GB1087896A - Process for the manufacture of urethanes - Google Patents

Process for the manufacture of urethanes

Info

Publication number
GB1087896A
GB1087896A GB2857765A GB2857765A GB1087896A GB 1087896 A GB1087896 A GB 1087896A GB 2857765 A GB2857765 A GB 2857765A GB 2857765 A GB2857765 A GB 2857765A GB 1087896 A GB1087896 A GB 1087896A
Authority
GB
United Kingdom
Prior art keywords
metals
fecl3
nitro
compounds
urethanes
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2857765A
Inventor
Arthur Ibbotson
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Imperial Chemical Industries Ltd
Original Assignee
Imperial Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Imperial Chemical Industries Ltd filed Critical Imperial Chemical Industries Ltd
Priority to GB2857765A priority Critical patent/GB1087896A/en
Priority to SE918866A priority patent/SE325562B/xx
Priority to DE19661568851 priority patent/DE1568851A1/en
Priority to FR68480A priority patent/FR1487542A/en
Priority to NL6609480A priority patent/NL6609480A/xx
Publication of GB1087896A publication Critical patent/GB1087896A/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/128—Halogens; Compounds thereof with iron group metals or platinum group metals
    • B01J27/13—Platinum group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D213/61—Halogen atoms or nitro radicals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G71/00—Macromolecular compounds obtained by reactions forming a ureide or urethane link, otherwise, than from isocyanate radicals in the main chain of the macromolecule

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Polyurethanes Or Polyureas (AREA)

Abstract

Polyurethanes are made by reacting (a) polynitro, polynitroso, nitro-azo or nitro-azoxy compounds with polyols and CO, or (b) hydroxynitro compounds with CO, in presence of a mixture of one or more multivalent metals with one or more halides of multivalent metals other than the first-mentioned metal or metals.ALSO:Urethanes are made by reacting an organic hydroxyl compound with CO and a compound containing a non-cyclic O = N-C or N = N-C group, in presence of a mixture of one or more multivalent metals with one or more halides of multivalent metals other than the first-mentioned metal or metals. The O = N-C or N = N-C compounds may be nitro, nitroso, azo or azoxy compounds. Examples describe the preparation of PhNHCO2Me from PhNO2, CO and MeOH in presence of (1) Pd/Al2O3 + FeCl3, (2) Pd/C + FeCl3 or (3) Fe + RhCl3.ALSO:Exemplified catalysts for making urethanes from nitro, nitroso, azo or azoxy compounds are (1) Pd/Al2O3 + FeCl3, (2) Pd/C + FeCl3 (3) Fe + RhCl3.
GB2857765A 1965-07-06 1965-07-06 Process for the manufacture of urethanes Expired GB1087896A (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
GB2857765A GB1087896A (en) 1965-07-06 1965-07-06 Process for the manufacture of urethanes
SE918866A SE325562B (en) 1965-07-06 1966-07-05
DE19661568851 DE1568851A1 (en) 1965-07-06 1966-07-06 Process for making urethanes
FR68480A FR1487542A (en) 1965-07-06 1966-07-06 Manufacturing process for urethanes and their polymers
NL6609480A NL6609480A (en) 1965-07-06 1966-07-06

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB2857765A GB1087896A (en) 1965-07-06 1965-07-06 Process for the manufacture of urethanes

Publications (1)

Publication Number Publication Date
GB1087896A true GB1087896A (en) 1967-10-18

Family

ID=10277822

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2857765A Expired GB1087896A (en) 1965-07-06 1965-07-06 Process for the manufacture of urethanes

Country Status (4)

Country Link
DE (1) DE1568851A1 (en)
GB (1) GB1087896A (en)
NL (1) NL6609480A (en)
SE (1) SE325562B (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4178455A (en) * 1977-07-25 1979-12-11 Mitsui Toatsu Chemicals, Incorporated Process for preparing aromatic urethanes
US4490551A (en) * 1979-03-02 1984-12-25 Bayer Aktiengesellschaft Process for the production of urethanes

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3009489A1 (en) * 1980-03-12 1981-09-17 Bayer Ag, 5090 Leverkusen METHOD FOR PRODUCING URETHANES

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4178455A (en) * 1977-07-25 1979-12-11 Mitsui Toatsu Chemicals, Incorporated Process for preparing aromatic urethanes
US4490551A (en) * 1979-03-02 1984-12-25 Bayer Aktiengesellschaft Process for the production of urethanes

Also Published As

Publication number Publication date
NL6609480A (en) 1967-01-09
SE325562B (en) 1970-07-06
DE1568851A1 (en) 1970-07-16

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