GB1081891A - Improvements relating to the production of phosphoric acids - Google Patents
Improvements relating to the production of phosphoric acidsInfo
- Publication number
- GB1081891A GB1081891A GB2952064A GB2952064A GB1081891A GB 1081891 A GB1081891 A GB 1081891A GB 2952064 A GB2952064 A GB 2952064A GB 2952064 A GB2952064 A GB 2952064A GB 1081891 A GB1081891 A GB 1081891A
- Authority
- GB
- United Kingdom
- Prior art keywords
- acid
- zone
- barrier
- effluent
- dip
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B25/00—Phosphorus; Compounds thereof
- C01B25/16—Oxyacids of phosphorus; Salts thereof
- C01B25/24—Condensed phosphoric acids
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Treating Waste Gases (AREA)
Abstract
Phosphoric acid of a P2O5 content greater than 68% w/w (IFB) is produced by continuously feeding wet-process phosphoric acid to a heating zone, e.g. in a submerged combustion evaporator, and withdrawing the more concentrated product acid. In the zone, the acid is maintained at its boiling-point by releasing hot combustion products into the acid, e.g. through a dip-tube extending vertically into the acid so as to form a stable bubble on the annular surface around the exhaust orifice at the lower end of dip-tube. The gaseous effluent from this zone is passed to a scrubbing zone, flowing therein at 15-100 f.p.s., and passed through apertures in a barrier obturating this scrubbing zone at 100-400 f.p.s., preferably 300-350 f.p.s., effecting a pressure drop across the barrier of not less than 15m w.g., preferably 35-40m w.g. A spray of water and/or hot weak phosphoric acid containing not more than 50% P2O5 (e.g. 30-50% at 70-120 DEG C.) is sprayed on to the upstream face of the barrier to cause large droplets of the acid to break into smaller droplets such that they mix intimately with the gaseous effluent. The acid is then separated from the effluent and thereafter, the effluent is treated with cold water. The product acid has a low content of insoluble polyphosphate and metaphosphate compounds. The apparatus is also claimed. Preferably, the annular surface surrounding the exhaust orifice of the dip tube has a radial extent, L, given by the formula L = kR(Qa -1) wherein R is the radius of the external orifice, Q is the heat-release rate of the burner in millions of B.Thu/hour, and k, a are constants such that k is \sF0.6, preferably \sF0.9, and a is 0.29-0.32, preferably 0.3.ALSO:Phosphoric acid of a P2O5 content greater than 68% W/W (IFB) are produced by continuously feeding wet-process phosphoric acid to a heating-zone e.g. in a submerged combustion evaporator, and withdrawing the more concentrated product acid. In the zone, the acid is maintained at its boiling-point by releasing hot combustion products into the acid e.g. through a dip-tube extending vertically into the acid so as to form a stable bubble on the annular surface around the exhaust orifice at the lower end of the dip tube. The gaseous effluent from this zone is passed to a scrubbing zone, flowing therein at 15-100 fps, and passed through apertures in a barrier obturating this scrubbing zone at 100-400 fps, preferably 300-350 fps, effecting a pressure drop across the barrier of not less than 15" w.g., preferably 35 - 40" w.g. A spray of water and/or hot, weak phosphoric acid containing not more than 50% P2O5 (e.g. 30-50%) at 70 - 100 DEG C is sprayed onto the upstream face of the barrier to cause large droplets of the acid to break into smaller droplets such that they mix intimately with the gaseous effluent. The acid is then separated from the effluent and thereafter, the effluent is treated with cold water. The product acid has a low content of insoluble polyphosphate and metaphosphate compounds. Preferably, the annular surface around the exhaust orifice of the dip tube has a radius, L. given by the formula:- <FORM:1081891/B1-B2/1> wherein R is the radius of the external orifice, Q is the heat release rate of the burner in millions of B.Th.U/ per hour, and a, k are constants, k being greater than or equal to 0.6, preferably greater than or equal to 0.9, and a is 0.29 - 0.32, preferably 0.3.
Priority Applications (9)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB2952064A GB1081891A (en) | 1964-07-21 | 1964-07-21 | Improvements relating to the production of phosphoric acids |
DK374465A DK123861B (en) | 1964-07-21 | 1965-07-21 | Process by concentrating phosphoric acid and apparatus for carrying out the process. |
SE9645/65A SE314358B (en) | 1964-07-21 | 1965-07-21 | |
DE19651567731 DE1567731B1 (en) | 1964-07-21 | 1965-07-21 | METHOD AND DEVICE FOR EXHAUST GAS TREATMENT IN CASE OF CONTINUOUS PHOSPHORIC ACID CONCENTRATION IN A SUBMERGED EVAPORATION PLANT |
FI175065A FI45038C (en) | 1964-07-21 | 1965-07-21 | Process for the treatment of gases leaving the evaporator during the production of phosphoric acids with a high P 2O5 content. |
NO15904265A NO115383B (en) | 1964-07-21 | 1965-07-21 | |
SE9644/65A SE312540B (en) | 1964-07-21 | 1965-07-21 | |
SE09643/65A SE327388B (en) | 1964-07-21 | 1965-07-21 | |
SE964265A SE313550B (en) | 1964-07-21 | 1965-07-21 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB2952064A GB1081891A (en) | 1964-07-21 | 1964-07-21 | Improvements relating to the production of phosphoric acids |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1081891A true GB1081891A (en) | 1967-09-06 |
Family
ID=10292840
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB2952064A Expired GB1081891A (en) | 1964-07-21 | 1964-07-21 | Improvements relating to the production of phosphoric acids |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB1081891A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4215098A (en) | 1978-04-26 | 1980-07-29 | Albright & Wilson Limited | Purification of wet process phosphoric acid |
CN110155976A (en) * | 2019-04-11 | 2019-08-23 | 贵州开磷集团矿肥有限责任公司 | A method of reducing wet phosphoric acid extracting bath liquid level protection top erosion resistant coating |
-
1964
- 1964-07-21 GB GB2952064A patent/GB1081891A/en not_active Expired
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4215098A (en) | 1978-04-26 | 1980-07-29 | Albright & Wilson Limited | Purification of wet process phosphoric acid |
CN110155976A (en) * | 2019-04-11 | 2019-08-23 | 贵州开磷集团矿肥有限责任公司 | A method of reducing wet phosphoric acid extracting bath liquid level protection top erosion resistant coating |
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