GB1092867A - Metal cleaning - Google Patents
Metal cleaningInfo
- Publication number
- GB1092867A GB1092867A GB47240/64A GB4724064A GB1092867A GB 1092867 A GB1092867 A GB 1092867A GB 47240/64 A GB47240/64 A GB 47240/64A GB 4724064 A GB4724064 A GB 4724064A GB 1092867 A GB1092867 A GB 1092867A
- Authority
- GB
- United Kingdom
- Prior art keywords
- hlb value
- articles
- toluidene
- container
- acids
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000002184 metal Substances 0.000 title abstract 4
- 229910052751 metal Inorganic materials 0.000 title abstract 4
- 238000004140 cleaning Methods 0.000 title abstract 2
- 239000004094 surface-active agent Substances 0.000 abstract 4
- 239000000203 mixture Substances 0.000 abstract 3
- -1 polyoxypropylene Polymers 0.000 abstract 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 abstract 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 2
- 239000002253 acid Substances 0.000 abstract 2
- 150000001412 amines Chemical class 0.000 abstract 2
- LTFTWJYRQNTCHI-UHFFFAOYSA-N hex-1-yn-3-ol Chemical compound CCCC(O)C#C LTFTWJYRQNTCHI-UHFFFAOYSA-N 0.000 abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- 239000003112 inhibitor Substances 0.000 abstract 2
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 abstract 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 abstract 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 abstract 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 abstract 1
- 229910000831 Steel Inorganic materials 0.000 abstract 1
- 150000007513 acids Chemical class 0.000 abstract 1
- 239000011324 bead Substances 0.000 abstract 1
- 229910052793 cadmium Inorganic materials 0.000 abstract 1
- 229910052799 carbon Inorganic materials 0.000 abstract 1
- 239000011248 coating agent Substances 0.000 abstract 1
- 238000000576 coating method Methods 0.000 abstract 1
- 238000005238 degreasing Methods 0.000 abstract 1
- 239000003599 detergent Substances 0.000 abstract 1
- 239000002270 dispersing agent Substances 0.000 abstract 1
- 239000006185 dispersion Substances 0.000 abstract 1
- 238000004945 emulsification Methods 0.000 abstract 1
- 239000003995 emulsifying agent Substances 0.000 abstract 1
- 239000011521 glass Substances 0.000 abstract 1
- 230000002209 hydrophobic effect Effects 0.000 abstract 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 abstract 1
- 229910052745 lead Inorganic materials 0.000 abstract 1
- 229910052753 mercury Inorganic materials 0.000 abstract 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 150000007522 mineralic acids Chemical class 0.000 abstract 1
- 238000007747 plating Methods 0.000 abstract 1
- 229920001451 polypropylene glycol Polymers 0.000 abstract 1
- 108090000623 proteins and genes Chemical class 0.000 abstract 1
- 102000004169 proteins and genes Human genes 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 239000010959 steel Substances 0.000 abstract 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 abstract 1
- 150000003585 thioureas Chemical class 0.000 abstract 1
- 229910052718 tin Inorganic materials 0.000 abstract 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 abstract 1
- YNJBWRMUSHSURL-UHFFFAOYSA-N trichloroacetic acid Chemical class OC(=O)C(Cl)(Cl)Cl YNJBWRMUSHSURL-UHFFFAOYSA-N 0.000 abstract 1
- 238000009736 wetting Methods 0.000 abstract 1
- 239000000080 wetting agent Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/02—Cleaning or pickling metallic material with solutions or molten salts with acid solutions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/40—Specific cleaning or washing processes
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
- Detergent Compositions (AREA)
Abstract
Prior to coating metal articles, particularly in a mechanical plating process, batches of the metal articles e.g. steel are cleaned in a container, such as a rotary barrel, in an aqueous descaling and degreasing solution comprising a strong acid, hydrogen embrittlement inhibitor and a surfactant composition having the combined properties of metal wetting, oxide detergency, oil emulsification and dirt dispersion, the container is agitated and the articles are then rinsed. Impact media such as glass beads may be added to the barrel to aid mechanical cleaning. Suitable acids are; sulphuric, phosphoric, tartaric, citric, diglycolic, chlorosulfonic, formic, acetic and mono-, di- or tri-chloroacetic acids. When strong inorganic acids are used carbon smutting is prevented by the addition of salts such as sulphates of Sn, Pb, Cd and Hg. The surfactant composition is a mixture of surfactants each of which has a hydrophobic polyoxypropylene nucleus and hydrophilic polyoxyethylene units graft polymerized thereon, one surfactant being a wetting agent with an HLB value of 1-5, one being a detergent with an HLB value of 12-17 one being an emulsifier with an HLB value of 12-17 and one being a dispersant with an HLB value greater than 17. The hydrogen embrittlement inhibitors may be polyoxyethylene glycol, o-toluidene, an adduct of o-toluidene and formaldehyde, ethylene oxide modified rosin amine, 1-hexyn-3-ol, substituted thioureas and amines or proteins.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US339606A US3330769A (en) | 1964-01-23 | 1964-01-23 | Metal cleaning |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1092867A true GB1092867A (en) | 1967-11-29 |
Family
ID=23329806
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB47240/64A Expired GB1092867A (en) | 1964-01-23 | 1964-11-19 | Metal cleaning |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US3330769A (en) |
| JP (1) | JPS4930615B1 (en) |
| BE (1) | BE658442A (en) |
| CH (1) | CH485871A (en) |
| DE (1) | DE1546161B2 (en) |
| FR (1) | FR1420885A (en) |
| GB (1) | GB1092867A (en) |
| NL (1) | NL149235B (en) |
| SE (1) | SE319664B (en) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3494795A (en) * | 1967-08-07 | 1970-02-10 | Fremont Ind Inc | Spray cleaning method for removing oil,grease,dirt and embedded oxides from painted surfaces |
| US3909437A (en) * | 1973-01-18 | 1975-09-30 | Dow Chemical Co | Noncorrosive acid, solvent and nonionic surfactant composition |
| US3979219A (en) * | 1975-03-06 | 1976-09-07 | Fremont Industries, Inc. | Wood finish remover |
| US4100096A (en) * | 1976-06-04 | 1978-07-11 | Addressograph Multigraph Corp. | Cleaner for hydrophilic metal surfaces of lithographic duplicators |
| BE871631A (en) * | 1978-10-27 | 1979-04-27 | Centre Rech Metallurgique | PROCESS FOR CONTINUOUS PICKLING OF STEEL SHEETS. |
| US4541945A (en) * | 1982-09-30 | 1985-09-17 | Amchem Products | Inhibitor-containing acid cleaning compositions and processes |
| US4608086A (en) * | 1983-01-19 | 1986-08-26 | Tennant Company | Membrane remover/etchant |
| JPS60224818A (en) * | 1984-04-20 | 1985-11-09 | Itochu Shoji Kk | Detection of colored things in raw cotton and device therefor |
| JPH0525713A (en) * | 1991-05-17 | 1993-02-02 | Murata Mach Ltd | Foreign matter detector of opening and scutching process |
| US5658869A (en) * | 1995-10-16 | 1997-08-19 | Singer; Barrie | Metal finishing composition |
| JP3673357B2 (en) * | 1997-01-27 | 2005-07-20 | メルテックス株式会社 | Pretreatment cleaner for plating |
| CN101932315B (en) * | 2007-12-07 | 2014-08-06 | 普莱斯博有限两合公司 | Method for applying polymer coating to inner surface of container |
| US8227027B2 (en) | 2007-12-07 | 2012-07-24 | Presspart Gmbh & Co. Kg | Method for applying a polymer coating to an internal surface of a container |
| CN104289468A (en) * | 2007-12-07 | 2015-01-21 | 普莱斯博有限两合公司 | Method for applying polymer coating to inner surface of container |
| US20190189312A1 (en) * | 2017-12-19 | 2019-06-20 | National Cheng Kung University | Pretreatment of Thick-Film Aluminum Electrode for Metal Plating |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2261700A (en) * | 1939-04-03 | 1941-11-04 | Nat Aluminate Corp | Cleaning composition |
| US2326837A (en) * | 1940-01-13 | 1943-08-17 | Nat Carbon Co Inc | Cleaning composition and method for its use |
| US2399267A (en) * | 1940-07-27 | 1946-04-30 | Solventol Chemical Products In | Cleaning method |
| US2571581A (en) * | 1948-09-09 | 1951-10-16 | Detrex Corp | Degreasing machine |
| US2683343A (en) * | 1952-11-15 | 1954-07-13 | Gen Motors Corp | Tumbling process |
| US3041285A (en) * | 1955-05-27 | 1962-06-26 | Purex Corp Ltd | Composition for cleaning and polishing aluminum and aluminum alloys |
| US2942956A (en) * | 1958-10-13 | 1960-06-28 | Wyandotte Chemicals Corp | Aluminum brightener compositions |
| US3162547A (en) * | 1961-07-31 | 1964-12-22 | Rohr Corp | Secondary deoxidizer for aluminum and its alloys |
-
1964
- 1964-01-23 US US339606A patent/US3330769A/en not_active Expired - Lifetime
- 1964-11-19 GB GB47240/64A patent/GB1092867A/en not_active Expired
- 1964-12-10 DE DE19641546161 patent/DE1546161B2/en active Pending
- 1964-12-17 JP JP39070790A patent/JPS4930615B1/ja active Pending
-
1965
- 1965-01-14 FR FR1893A patent/FR1420885A/en not_active Expired
- 1965-01-15 CH CH59665A patent/CH485871A/en not_active IP Right Cessation
- 1965-01-18 BE BE658442D patent/BE658442A/xx unknown
- 1965-01-21 SE SE783/65A patent/SE319664B/xx unknown
- 1965-01-22 NL NL656500857A patent/NL149235B/en not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| FR1420885A (en) | 1965-12-10 |
| CH485871A (en) | 1970-02-15 |
| NL6500857A (en) | 1965-07-26 |
| NL149235B (en) | 1976-04-15 |
| DE1546161B2 (en) | 1972-03-02 |
| BE658442A (en) | 1965-05-17 |
| JPS4930615B1 (en) | 1974-08-14 |
| SE319664B (en) | 1970-01-19 |
| DE1546161A1 (en) | 1969-07-17 |
| US3330769A (en) | 1967-07-11 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| GB1092867A (en) | Metal cleaning | |
| CA1085704A (en) | Acid cleaner and process for disposal thereof | |
| US5705472A (en) | Neutral aqueous cleaning composition | |
| US3886099A (en) | Water soluble flux remover | |
| US4390465A (en) | Low temperature composition for plating pretreatment of ferrous metals | |
| CN100480365C (en) | Detergent composition | |
| CN111705323A (en) | Environment-friendly stainless steel cleaning agent and method for cleaning stainless steel parts | |
| CA2177278A1 (en) | Wheel cleaning composition containing acid fluoride salts | |
| CA2370531A1 (en) | Composition comprising a poly(oxyalkylene) ammonium surfactant and method for road-film removal | |
| KR880011319A (en) | Liquid Alkaline Concentrate Freshener | |
| CN103469237A (en) | Metal oil contamination cleaner | |
| US1949713A (en) | Material for preparing metal surfaces for painting and the like | |
| DE69120830T2 (en) | IN THE ESSENTIAL PHOSPHATE-FREE, LOW-ACID CLEANING AGENT FOR PLASTIC ITEMS | |
| CN112625808B (en) | Acidic cleaning agent and preparation method and application thereof | |
| US20050256025A1 (en) | Metal brightener and surface cleaner | |
| EP0376367A1 (en) | Aqueous cleaning agent for metal surfaces | |
| JP3025850B2 (en) | Flux cleaner | |
| US3645790A (en) | Composition and process for cleaning metal | |
| CN103469229A (en) | Water-based metal surface cleaner | |
| US3312625A (en) | Pickling inhibitor composition | |
| CN110453232B (en) | Phosphorus-free normal-temperature composite metal surface degreasing agent | |
| JP3514782B2 (en) | Low residue cleaning agent | |
| CN110565104A (en) | Environment-friendly spray cleaning agent and preparation method thereof | |
| CA2133468A1 (en) | Cleaning compositions for hard surfaces, more particularly glass | |
| US5468412A (en) | Low foaming aqueous cleaning and passivating treatment for metals |