GB1079410A - Process for preparing bismuth subnitrate - Google Patents

Process for preparing bismuth subnitrate

Info

Publication number
GB1079410A
GB1079410A GB2922066A GB2922066A GB1079410A GB 1079410 A GB1079410 A GB 1079410A GB 2922066 A GB2922066 A GB 2922066A GB 2922066 A GB2922066 A GB 2922066A GB 1079410 A GB1079410 A GB 1079410A
Authority
GB
United Kingdom
Prior art keywords
anode
subnitrate
nitrate
bio
electrolyte
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2922066A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of GB1079410A publication Critical patent/GB1079410A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00Electrolytic production of inorganic compounds or non-metals
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G29/00Compounds of bismuth

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
  • Electrolytic Production Of Metals (AREA)

Abstract

Bismuth subnitrate 5 (BiO.NO3).BiO.OH.4H2O is prepared by electrolysing an aqueous solution of an inorganic nitrate, e.g. 10-40% by weight of an alkali metal or ammonium nitrate, maintained at a pH in the range 1 to 7 by adding HNO3 using a Bi anode and recovering the subnitrate deposited at the anode; the cathode may be of stainless steel. The process may be operated continuously, the subnitrate precipitated from the anode being withdrawn in a stream of electrolyte from the electrolysis vessel, and after filtering recycling the electrolyte, regenerated and heated if necessary, to the vessel. A prior process is disclosed using an electrolytic cell having a Bi anode, Ni cathode, and separate NaNO3 anolyte and NaOH catholyte, wherein bismuthyl nitrate is electrolytically formed.
GB2922066A 1965-07-01 1966-06-29 Process for preparing bismuth subnitrate Expired GB1079410A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
NL6508499A NL6508499A (en) 1965-07-01 1965-07-01

Publications (1)

Publication Number Publication Date
GB1079410A true GB1079410A (en) 1967-08-16

Family

ID=19793540

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2922066A Expired GB1079410A (en) 1965-07-01 1966-06-29 Process for preparing bismuth subnitrate

Country Status (3)

Country Link
DE (1) DE1592217C3 (en)
GB (1) GB1079410A (en)
NL (2) NL6508499A (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1298634C (en) * 2004-07-22 2007-02-07 中国地质大学(武汉) Process for preparing nano alkaline bismuth nitrate by micro emulsion

Also Published As

Publication number Publication date
DE1592217C3 (en) 1974-11-07
NL130170C (en)
NL6508499A (en) 1967-01-02
DE1592217A1 (en) 1970-07-16
DE1592217B2 (en) 1971-01-21

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