GB1101055A - The production of allyl acetate - Google Patents

The production of allyl acetate

Info

Publication number
GB1101055A
GB1101055A GB609264A GB609264A GB1101055A GB 1101055 A GB1101055 A GB 1101055A GB 609264 A GB609264 A GB 609264A GB 609264 A GB609264 A GB 609264A GB 1101055 A GB1101055 A GB 1101055A
Authority
GB
United Kingdom
Prior art keywords
acetate
acetic acid
water
preferred
molar
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB609264A
Inventor
Duncan CLARK
Percy Hayden
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Imperial Chemical Industries Ltd
Original Assignee
Imperial Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to BE659697D priority Critical patent/BE659697A/xx
Application filed by Imperial Chemical Industries Ltd filed Critical Imperial Chemical Industries Ltd
Priority to GB609264A priority patent/GB1101055A/en
Priority to DE19651268138 priority patent/DE1268138C2/en
Priority to NL6501823A priority patent/NL6501823A/xx
Priority to FR5448A priority patent/FR1424699A/en
Priority to ES0309337A priority patent/ES309337A1/en
Publication of GB1101055A publication Critical patent/GB1101055A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
    • C07C67/05—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation
    • C07C67/055—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation in the presence of platinum group metals or their compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Allyl acetate is prepared by contacting propylene with molecular oxygen in the presence of a palladium salt, acetic acid, the acetate of an alkali metal, alkaline earth metal or copper, and a copper salt, either under anhydrous conditions or in the presence of a quantity of water not exceeding 20% by wt., based on total weight of acetic acid and water, and maintaining the halide ion concentration at or less than 0.20 molar, the concentration of the acetate being at least 0.20 molar, both molarities being based on total volume of acetic acid and water,if present. Preferred palladium salts are the acetate, chloride and bromide, and preferred acetates those of lithium, sodium and potassium. The copper salt provides a redox system and may be cupric chloride or acetate. It is preferred to operate in the absence of added solvents, at 50-150 DEG C. and under superatmospheric pressure. In examples, isopropenyl and n-propenyl acetates are obtained as by-products.
GB609264A 1964-02-13 1964-02-13 The production of allyl acetate Expired GB1101055A (en)

Priority Applications (6)

Application Number Priority Date Filing Date Title
BE659697D BE659697A (en) 1964-02-13
GB609264A GB1101055A (en) 1964-02-13 1964-02-13 The production of allyl acetate
DE19651268138 DE1268138C2 (en) 1964-02-13 1965-02-10 METHOD FOR MANUFACTURING ALLYL ACETATE
NL6501823A NL6501823A (en) 1964-02-13 1965-02-12
FR5448A FR1424699A (en) 1964-02-13 1965-02-12 Ester production process
ES0309337A ES309337A1 (en) 1964-02-13 1965-02-13 The production of allyl acetate

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB609264A GB1101055A (en) 1964-02-13 1964-02-13 The production of allyl acetate

Publications (1)

Publication Number Publication Date
GB1101055A true GB1101055A (en) 1968-01-31

Family

ID=9808228

Family Applications (1)

Application Number Title Priority Date Filing Date
GB609264A Expired GB1101055A (en) 1964-02-13 1964-02-13 The production of allyl acetate

Country Status (5)

Country Link
BE (1) BE659697A (en)
DE (1) DE1268138C2 (en)
ES (1) ES309337A1 (en)
GB (1) GB1101055A (en)
NL (1) NL6501823A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3970713A (en) * 1969-07-02 1976-07-20 Bayer Aktiengesellschaft Process for the production of allyl alcohol
US4051181A (en) * 1975-08-11 1977-09-27 National Distillers And Chemical Corporation Oxidation of allyl alcohol to acrylic acid
US4550097A (en) * 1984-08-20 1985-10-29 Phillips Petroleum Company Catalyst for the production of allyl acetate
US4571431A (en) * 1984-08-20 1986-02-18 Phillips Petroleum Company Process for the production of allyl acetate

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2428590A (en) * 1942-09-01 1947-10-07 Shell Dev Production of allyl type compounds
FR1370867A (en) * 1963-07-24 1964-08-28 Consortium Elektrochem Ind Improvements in the preparation of vinyl esters

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3970713A (en) * 1969-07-02 1976-07-20 Bayer Aktiengesellschaft Process for the production of allyl alcohol
US4051181A (en) * 1975-08-11 1977-09-27 National Distillers And Chemical Corporation Oxidation of allyl alcohol to acrylic acid
US4550097A (en) * 1984-08-20 1985-10-29 Phillips Petroleum Company Catalyst for the production of allyl acetate
US4571431A (en) * 1984-08-20 1986-02-18 Phillips Petroleum Company Process for the production of allyl acetate

Also Published As

Publication number Publication date
DE1268138B (en) 1974-07-18
DE1268138C2 (en) 1974-07-18
BE659697A (en)
ES309337A1 (en) 1965-12-16
NL6501823A (en) 1965-08-16

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