GB1079410A - Process for preparing bismuth subnitrate - Google Patents
Process for preparing bismuth subnitrateInfo
- Publication number
- GB1079410A GB1079410A GB2922066A GB2922066A GB1079410A GB 1079410 A GB1079410 A GB 1079410A GB 2922066 A GB2922066 A GB 2922066A GB 2922066 A GB2922066 A GB 2922066A GB 1079410 A GB1079410 A GB 1079410A
- Authority
- GB
- United Kingdom
- Prior art keywords
- anode
- subnitrate
- nitrate
- bio
- electrolyte
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G29/00—Compounds of bismuth
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
- Electrolytic Production Of Metals (AREA)
Abstract
Bismuth subnitrate 5 (BiO.NO3).BiO.OH.4H2O is prepared by electrolysing an aqueous solution of an inorganic nitrate, e.g. 10-40% by weight of an alkali metal or ammonium nitrate, maintained at a pH in the range 1 to 7 by adding HNO3 using a Bi anode and recovering the subnitrate deposited at the anode; the cathode may be of stainless steel. The process may be operated continuously, the subnitrate precipitated from the anode being withdrawn in a stream of electrolyte from the electrolysis vessel, and after filtering recycling the electrolyte, regenerated and heated if necessary, to the vessel. A prior process is disclosed using an electrolytic cell having a Bi anode, Ni cathode, and separate NaNO3 anolyte and NaOH catholyte, wherein bismuthyl nitrate is electrolytically formed.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
NL6508499A NL6508499A (en) | 1965-07-01 | 1965-07-01 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1079410A true GB1079410A (en) | 1967-08-16 |
Family
ID=19793540
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB2922066A Expired GB1079410A (en) | 1965-07-01 | 1966-06-29 | Process for preparing bismuth subnitrate |
Country Status (3)
Country | Link |
---|---|
DE (1) | DE1592217C3 (en) |
GB (1) | GB1079410A (en) |
NL (2) | NL6508499A (en) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1298634C (en) * | 2004-07-22 | 2007-02-07 | 中国地质大学(武汉) | Process for preparing nano alkaline bismuth nitrate by micro emulsion |
-
0
- NL NL130170D patent/NL130170C/xx active
-
1965
- 1965-07-01 NL NL6508499A patent/NL6508499A/xx unknown
-
1966
- 1966-06-29 GB GB2922066A patent/GB1079410A/en not_active Expired
- 1966-06-30 DE DE19661592217 patent/DE1592217C3/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
DE1592217C3 (en) | 1974-11-07 |
NL130170C (en) | |
NL6508499A (en) | 1967-01-02 |
DE1592217A1 (en) | 1970-07-16 |
DE1592217B2 (en) | 1971-01-21 |
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