic hydrocracking with a physical mixture of a crystalline aluminosilicate and a porous support containing a hydrogenation component

Publications (1)

Publication Number Publication Date
GB1094467A true GB1094467A (en) 1967-12-13

Family

ID=23693619

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2666/66A Expired GB1094467A (en) 1965-01-21 1966-01-20 Catalytic hydrocracking

Country Status (5)

Country Link
US (1) US3304254A (en)
DE (1) DE1542440B2 (en)
FR (1) FR1482865A (en)
GB (1) GB1094467A (en)
NL (1) NL6600849A (en)

Families Citing this family (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3406123A (en) * 1965-09-15 1968-10-15 Texaco Inc Catalysts and their method of preparation
US3395094A (en) * 1966-05-04 1968-07-30 Mobil Oil Corp Shape selective naphtha processing
US3432568A (en) * 1966-06-20 1969-03-11 Mobil Oil Corp Upgrading of hydrocarbons in the presence of a mixed alumino-silicate and metal catalyst
US3617507A (en) * 1968-02-17 1971-11-02 Basf Ag Process for hydrocracking heavy hydrocarbons
US3620964A (en) * 1968-07-09 1971-11-16 Mobil Oil Corp Hydrocracking catalyst composition, method for making the same and hydrocracking in the presence thereof
DE2033751C3 (en) * 1968-08-02 1983-03-17 Chevron Research Co., 94105 San Francisco, Calif. Catalyst for treating hydrocarbons with hydrogen and using this catalyst
US3617509A (en) * 1969-07-07 1971-11-02 Standard Oil Co Catalytic composition, method of preparing same, and hydrocarbon-conversion process employing same
US3720601A (en) * 1969-07-09 1973-03-13 Mobil Oil Corp Hydrocracking process
US3875081A (en) * 1969-10-24 1975-04-01 Union Oil Co Hydrocarbon conversion catalyst
BE758640R (en) * 1970-01-02 1971-04-16 Standard Oil Co PROCESS FOR REFINING THE
US3716475A (en) * 1970-01-30 1973-02-13 Chevron Res Hydrotreating catalyst comprising an interstratified crystalline clay-type aluminosilicate component and a crystalline zeolitic molecular sieve component and process using said catalyst
US3963644A (en) * 1970-10-26 1976-06-15 Union Oil Company Of California Conversion catalysts
US3860533A (en) * 1971-12-17 1975-01-14 Union Oil Co Hydrocracking catalyst
US3865716A (en) * 1973-09-13 1975-02-11 Exxon Research Engineering Co Process for the selective hydrogenation of olefins
US3998721A (en) * 1973-12-26 1976-12-21 Uop Inc. Hydrocarbonaceous black oil conversion process
US3909453A (en) * 1973-12-26 1975-09-30 Universal Oil Prod Co Method of manufacturing a catalyst for the hydro-refining of residual oils
JPS5821890B2 (en) * 1974-12-26 1983-05-04 エクソン リサ−チ アンド エンヂニアリング コムパニ− Olefinno Sentaku Tekisisotenkahou
US4071436A (en) * 1976-03-11 1978-01-31 Chevron Research Company Process for removing sulphur from a gas
US4058484A (en) * 1976-09-09 1977-11-15 Filtrol Corporation Ammonium faujasite zeolites
US4085069A (en) * 1976-08-27 1978-04-18 Filtrol Corporation Hydrothermally stable catalysts containing ammonium faujasite zeolites
CA1122912A (en) * 1977-04-11 1982-05-04 William A. Blanton, Jr. Method for removing pollutants from catalyst regenerator flue gas
CA1124224A (en) * 1977-04-11 1982-05-25 Chevron Research And Technology Company Process for removing pollutants from catalyst regenerator flue gas
US4243557A (en) * 1978-12-26 1981-01-06 Exxon Research & Engineering Co. Sulfur transfer cracking catalyst
US4240899A (en) * 1979-11-05 1980-12-23 Exxon Research & Engineering Co. Sulfur transfer process in catalytic cracking
DE3067678D1 (en) * 1980-06-23 1984-06-07 Exxon Research Engineering Co Process for catalytic hydrogenation of hydrogenatable compounds in a hydrocarbon feedstock, and hydrogenated hydrocarbon products
US4515681A (en) * 1982-09-08 1985-05-07 Exxon Research & Engineering Co. Catalytic dewaxing using collapsed large pore zeolites
US4661239A (en) * 1985-07-02 1987-04-28 Uop Inc. Middle distillate producing hydrocracking process
DK2794092T3 (en) * 2011-12-23 2020-11-16 Shell Int Research PROCEDURE FOR MAKING A HYDRO CRACKING CATALYST
MX352582B (en) 2012-11-06 2017-11-07 Mexicano Inst Petrol Mesoporous composite of molecular meshes for the hydrocracking of heavy crude oil and residues.

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2854401A (en) * 1954-09-13 1958-09-30 Socony Mobil Oil Co Inc Hydrocracking with a physical mixture of catalyst particles containing platinum
US2974099A (en) * 1958-07-24 1961-03-07 Exxon Research Engineering Co Catalytic conversion of heavy naphtha fractions
NL273443A (en) * 1961-03-08

Also Published As

Publication number Publication date
DE1542440A1 (en) 1970-04-16
FR1482865A (en) 1967-06-02
NL6600849A (en) 1966-07-22
US3304254A (en) 1967-02-14
DE1542440B2 (en) 1975-01-30

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