GB1097360A - Preparation of methylene glutaronitrile derivatives - Google Patents

Preparation of methylene glutaronitrile derivatives

Info

Publication number
GB1097360A
GB1097360A GB41244/66A GB4124466A GB1097360A GB 1097360 A GB1097360 A GB 1097360A GB 41244/66 A GB41244/66 A GB 41244/66A GB 4124466 A GB4124466 A GB 4124466A GB 1097360 A GB1097360 A GB 1097360A
Authority
GB
United Kingdom
Prior art keywords
glutaronitrile
hydrogen
cycloalkyl
alkenyl
alkyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB41244/66A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Millennium Petrochemicals Inc
Original Assignee
National Destillers and Chemical Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by National Destillers and Chemical Corp filed Critical National Destillers and Chemical Corp
Publication of GB1097360A publication Critical patent/GB1097360A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
    • C07D211/04—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D211/06—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members
    • C07D211/36—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D211/60—Carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/315—Compounds containing carbon-to-nitrogen triple bonds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M1/00—Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants
    • C10M1/08—Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants with additives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/16—Nitriles
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2050/00—Form in which the lubricant is applied to the material being lubricated
    • C10N2050/015—Dispersions of solid lubricants
    • C10N2050/02—Dispersions of solid lubricants dissolved or suspended in a carrier which subsequently evaporates to leave a lubricant coating

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

2-Ethoxymethyl glutaronitrile may be used as a lubricant additive.ALSO:The invention comprises compounds of the formula <FORM:1097360/C2/1> where Z is -OR, -NR1R11, halogen, -SR1 or -N(R1)-CO-R11, where R is alkyl, alkenyl, cycloalkyl or aryl containing 1 to 20 carbons and R1 and R11 are hydrogen, alkyl, alkenyl, cycloalkyl or aryl containing 1 to 20 carbon atoms. The invention also comprises a process for preparing an organic compound by reacting 2-methylene glutaronitrile with a compound containing at least one active hydrogen atom. The reaction may be effected at 0-100 DEG C. in a solvent, e.g. water, dioxan, t-butanol or tetrahydrofuran, at ambient or autogenous pressures up to 20 atmospheres and a cyanoalkylation catalyst, e.g. metallic sodium, sodium methylate, hydroxide or ethoxide, potassium hydroxide or a quaternary nitrogen base, may be present in an amount, e.g. of 0.01 to 1% by wt. based on the nitrile. In the examples, 2-methylene glutaronitrile is reacted with ethanol, allyl alcohol, ethylene glycol, ammonia, dimethylamine, hydrogen chloride and hydrogen bromide.
GB41244/66A 1965-09-24 1966-09-15 Preparation of methylene glutaronitrile derivatives Expired GB1097360A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US49007465A 1965-09-24 1965-09-24

Publications (1)

Publication Number Publication Date
GB1097360A true GB1097360A (en) 1968-01-03

Family

ID=23946523

Family Applications (1)

Application Number Title Priority Date Filing Date
GB41244/66A Expired GB1097360A (en) 1965-09-24 1966-09-15 Preparation of methylene glutaronitrile derivatives

Country Status (5)

Country Link
BE (1) BE687282A (en)
DE (1) DE1593176A1 (en)
FR (1) FR1495198A (en)
GB (1) GB1097360A (en)
NL (1) NL6613372A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2011075401A1 (en) * 2009-12-14 2011-06-23 The Lubrizol Corporation Lubricating composition containing a nitrile compound

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2887546A1 (en) * 2005-06-24 2006-12-29 Arkema Sa PROCESS FOR THE PREPARATION OF TRIAMINES AND FAT-CHAINED BRANCHED ETHERDIAMINES

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2011075401A1 (en) * 2009-12-14 2011-06-23 The Lubrizol Corporation Lubricating composition containing a nitrile compound
US8946135B2 (en) 2009-12-14 2015-02-03 The Lubrizol Corporation Lubricating composition containing a nitrile compound

Also Published As

Publication number Publication date
NL6613372A (en) 1967-03-28
FR1495198A (en) 1967-09-15
BE687282A (en) 1967-03-01
DE1593176A1 (en) 1971-03-25

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