GB1079225A - Extrudable polyolefin compositions containing organic acid salts of metals - Google Patents

Extrudable polyolefin compositions containing organic acid salts of metals

Info

Publication number
GB1079225A
GB1079225A GB5185364A GB5185364A GB1079225A GB 1079225 A GB1079225 A GB 1079225A GB 5185364 A GB5185364 A GB 5185364A GB 5185364 A GB5185364 A GB 5185364A GB 1079225 A GB1079225 A GB 1079225A
Authority
GB
United Kingdom
Prior art keywords
acetate
copolymer
nickel acetate
polyacrylic acid
organic acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB5185364A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Montedison SpA
Original Assignee
Montecatini Societa Generale per lIndustria Mineraria e Chimica SpA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Montecatini Societa Generale per lIndustria Mineraria e Chimica SpA filed Critical Montecatini Societa Generale per lIndustria Mineraria e Chimica SpA
Publication of GB1079225A publication Critical patent/GB1079225A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F22/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides or nitriles thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/62—Monocarboxylic acids having ten or more carbon atoms; Derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/44—Preparation of metal salts or ammonium salts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/02—Homopolymers or copolymers of acids; Metal or ammonium salts thereof
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/44—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds
    • D01F6/46—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds of polyolefins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C08L23/12—Polypropene

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Artificial Filaments (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Multicomponent Fibers (AREA)
  • Coloring (AREA)

Abstract

An extrudable mixture comprises a crystalline polyolefin and from 0.1 to 10% by weight of a compound of a metal of Group IIIb, IVa or VIII of the Periodic Table according to Mendeleef, and a homopolymer of an unsaturated organic acid or a copolymer of an unsaturated organic acid with an unsaturated ester. In the examples, polyethylene is blended with polyacrylic acid and nickel acetate, and polypropylene is blended with (1) a vinyl acetate/crotonic acid copolymer and nickel acetate, (2) polyacrylic acid and nickel acetate, (3) a partially saponified polymethylmethacrylate and nickel acetate, (4) a vinyl acetate/crotonic acid copolymer and cobalt acetate, or (5) a partially saponified polyacrylic acid and (A) cobalt acetate, (B) aluminium sulphate or (C) titanium trichloride. The vinyl acetate/crotonic acid copolymer is prepared by copolymerization of the monomers in aqueous emulsion in the presence of potassium persulphate, sodium bisulphite and lauryl mercaptan, and produces a copolymer with an intrinsic viscosity of 0.40. The mixtures are extruded to produce textile fibres, films, tapes and other shaped articles. The shaped articles are then dyed (see Division D1).ALSO:Dyeable shaped articles, such as textile fibres, films and tapes, are extruded from a mixture comprising a crystalline polyolefin and from 0.1 to 10% by weight of a compound of a metal of group IIIB, IVA or VIII of the Periodic Table according to Mendeleef, and a homopolymer of an unsaturated organic acid or a copolymer of an unsaturated organic acid with an unsaturated ester. In the examples, polyethylene is blended with polyacrylic acid and nickel acetate, and polypropylene is blended with 1) a vinyl acetate/crotonic acid copolymer and nickel acetate, 2) polyacrylic acid and nickel acetate, 3) a partially saponified polymethylmethacrylate and nickel acetate, 4) a vinyl acetate/crotonic acid copolymer and cobalt acetate, or 5) a partially saponified polyacrylic acid and A) titanium trichloride, B) cobalt acetate or C) aluminium sulphate. Fibres spun from the mixture of the invention are dyed with olefin, naprolene and Mayfon class dyestuffs, and disperse dyestuffs, many of which are exemplified.
GB5185364A 1963-12-31 1964-12-21 Extrudable polyolefin compositions containing organic acid salts of metals Expired GB1079225A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
IT2668663 1963-12-31
IT2668763 1963-12-31

Publications (1)

Publication Number Publication Date
GB1079225A true GB1079225A (en) 1967-08-16

Family

ID=26328689

Family Applications (2)

Application Number Title Priority Date Filing Date
GB5185264A Expired GB1115301A (en) 1963-12-31 1964-12-21 Extrudable polyolefin compositions
GB5185364A Expired GB1079225A (en) 1963-12-31 1964-12-21 Extrudable polyolefin compositions containing organic acid salts of metals

Family Applications Before (1)

Application Number Title Priority Date Filing Date
GB5185264A Expired GB1115301A (en) 1963-12-31 1964-12-21 Extrudable polyolefin compositions

Country Status (4)

Country Link
DE (2) DE1282846B (en)
GB (2) GB1115301A (en)
NL (2) NL6414527A (en)
SE (2) SE330951B (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104473897B (en) * 2014-11-27 2017-09-26 天津坤健生物制药有限公司 A kind of preparation method of 2-ethylisonicotinthionamide tablet

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE598061A (en) * 1959-12-10 1900-01-01
BE639135A (en) * 1962-05-24 1964-04-24
JPH0248963A (en) * 1988-05-02 1990-02-19 Canon Inc Recording device, thermal transfer printing device and recording method

Also Published As

Publication number Publication date
SE330950B (en) 1970-12-07
NL6414527A (en) 1965-07-02
GB1115301A (en) 1968-05-29
SE330951B (en) 1970-12-07
DE1282846B (en) 1969-02-20
NL6414528A (en) 1965-07-02
DE1289243B (en) 1969-02-13

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