GB1078870A - Process for the production of shaped articles from vinyl chloride polymer-ethylenically unsaturated monomer compositions - Google Patents

Process for the production of shaped articles from vinyl chloride polymer-ethylenically unsaturated monomer compositions

Info

Publication number
GB1078870A
GB1078870A GB28234/66A GB2823466A GB1078870A GB 1078870 A GB1078870 A GB 1078870A GB 28234/66 A GB28234/66 A GB 28234/66A GB 2823466 A GB2823466 A GB 2823466A GB 1078870 A GB1078870 A GB 1078870A
Authority
GB
United Kingdom
Prior art keywords
vinyl chloride
tert
methyl
chloride polymer
ethylenically unsaturated
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB28234/66A
Inventor
Clifford Francis Thompson
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Chemical Co
Original Assignee
Dow Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to CA808724A priority Critical patent/CA808724A/en
Application filed by Dow Chemical Co filed Critical Dow Chemical Co
Priority to GB28234/66A priority patent/GB1078870A/en
Priority to DE19661595513 priority patent/DE1595513A1/en
Priority to NL6609073A priority patent/NL6609073A/xx
Publication of GB1078870A publication Critical patent/GB1078870A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F259/00—Macromolecular compounds obtained by polymerising monomers on to polymers of halogen containing monomers as defined in group C08F14/00
    • C08F259/02—Macromolecular compounds obtained by polymerising monomers on to polymers of halogen containing monomers as defined in group C08F14/00 on to polymers containing chlorine
    • C08F259/04—Macromolecular compounds obtained by polymerising monomers on to polymers of halogen containing monomers as defined in group C08F14/00 on to polymers containing chlorine on to polymers of vinyl chloride

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Graft Or Block Polymers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

Graft polymers are obtained by dispersing a vinyl chloride polymer in an ethylenically unsaturated monomer and polymerizing the mixture in the presence of an organic peroxide catalyst and a stannous salt of an organic acid. The vinyl chloride polymer can be a homopolymer or a copolymer containing up to 15% by weight of vinyl acetate or propionate, methyl or butyl acrylate, methyl or lauryl methacrylate or vinylidene chloride and is preferably of plastisol grade particles. The monomer may be styrene or an alkyl and/or halogen derivative or a mixture thereof with an ester of fumaric or acrylic or methacrylic acid. Specified peroxides are ditert butyl and dicumyl peroxides, 1,4-bis(tert.-butyl peroxy methyl) durene, 2,5-dimethyl - 2,5 - di - (tert.-butyl peroxy)-hexane or -hexyne-3, and 2,2-bis-(tert.-butyl peroxy)-butane and specified stannous salts are naphthenate, octoate, caproate, and laurate. Reaction is effected at 120-180 DEG C. at which temperature the polymer is solvated. Pigments, stabilizers, dyes, antioxidants and inhibitors may be present, or materials to be impregnated, e.g. cloth, wood fibres, cotton linters, glass fibres, glass cloth, or paper.
GB28234/66A 1966-06-23 1966-06-23 Process for the production of shaped articles from vinyl chloride polymer-ethylenically unsaturated monomer compositions Expired GB1078870A (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
CA808724A CA808724A (en) 1966-06-23 Method and catalysts for converting vinyl chloride polymer monomer compositions to polymeric products
GB28234/66A GB1078870A (en) 1966-06-23 1966-06-23 Process for the production of shaped articles from vinyl chloride polymer-ethylenically unsaturated monomer compositions
DE19661595513 DE1595513A1 (en) 1966-06-23 1966-06-28 Process for the production of shaped articles from compositions of vinyl chloride polymer and ethylenically unsaturated monomers
NL6609073A NL6609073A (en) 1966-06-23 1966-06-29

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
CA808724T
GB28234/66A GB1078870A (en) 1966-06-23 1966-06-23 Process for the production of shaped articles from vinyl chloride polymer-ethylenically unsaturated monomer compositions
DED0050418 1966-06-28
NL6609073A NL6609073A (en) 1966-06-23 1966-06-29

Publications (1)

Publication Number Publication Date
GB1078870A true GB1078870A (en) 1967-08-09

Family

ID=60922785

Family Applications (1)

Application Number Title Priority Date Filing Date
GB28234/66A Expired GB1078870A (en) 1966-06-23 1966-06-23 Process for the production of shaped articles from vinyl chloride polymer-ethylenically unsaturated monomer compositions

Country Status (4)

Country Link
CA (1) CA808724A (en)
DE (1) DE1595513A1 (en)
GB (1) GB1078870A (en)
NL (1) NL6609073A (en)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0021703A1 (en) * 1979-06-11 1981-01-07 Union Carbide Corporation Radiation curable dispersions containing high molecular weight nonpolymerizable vinyl resins
FR2471988A1 (en) * 1979-12-21 1981-06-26 Dart Ind Inc CATALYSTS AND PROCESS FOR THE PREPARATION OF POLYMERS AND COPOLYMERS OF ETHYLENICALLY UNSATURATED MONOMERS
WO2002059171A2 (en) * 2001-01-26 2002-08-01 The University Of Pennsylvania Living radical graft copolymerization of vinyl monomers initiated from the structural defects of polyvinylchloride
US6838535B2 (en) 2001-03-23 2005-01-04 University Of Pennsylvania Process for the living radical polymerization of chlorine containing monomers
US7026420B2 (en) 2001-03-23 2006-04-11 University Of Pennsylvania Aqueous room temperature living radical polymerization of vinyl halides
US7345127B2 (en) 2001-03-23 2008-03-18 University Of Pennsylvania Living radical polymerization of halogen-containing and acrylic monomers and the formation of block copolymers therefrom
WO2019180734A1 (en) * 2018-03-20 2019-09-26 Hindustan Petroleum Corporation Limited Hydrocarbon-soluble formulation for thermal cracking process

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2520028B2 (en) * 1975-05-06 1980-01-24 Chemische Fabrik Stockhausen & Cie, 4150 Krefeld Water-in-oil dispersions of Mannich bases of polyacrylamide or its copolymers and their use as flocculants, sedimentation, drainage and retention aids

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0021703A1 (en) * 1979-06-11 1981-01-07 Union Carbide Corporation Radiation curable dispersions containing high molecular weight nonpolymerizable vinyl resins
FR2471988A1 (en) * 1979-12-21 1981-06-26 Dart Ind Inc CATALYSTS AND PROCESS FOR THE PREPARATION OF POLYMERS AND COPOLYMERS OF ETHYLENICALLY UNSATURATED MONOMERS
WO2002059171A2 (en) * 2001-01-26 2002-08-01 The University Of Pennsylvania Living radical graft copolymerization of vinyl monomers initiated from the structural defects of polyvinylchloride
WO2002059171A3 (en) * 2001-01-26 2003-08-21 Univ Pennsylvania Living radical graft copolymerization of vinyl monomers initiated from the structural defects of polyvinylchloride
US6838535B2 (en) 2001-03-23 2005-01-04 University Of Pennsylvania Process for the living radical polymerization of chlorine containing monomers
US7026420B2 (en) 2001-03-23 2006-04-11 University Of Pennsylvania Aqueous room temperature living radical polymerization of vinyl halides
US7345127B2 (en) 2001-03-23 2008-03-18 University Of Pennsylvania Living radical polymerization of halogen-containing and acrylic monomers and the formation of block copolymers therefrom
US7470762B2 (en) 2001-03-23 2008-12-30 University Of Pennsylvania Living radical polymerization of acrylic monomers and the formation of block copolymers therefrom
WO2019180734A1 (en) * 2018-03-20 2019-09-26 Hindustan Petroleum Corporation Limited Hydrocarbon-soluble formulation for thermal cracking process

Also Published As

Publication number Publication date
DE1595513A1 (en) 1970-04-30
NL6609073A (en) 1968-01-02
CA808724A (en) 1969-03-18

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