GB1097584A - Sheet - Google Patents
SheetInfo
- Publication number
- GB1097584A GB1097584A GB3892063A GB3892063A GB1097584A GB 1097584 A GB1097584 A GB 1097584A GB 3892063 A GB3892063 A GB 3892063A GB 3892063 A GB3892063 A GB 3892063A GB 1097584 A GB1097584 A GB 1097584A
- Authority
- GB
- United Kingdom
- Prior art keywords
- copolymer
- water
- units
- alkyl
- hydrogen
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
- D04H1/4326—Condensation or reaction polymers
- D04H1/4334—Polyamides
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/58—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives
- D04H1/64—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives the bonding agent being applied in wet state, e.g. chemical agents in dispersions or solutions
- D04H1/645—Impregnation followed by a solidification process
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H3/00—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
- D04H3/08—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating
- D04H3/16—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating with bonds between thermoplastic filaments produced in association with filament formation, e.g. immediately following extrusion
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Dispersion Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Laminated Bodies (AREA)
Abstract
Copolymers comprising at least 25 weight per cent of units of an N-substituted unsaturated amide of formula <FORM:1097584/C3/1> where R and R1 are hydrogen or C1- 3 alkyl and R11 is hydroxyl, C1- 3 alkoxy or dialkylamino, the balance of the copolymer being units of one or more ethylenically unsaturated monomers other than unsaturated amides may be prepared by copolymerizing the monomers in aqueous media in the presence of a catalyst. Preferred amides are reaction products of formaldehyde with acrylamide, methacrylamide or dialkylamine. Specified are acrylonitrile, vinyl acetate, methyl acrylate, methyl methacrylate and styrene, optionally together with with sufficient acid, e.g. acrylic, methacrylic, itaconic or maleic acid, to render the alkali metal, ammonium and amine salts of the copolymers water-soluble. The copolymers may be spun into fibres which may be felted or netted, or used for impregnating fabrics and felts; and may be cross-linked by heating. In Examples (1 and 2) acrylonitrile, acrylic acid and N-methylol acrylamide are copolymerized in water/isopropanol in the presence of azodiisobutyronitrile, and (3) methyl acrylate and N-methylol acrylamide are copolymerized in water in the presence of azo-g -cyanovaleric acid, and polymer solution blended with a butadiene/acrylonitrile elastomer latex and magnesium chloride solution.ALSO:Flexible sheets may be prepared by bonding fibres with a copolymer comprising at least 25 weight per cent of units of an N-substituted unsaturated amide of formula <FORM:1097584/D1-D2/1> where R is hydrogen, alkyl or substituted alkyl, R1 is hydrogen or alkyl containing up to 3 carbon atoms and R11 is hydroxyl, alkoxy containing up to 3 carbon atoms or dialkylamino, the balance of units being other than those of unsaturated amides. Fabrics may be impregnated with solutions of the copolymers, e.g. in water, aqueous calcium chloride and sodium thiocyanate solutions, alcohols and ketones, and the polymers precipitated, e.g. by acid. The sheets or fabrics may be given a permanent set by wetting, shaping and drying in the desired shape. In examples (2) a disc of viscose rayon fibre wadding is impregnated with a water/isopropanol solution of a copolymer of acrylonitrile and N-methylol acrylamide, washed with dilute sulphuric acid and water and dried at room temperature and hot pressed, and (3) a needled crimped nylon felt is impregnated with a mixture of a butadiene/acrylonitrile elastomer latex, magnesium chloride solution and an aqueous solution of a methyl acrylate / N-methylol acrylamide copolymer, dried in air and compressed at 800 p.s.i. at 160 DEG C. for 20 seconds.ALSO:Flexible sheet materials incorporating a copolymer comprising at least 25 per cent. by weight of units of an N-substituted unsaturated amide of formula <FORM:1097584/B1-B2/1> where R is hydrogen, alkyl or substituted alkyl, R1 is hydrogen or alkyl containing up to 3 carbon atoms and R11 is hydroxyl, alkoxy containing up to 3 carbon atoms or dialkyl amino, the balance of the copolymer being units of one or more ethylenically unsaturated monomers other than unsaturated amides, may be prepared by casting a coherent sheet of the copolymer on a fabric or a mat or web of unwoven fibres. The copolymer may be applied from solutions in water, aqueous calcium chloride or sodium thiocyanate solutions, lower alcohols or ketones.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB3892063A GB1097584A (en) | 1963-10-03 | 1963-10-03 | Sheet |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB3892063A GB1097584A (en) | 1963-10-03 | 1963-10-03 | Sheet |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1097584A true GB1097584A (en) | 1968-01-03 |
Family
ID=10406494
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB3892063A Expired GB1097584A (en) | 1963-10-03 | 1963-10-03 | Sheet |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB1097584A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4980437A (en) * | 1987-01-26 | 1990-12-25 | Chemische Fabrik Stockhausen Gmbh | Acrylic copolymers for re-tanning |
-
1963
- 1963-10-03 GB GB3892063A patent/GB1097584A/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4980437A (en) * | 1987-01-26 | 1990-12-25 | Chemische Fabrik Stockhausen Gmbh | Acrylic copolymers for re-tanning |
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