GB1006729A - Production of organo-silicon compounds - Google Patents

Production of organo-silicon compounds

Info

Publication number
GB1006729A
GB1006729A GB15840/63A GB1584063A GB1006729A GB 1006729 A GB1006729 A GB 1006729A GB 15840/63 A GB15840/63 A GB 15840/63A GB 1584063 A GB1584063 A GB 1584063A GB 1006729 A GB1006729 A GB 1006729A
Authority
GB
United Kingdom
Prior art keywords
silanes
examples
siloxanes
starting
atoms
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB15840/63A
Inventor
Ernest Arthur Mason
William Hamilton Bell
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Imperial Chemical Industries Ltd
Original Assignee
Imperial Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Imperial Chemical Industries Ltd filed Critical Imperial Chemical Industries Ltd
Priority to GB15840/63A priority Critical patent/GB1006729A/en
Priority to FR971918A priority patent/FR1396643A/en
Publication of GB1006729A publication Critical patent/GB1006729A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic System
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/0834—Compounds having one or more O-Si linkage
    • C07F7/0838—Compounds with one or more Si-O-Si sequences
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic System
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/0834—Compounds having one or more O-Si linkage
    • C07F7/0838—Compounds with one or more Si-O-Si sequences
    • C07F7/0872—Preparation and treatment thereof
    • C07F7/0889—Reactions not involving the Si atom of the Si-O-Si sequence

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Silanes and siloxanes containing a quaternary ammonium group are made by reacting a tertiary amine with a silane or siloxane containing at least one halogen atom separated from Si by at least 3 C atoms. Amines specified are trimethyl-, triethyl-, phenyldimethyl-, phenylethyldimethyl-, chlorophenyldimethyl- and g - chlorobutyldiphenyl - amines, N,N1-ethanopiperazine, N-methylpiperidine, pyridine, pyridazine, pyrazine, pyrimidine and bis-(trimethylsiloxy)methylsilyl - ethyl - a -picoline. The starting silanes may have the formula R1aRbSiX(4- ab), wherein R1 is the g haloalkyl group of at least 3 C atoms, R is H or a monovalent hydrocarbon (saturated or unsaturated) or halohydrocarbon group, X is alkoxy, aroxy, acyloxy or halogen, a is 1, 2, 3 or 4, b is 0, 1, 2 or 3 and a + b = 4. The starting siloxanes are preferably linear siloxanes. The reaction may be effected in a solvent and preferably at 25 DEG to 150 DEG C. In a typical Example (1) g - iodopropyl - pentamethyldisiloxane, obtained by refluxing the corresponding g -chloropropylsiloxane with NaI and anhydrous acetone, was heated with N,N1-ethano-piperazine to yield a white solid which was water-soluble and was of value as a surfactant. Disiloxanes were also used as the starting materials in Examples (2) and (4) to (8), whereas silanes were used in Examples (3) and (13) and linear polysiloxanes in Examples (9), (10) and (11). Uses.-As antifoam agents and sizes for fibrous glass surfaces. Specification 882,053 is referred to.
GB15840/63A 1963-04-22 1963-04-22 Production of organo-silicon compounds Expired GB1006729A (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
GB15840/63A GB1006729A (en) 1963-04-22 1963-04-22 Production of organo-silicon compounds
FR971918A FR1396643A (en) 1963-04-22 1964-04-22 Manufacturing process for organosilicon compounds

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB15840/63A GB1006729A (en) 1963-04-22 1963-04-22 Production of organo-silicon compounds

Publications (1)

Publication Number Publication Date
GB1006729A true GB1006729A (en) 1965-10-06

Family

ID=10066475

Family Applications (1)

Application Number Title Priority Date Filing Date
GB15840/63A Expired GB1006729A (en) 1963-04-22 1963-04-22 Production of organo-silicon compounds

Country Status (1)

Country Link
GB (1) GB1006729A (en)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3340708A1 (en) * 1982-11-10 1984-05-10 Oreal POLYQUATERAL POLYSILOXANE POLYMERS, A METHOD FOR THE PRODUCTION THEREOF, AND COSMETIC AGENTS CONTAINING THESE COMPOUNDS
US4986922A (en) * 1990-04-04 1991-01-22 Dow Corning Corporation Softening compositions including quaternary ammonium functional siloxanes
US5008328A (en) * 1985-08-21 1991-04-16 Kansai Paint Co., Ltd. Aqueous organosilicon resin coating compositions
US5041590A (en) * 1990-01-04 1991-08-20 Dow Corning Corporation Quaternary ammonium functional siloxane surfactants
DE10004321A1 (en) * 2000-02-01 2001-08-09 Wacker Chemie Gmbh Organosilicon compounds with side chains containing quaternary ammonium groups derived from amine compounds with at least two tert. nitrogen atoms, used as softeners for textile treatment
DE10253152A1 (en) * 2002-11-14 2004-06-03 Rudolf Gmbh & Co. Kg Chemische Fabrik Partially quaternized, amino-functional organopolysiloxanes and their use in aqueous systems
DE102004002208A1 (en) * 2004-01-15 2005-08-18 Rudolf Gmbh & Co. Kg Chemische Fabrik Aqueous preparations based on organopolysiloxane-polyammonium block copolymers, used as after-treatment agents for improving the soft feel and color fastness of dyed cotton-based textiles

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3340708A1 (en) * 1982-11-10 1984-05-10 Oreal POLYQUATERAL POLYSILOXANE POLYMERS, A METHOD FOR THE PRODUCTION THEREOF, AND COSMETIC AGENTS CONTAINING THESE COMPOUNDS
DE3340708C2 (en) * 1982-11-10 2000-04-06 Oreal Polyquaternary polysiloxane polymers, a process for their preparation and cosmetic compositions containing these compounds
US5008328A (en) * 1985-08-21 1991-04-16 Kansai Paint Co., Ltd. Aqueous organosilicon resin coating compositions
US5041590A (en) * 1990-01-04 1991-08-20 Dow Corning Corporation Quaternary ammonium functional siloxane surfactants
US4986922A (en) * 1990-04-04 1991-01-22 Dow Corning Corporation Softening compositions including quaternary ammonium functional siloxanes
DE10004321A1 (en) * 2000-02-01 2001-08-09 Wacker Chemie Gmbh Organosilicon compounds with side chains containing quaternary ammonium groups derived from amine compounds with at least two tert. nitrogen atoms, used as softeners for textile treatment
DE10253152A1 (en) * 2002-11-14 2004-06-03 Rudolf Gmbh & Co. Kg Chemische Fabrik Partially quaternized, amino-functional organopolysiloxanes and their use in aqueous systems
US7329707B2 (en) 2002-11-14 2008-02-12 Rudolf Gmbh & Co. Kg Chemische Fabrik Partially quaternised, amino-functional organopolysiloxanes and their use in aqueous systems
DE102004002208A1 (en) * 2004-01-15 2005-08-18 Rudolf Gmbh & Co. Kg Chemische Fabrik Aqueous preparations based on organopolysiloxane-polyammonium block copolymers, used as after-treatment agents for improving the soft feel and color fastness of dyed cotton-based textiles
DE102004002208B4 (en) * 2004-01-15 2011-03-17 Rudolf Gmbh & Co. Kg Chemische Fabrik Preparations based on organopolysiloxane-polyammonium block copolymers and their use on textile substrates

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