GB1086980A - Glass fibre reinforced moulding compositions - Google Patents

Glass fibre reinforced moulding compositions

Info

Publication number
GB1086980A
GB1086980A GB42380/66A GB4238066A GB1086980A GB 1086980 A GB1086980 A GB 1086980A GB 42380/66 A GB42380/66 A GB 42380/66A GB 4238066 A GB4238066 A GB 4238066A GB 1086980 A GB1086980 A GB 1086980A
Authority
GB
United Kingdom
Prior art keywords
styrene
copolymer
acrylonitrile
fibre reinforced
glass fibre
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB42380/66A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bayer AG
Original Assignee
Bayer AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer AG filed Critical Bayer AG
Publication of GB1086980A publication Critical patent/GB1086980A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L25/00Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
    • C08L25/02Homopolymers or copolymers of hydrocarbons
    • C08L25/04Homopolymers or copolymers of styrene
    • C08L25/08Copolymers of styrene
    • C08L25/12Copolymers of styrene with unsaturated nitriles
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00Use of ingredients characterised by shape
    • C08K7/02Fibres or whiskers
    • C08K7/04Fibres or whiskers inorganic
    • C08K7/14Glass
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00Use of pretreated ingredients
    • C08K9/04Ingredients treated with organic substances
    • C08K9/06Ingredients treated with organic substances with silicon-containing compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L55/00Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
    • C08L55/02ABS [Acrylonitrile-Butadiene-Styrene] polymers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Reinforced Plastic Materials (AREA)

Abstract

Glass fibre reinforced moulding compositions comprise (A) 0.1-30% of glass fibres sized with water or with vinyl silane and (B) 99.9-70% of an elastic-thermoplastic copolymer mixture comprising (a) 10-50% of an elastic copolymer of a conjugated diolefine, e.g. butadiene and styrene, acrylonitrile and/or an alkyl substituted derivative of styrene and/or acrylonitrile, e.g. a -methylstyrene or methacrylonitrile, and (b) 90-50% of a thermoplastic copolymer of styrene or a nuclear or side-chain alkylated styrene, e.g. a -methyl-styrene, with acrylonitrile or methacrylonitrile. Copolymer (B) may be prepared by mixing a latex obtained by the emulsion polymerization of butadiene, acrylonitrile, methacrylic acid and divinylbenzene with a latex of a copolymer of styrene and acrylonitrile, adding an anti-oxidant, e.g. 2,21-methylene - bis - 4 - methyl - 6 - cyclohexyl phenol, and coagulating the mixture with calcium chloride solution. The composition may be prepared by homogenizing the copolymer (B) with the water-sized glass fibres, e.g. of diameter 1-50 microns and length 0.05-6 mm., adding calcium or zinc stearate, the above antioxidant and titanium dioxide, compacting the powder into strips and then granulating. The composition may be formed into shaped articles.
GB42380/66A 1965-11-24 1966-09-22 Glass fibre reinforced moulding compositions Expired GB1086980A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEF0047747 1965-11-24

Publications (1)

Publication Number Publication Date
GB1086980A true GB1086980A (en) 1967-10-11

Family

ID=7101815

Family Applications (1)

Application Number Title Priority Date Filing Date
GB42380/66A Expired GB1086980A (en) 1965-11-24 1966-09-22 Glass fibre reinforced moulding compositions

Country Status (11)

Country Link
AT (1) AT273483B (en)
BE (1) BE690113A (en)
CH (1) CH460331A (en)
DE (1) DE1250117B (en)
DK (1) DK114156B (en)
ES (1) ES333671A1 (en)
FI (1) FI45233C (en)
FR (1) FR1501419A (en)
GB (1) GB1086980A (en)
NL (1) NL6616569A (en)
SE (1) SE334237B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4547533A (en) * 1983-07-09 1985-10-15 Bayer Aktiengesellschaft Glass-fiber-reinforced ABS-molding compositions

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2174786B1 (en) * 1972-03-10 1974-08-02 Charbonnages Ste Chimique
US4064099A (en) * 1974-06-06 1977-12-20 Shiseido Company, Ltd. Thermoplastic resin composition having a pearly luster
AU559998B2 (en) * 1984-02-21 1987-03-26 Dow Chemical Company, The Mineral fiber rubber reinforced resins
JPS59187046A (en) * 1984-10-05 1984-10-24 Mitsubishi Monsanto Chem Co Glass-fiber reinforced heat-resistant resin composition
DE4330860C2 (en) * 1993-09-11 2002-08-08 Basf Ag Process for the production of a flat semi-finished product from glass mat-reinforced propylene polymers

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4547533A (en) * 1983-07-09 1985-10-15 Bayer Aktiengesellschaft Glass-fiber-reinforced ABS-molding compositions

Also Published As

Publication number Publication date
SE334237B (en) 1971-04-19
AT273483B (en) 1969-08-11
FI45233B (en) 1971-12-31
ES333671A1 (en) 1967-10-01
BE690113A (en) 1967-05-02
CH460331A (en) 1968-07-31
FR1501419A (en) 1967-11-10
NL6616569A (en) 1967-05-25
DE1250117B (en)
FI45233C (en) 1972-04-10
DK114156B (en) 1969-06-02

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