GB1092673A - Copolymers for use as binders in paper coating compositions - Google Patents
Copolymers for use as binders in paper coating compositionsInfo
- Publication number
- GB1092673A GB1092673A GB879665A GB879665A GB1092673A GB 1092673 A GB1092673 A GB 1092673A GB 879665 A GB879665 A GB 879665A GB 879665 A GB879665 A GB 879665A GB 1092673 A GB1092673 A GB 1092673A
- Authority
- GB
- United Kingdom
- Prior art keywords
- weight
- acid
- acrylate
- copolymer
- esters
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/56—Macromolecular organic compounds or oligomers thereof obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D21H19/58—Polymers or oligomers of diolefins, aromatic vinyl monomers or unsaturated acids or derivatives thereof
Abstract
Binders for paper-coating compositions comprise a mixture in aqueous dispersion of: (a) 95 to 60% by weight of a copolymer A having a glass temperature of from - 60 DEG to + 20 DEG C. and derived from 40-70% by weight styrene, 30-60% of an acrylate and/or methacrylate ester of a C2-C12 aliphatic alcohol and 0-10% of at least one other ethylenically unsaturated compound, and (b) 5 to 40% by weight of a copolymer B derived from 15-55% by weight of acrylic and/or methacrylic acid, 2-6% of acrylamide and/or methacrylamide and 85-45% of at least one other ethylenically unsaturated compound which forms a water-insoluble homopolymer, of which at least 20% by weight (with reference to these other compounds) is one or more acrylate and/or methacrylate esters of a C1-C4 aliphatic alcohol. The optional monomer components of copolymer A include acrylonitrile, vinyl chloride, vinylidene chloride, acrylic acid, methacrylic acid, crotonic acid, maleic acid, fumaric acid, itaconic acid and amides, substituted amides and hemi esters of such acids, vinyl sulphonic acid and p-styrene sulphonic acid. Monomer components (forming water-insoluble homopolymers) which may be incorporated in copolymer B, in addition to the essential (meth)-acrylate esters, include corresponding esters of alcohols with more than 4 carbon atoms, styrene, vinyl chloride, vinylidene chloride, vinyl esters, acrylonitrile and methacrylonitrile. For use as paper-coating compositions, the binders are mixed with fillers or pigments, e.g. clay or titanium dioxide, and other optional components, e.g. sodium polyacrylate, and adjuste to neutral or alkaline pH by treatment with an alkali. In an example, (A) styrene, n-butyl acrylate, acrylic acid and sodium vinyl sulphonate are polymerized in aqueous emulsion using potassium persulphate catalyst, and (B) ethyl acrylate, acrylic acid and acrylamide are polymerized in aqueous emulsion using potassium persulphate catalyst and in the presence of dodecyl mercaptan.ALSO:Neutral or alkaline paper coating compositions comprise a pigment or filler, e.g. clay or titanium dioxide, suspended in a binder comprising an aqueous dispersion of (a) 95 to 60% by weight of a copolymer derived from styrene, an acrylate and/or methacrylate ester of a C2-C12 aliphatic alcohol and optionally at least one other ethylenically unsaturated compound, e.g. acrylic acid, sodium vinyl sulphonate and/or acrylonitrile, and 5 to 40% by weight of a copolymer derived from acrylic and/or methacrylic acid, acrylamide and/or methacrylamide and at least one other ethylenically unsaturated compound which forms a water-insoluble homopolymer, of which at least 20% by weight of these other compounds is one or more acrylate and/or methacrylate esters of C1-C4 aliphatic alcohol (acrylonitrile may also be included, for example, in said other compounds). The coating compositions may include other components, e.g. sodium polyacrylate. Paper can be coated with the compositions by known methods such as roller coating or with a blade coater.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEB75688A DE1258721B (en) | 1964-03-03 | 1964-03-03 | Binders for paper coating slips |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1092673A true GB1092673A (en) | 1967-11-29 |
Family
ID=6978766
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB879665A Expired GB1092673A (en) | 1964-03-03 | 1965-03-02 | Copolymers for use as binders in paper coating compositions |
Country Status (6)
Country | Link |
---|---|
DE (1) | DE1258721B (en) |
FI (1) | FI43539B (en) |
FR (1) | FR1425907A (en) |
GB (1) | GB1092673A (en) |
NO (1) | NO121128B (en) |
SE (1) | SE306663B (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1984002139A1 (en) * | 1982-11-23 | 1984-06-07 | Dow Chemical Co | Polymeric compositions useful as binders in coating colors and coating colors prepared therefrom |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3440188A (en) * | 1966-01-10 | 1969-04-22 | Gulf Oil Corp | Aqueous-based polish comprising ethylene acrylate ester copolymer and homopolymer or copolymer of styrene and/or acrylate esters |
DE19512882A1 (en) * | 1995-04-06 | 1996-10-10 | Basf Ag | Aqueous polymer dispersion |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB751729A (en) * | 1952-06-25 | 1956-07-04 | John Charles Rice | Method of producing a high finish on paper products |
US2790735A (en) * | 1955-01-31 | 1957-04-30 | Rohm & Haas | Coated paper products and methods of making them |
-
1964
- 1964-03-03 DE DEB75688A patent/DE1258721B/en active Pending
-
1965
- 1965-03-01 FI FI49865A patent/FI43539B/fi active
- 1965-03-02 GB GB879665A patent/GB1092673A/en not_active Expired
- 1965-03-02 NO NO15701265A patent/NO121128B/no unknown
- 1965-03-03 SE SE277965A patent/SE306663B/xx unknown
- 1965-03-03 FR FR7755A patent/FR1425907A/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1984002139A1 (en) * | 1982-11-23 | 1984-06-07 | Dow Chemical Co | Polymeric compositions useful as binders in coating colors and coating colors prepared therefrom |
Also Published As
Publication number | Publication date |
---|---|
FR1425907A (en) | 1966-01-24 |
DE1258721B (en) | 1968-01-11 |
FI43539B (en) | 1970-12-31 |
SE306663B (en) | 1968-12-02 |
NO121128B (en) | 1971-01-18 |
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