GB1096922A - Improvements in and relating to the preparation of tetraalkylated tin - Google Patents
Improvements in and relating to the preparation of tetraalkylated tinInfo
- Publication number
- GB1096922A GB1096922A GB18371/65A GB1837165A GB1096922A GB 1096922 A GB1096922 A GB 1096922A GB 18371/65 A GB18371/65 A GB 18371/65A GB 1837165 A GB1837165 A GB 1837165A GB 1096922 A GB1096922 A GB 1096922A
- Authority
- GB
- United Kingdom
- Prior art keywords
- water
- tin
- ether
- phase
- solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical class [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 title 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 10
- 239000012071 phase Substances 0.000 abstract 7
- VXKWYPOMXBVZSJ-UHFFFAOYSA-N tetramethyltin Chemical compound C[Sn](C)(C)C VXKWYPOMXBVZSJ-UHFFFAOYSA-N 0.000 abstract 5
- 238000000605 extraction Methods 0.000 abstract 2
- -1 methyl tin halide Chemical class 0.000 abstract 2
- 229910021627 Tin(IV) chloride Inorganic materials 0.000 abstract 1
- 239000003513 alkali Substances 0.000 abstract 1
- 150000004820 halides Chemical class 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- JHHJZXAFNAJSCA-UHFFFAOYSA-N methyl(oxo)tin Chemical class C[Sn]=O JHHJZXAFNAJSCA-UHFFFAOYSA-N 0.000 abstract 1
- 239000012074 organic phase Substances 0.000 abstract 1
- HPGGPRDJHPYFRM-UHFFFAOYSA-J tin(iv) chloride Chemical compound Cl[Sn](Cl)(Cl)Cl HPGGPRDJHPYFRM-UHFFFAOYSA-J 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/22—Tin compounds
- C07F7/2296—Purification, stabilisation, isolation
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Processing Of Solid Wastes (AREA)
Abstract
Tetramethyl tin is recovered from a solution consisting of tetramethyl tin and a watersoluble ether by contacting the solution with water thereby to form a tetramethyl tin phase and a water phase containing a water soluble ether; these phases are then separated. The ether has a high solubility in water at the extraction temp., i.e. 15-50 DEG C., and is preferably infinitely miscible with water. The soluble can contain at least one methyl tin halide, this halide entering the water phase during contact of the solution with water. The initial solution can be formed by reacting methyl magnesium halide and tin tetrachloride, this solution is hydrolysed and the organic phase is extracted with water, e.g. at 15-50 DEG C. and the tetramethyl tin phase is separated. The tetramethyl tin can be separated from the ether/water phase using a countercurrent extraction technique. Methyl tin oxides can be recovered from the water phase after removal of the ether by treatment with alkali.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US36431864A | 1964-05-01 | 1964-05-01 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1096922A true GB1096922A (en) | 1967-12-29 |
Family
ID=23433969
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB18371/65A Expired GB1096922A (en) | 1964-05-01 | 1965-04-30 | Improvements in and relating to the preparation of tetraalkylated tin |
Country Status (5)
| Country | Link |
|---|---|
| DE (1) | DE1279018B (en) |
| ES (1) | ES312303A1 (en) |
| GB (1) | GB1096922A (en) |
| IL (1) | IL23411A (en) |
| NL (1) | NL6505520A (en) |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE163325C (en) * | ||||
| NL268499A (en) * | 1960-08-22 |
-
1965
- 1965-04-21 IL IL23411A patent/IL23411A/en unknown
- 1965-04-27 ES ES0312303A patent/ES312303A1/en not_active Expired
- 1965-04-27 DE DEM65038A patent/DE1279018B/en active Pending
- 1965-04-29 NL NL6505520A patent/NL6505520A/xx unknown
- 1965-04-30 GB GB18371/65A patent/GB1096922A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| IL23411A (en) | 1968-08-22 |
| ES312303A1 (en) | 1965-12-01 |
| DE1279018B (en) | 1968-10-03 |
| NL6505520A (en) | 1965-11-02 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| IL39710A0 (en) | Recovery of acids from aqueous solutions by solvent extraction | |
| IT1040896B (en) | PROCEDURE FOR THE RECOVERY OF THE GALLIUM PRESENT IN THE WATER SOLUTIONS BY EXTRACTION OF LIQUID LIQUID BY MEANS OF AN ORGANIC PHASE | |
| ES280459A1 (en) | A procedure for the extraction of metals from the aqueous solutions of your salts (Machine-translation by Google Translate, not legally binding) | |
| ES416573A1 (en) | Method of separating and recovering mucopolysaccharides from connective tissues of animals | |
| GB1096922A (en) | Improvements in and relating to the preparation of tetraalkylated tin | |
| JPS529963A (en) | Method for removing arsenic and silicic acid contained in aqueous solu tion simultaneously | |
| SE7313965L (en) | ||
| ES426753A1 (en) | Purification of phosophoric acid by means of organic solvents | |
| GB997325A (en) | Recovery of acrylic acid | |
| SE7611308L (en) | RECOVERY OF ORGANOTENN HALOGENIDES | |
| SE385769B (en) | PROCEDURE FOR THE PRODUCTION OF A QUICK, SUSTAINABLE, NEUTRAL SOLUTION OF CLEAN, CRYSTALINT OR WHEN ADDED TO ZINK IN WATER CRYSTALIZED NOTINSULIN OR INSULIN MIXTURES, CONTAINING SUCH ... | |
| IT1046020B (en) | PROCEDURE FOR THE RECOVERY OF A DIALKYLBENZEN DIHYDROPEROXIDE FROM ITS ALCALINE AQUEOUS SOLUTIONS BY COUNTER-CURRENT EXTRACTION WITH HIGH EFFICIENCY | |
| GB1036205A (en) | Process for the separation of the products obtained through the nitration of cyclohexane in gaseous phase | |
| CH410879A (en) | Process for the continuous extraction of hydrofluoric acid from its aqueous solutions | |
| GB1209272A (en) | Cleaning of phosphoric acid | |
| OA04776A (en) | Process for extracting the solvent contained in proteins. | |
| GB1072238A (en) | Process for the preparation of pivalolactone | |
| JPS539711A (en) | Recovery of dimethylformamide | |
| NL7409335A (en) | PROCESS FOR CONVERTING SULFURIC ACID OR WATER SULPHATES CONTAINED IN SOLUTION TO USEABLE PRODUCTS. | |
| GB790760A (en) | Recovering trimethylolethane | |
| ES325770A1 (en) | Procedure for the treatment of recovery of aqueous solutions containing glycolic ether and hexadienic acids. (Machine-translation by Google Translate, not legally binding) | |
| JPS5230070A (en) | Taking and washing device of undiluted solution from drum ca or the li ke | |
| JPS5382660A (en) | Extracting and separating method of metal by liquid-liquid extraction | |
| JPS51145174A (en) | Sealed type continuous defatting washing apparatus | |
| GB2039897A (en) | Process for purifying naphthoqinone |