GB1103314A - Foamed oxymethylene polymers - Google Patents

Foamed oxymethylene polymers

Info

Publication number
GB1103314A
GB1103314A GB2563265A GB2563265A GB1103314A GB 1103314 A GB1103314 A GB 1103314A GB 2563265 A GB2563265 A GB 2563265A GB 2563265 A GB2563265 A GB 2563265A GB 1103314 A GB1103314 A GB 1103314A
Authority
GB
United Kingdom
Prior art keywords
polymer
liquid
oxymethylene
trapped
per cent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2563265A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Celanese Corp
Original Assignee
Celanese Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Celanese Corp filed Critical Celanese Corp
Publication of GB1103314A publication Critical patent/GB1103314A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/28Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof by elimination of a liquid phase from a macromolecular composition or article, e.g. drying of coagulum
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2359/00Characterised by the use of polyacetals containing polyoxymethylene sequences only
    • C08J2359/02Copolyoxymethylenes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Polyethers (AREA)

Abstract

A cellular oxymethylene polymer product is prepared by dissolving the solid polymer in a volatilizable liquid and then evaporating the liquid so as to precipitate the polymer while causing a dispersion of gaseous or vaporous bubbles to be trapped in the solidifying polymer. Preferably the liquid is a solvent for the polymer only at temperatures above its boiling point at normal pressure, the solution being formed under pressure and the pressure being suddenly released to cause rapid volatilization of the liquid. Suitable solvents are alcohols containing 1 to 20 carbon atoms, ketones, alkanolamines, esters and ethers, optionally in mixture with water. The volatilization of the liquid can also be effected by bubbling an inert gas through the solution, the gas being trapped by the solidifying polymer. Preferred polymers are those containing 0.4 to 15 mole per cent of oxyethylene groups distributed among the oxymethylene groups which form the major part of the polymer, e.g. a copolymer of trioxane and approximately 2 weight per cent ethylene oxide. In examples, methanol, ammonia and water are used and nitrogen as the inert gas.
GB2563265A 1964-06-30 1965-06-17 Foamed oxymethylene polymers Expired GB1103314A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US37938564A 1964-06-30 1964-06-30

Publications (1)

Publication Number Publication Date
GB1103314A true GB1103314A (en) 1968-02-14

Family

ID=23497025

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2563265A Expired GB1103314A (en) 1964-06-30 1965-06-17 Foamed oxymethylene polymers

Country Status (4)

Country Link
BE (1) BE666159A (en)
DE (1) DE1282971B (en)
GB (1) GB1103314A (en)
NL (1) NL6508352A (en)

Also Published As

Publication number Publication date
BE666159A (en) 1965-12-30
NL6508352A (en) 1965-12-31
DE1282971B (en) 1968-11-14

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