GB1104206A - A process for the production of organosilicon compounds - Google Patents
A process for the production of organosilicon compoundsInfo
- Publication number
- GB1104206A GB1104206A GB895966A GB895966A GB1104206A GB 1104206 A GB1104206 A GB 1104206A GB 895966 A GB895966 A GB 895966A GB 895966 A GB895966 A GB 895966A GB 1104206 A GB1104206 A GB 1104206A
- Authority
- GB
- United Kingdom
- Prior art keywords
- silicon
- ingredient
- heated
- phosphene
- bis
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000003961 organosilicon compounds Chemical class 0.000 title abstract 2
- -1 2-ethylhexyl Chemical group 0.000 abstract 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 abstract 2
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 abstract 2
- 206010034962 Photopsia Diseases 0.000 abstract 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 abstract 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 2
- 239000004615 ingredient Substances 0.000 abstract 2
- 229910000065 phosphene Inorganic materials 0.000 abstract 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 abstract 2
- CLSUSRZJUQMOHH-UHFFFAOYSA-L platinum dichloride Chemical compound Cl[Pt]Cl CLSUSRZJUQMOHH-UHFFFAOYSA-L 0.000 abstract 2
- 229910052710 silicon Inorganic materials 0.000 abstract 2
- OSDWBNJEKMUWAV-UHFFFAOYSA-N Allyl chloride Chemical compound ClCC=C OSDWBNJEKMUWAV-UHFFFAOYSA-N 0.000 abstract 1
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- 125000001931 aliphatic group Chemical group 0.000 abstract 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 abstract 1
- 235000010290 biphenyl Nutrition 0.000 abstract 1
- 239000004305 biphenyl Substances 0.000 abstract 1
- 125000006267 biphenyl group Chemical group 0.000 abstract 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 abstract 1
- KTQYJQFGNYHXMB-UHFFFAOYSA-N dichloro(methyl)silicon Chemical compound C[Si](Cl)Cl KTQYJQFGNYHXMB-UHFFFAOYSA-N 0.000 abstract 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 abstract 1
- VDCSGNNYCFPWFK-UHFFFAOYSA-N diphenylsilane Chemical compound C=1C=CC=CC=1[SiH2]C1=CC=CC=C1 VDCSGNNYCFPWFK-UHFFFAOYSA-N 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 abstract 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 1
- 239000005048 methyldichlorosilane Substances 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 abstract 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 1
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 abstract 1
- 229910052697 platinum Inorganic materials 0.000 abstract 1
- 239000010703 silicon Substances 0.000 abstract 1
- 150000003377 silicon compounds Chemical class 0.000 abstract 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 abstract 1
- 125000003944 tolyl group Chemical group 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/0801—General processes
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
Abstract
Organosilicon compounds containing a carbon-silicon bond are obtained by heating to above 30 DEG C. a mixture of (1) a silicon compound containing at least one silicon bonded hydrogen atom per molecule there being not more than two hydrogen atoms attached to any one silicon atom with (2) a compound containing aliphatically unsaturated carbon atoms in the presence of (3) a platinum complex of the general formula (R3P)2PtCl2, where R is a monovalent hydrocarbon radical free from aliphatic unsaturation. R may be methyl, isopropyl, butyl, 2-ethylhexyl, cyclopentyl or octadecyl; phenyl or diphenyl; tolyl, benzyl or 2-phenyl propyl. In Example 1 methyldichlorosilane, ingredient (2), is heated with methylacrylate, allyl chloride or styrene, ingredient (1), in the presence of cis bis-tributyl phosphene dichloro platinum. In Example 6 diphenyl silane is heated with the compound having <FORM:1104206/C3/1> in the presence of bis - (octyl dimethyl phosphene) dichloroplatinum to give a polymeric gum containing the units shown in <FORM:1104206/C3/2> Many other examples are given.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US43726965A | 1965-03-04 | 1965-03-04 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1104206A true GB1104206A (en) | 1968-02-21 |
Family
ID=23735753
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB895966A Expired GB1104206A (en) | 1965-03-04 | 1966-03-01 | A process for the production of organosilicon compounds |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB1104206A (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0288286A2 (en) * | 1987-04-22 | 1988-10-26 | Tonen Corporation | Process for preparing epoxy group-containing silanes |
| US5206402A (en) * | 1992-09-17 | 1993-04-27 | Dow Corning Corporation | Process for preparation of Ω-alkenylchlorosilanes |
| EP0539065A1 (en) * | 1991-10-21 | 1993-04-28 | Dow Corning Corporation | Platinum catalyzed process for preparation of alpha, omega-silylalkenes and organosiloxane copolymers |
| US5225511A (en) * | 1992-05-26 | 1993-07-06 | Dow Corning Corporation | Organofunctional polysiloxanes and method for preparation |
| US5227448A (en) * | 1992-05-26 | 1993-07-13 | Dow Corning Corporation | Method for preparing organofunctional polysiloxanes |
| US5247045A (en) * | 1992-07-13 | 1993-09-21 | Dow Corning Corporation | Hydrosilylation process for preparation of novel chlorine end-terminated organosiloxanes |
| US5436308A (en) * | 1992-06-03 | 1995-07-25 | Dow Corning Corporation | Cross-linked organofunctional polysiloxanes and method for preparation |
-
1966
- 1966-03-01 GB GB895966A patent/GB1104206A/en not_active Expired
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0288286A2 (en) * | 1987-04-22 | 1988-10-26 | Tonen Corporation | Process for preparing epoxy group-containing silanes |
| EP0288286A3 (en) * | 1987-04-22 | 1990-08-29 | Toa Nenryo Kogyo Kabushiki Kaisha | Process for preparing epoxy group-containing silanes |
| EP0539065A1 (en) * | 1991-10-21 | 1993-04-28 | Dow Corning Corporation | Platinum catalyzed process for preparation of alpha, omega-silylalkenes and organosiloxane copolymers |
| US5225511A (en) * | 1992-05-26 | 1993-07-06 | Dow Corning Corporation | Organofunctional polysiloxanes and method for preparation |
| US5227448A (en) * | 1992-05-26 | 1993-07-13 | Dow Corning Corporation | Method for preparing organofunctional polysiloxanes |
| US5436308A (en) * | 1992-06-03 | 1995-07-25 | Dow Corning Corporation | Cross-linked organofunctional polysiloxanes and method for preparation |
| US5247045A (en) * | 1992-07-13 | 1993-09-21 | Dow Corning Corporation | Hydrosilylation process for preparation of novel chlorine end-terminated organosiloxanes |
| US5206402A (en) * | 1992-09-17 | 1993-04-27 | Dow Corning Corporation | Process for preparation of Ω-alkenylchlorosilanes |
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