GB1071795A - Cross-linked interpolymer latex and compositions comprising the same - Google Patents

Cross-linked interpolymer latex and compositions comprising the same

Info

Publication number
GB1071795A
GB1071795A GB36008/64A GB3600864A GB1071795A GB 1071795 A GB1071795 A GB 1071795A GB 36008/64 A GB36008/64 A GB 36008/64A GB 3600864 A GB3600864 A GB 3600864A GB 1071795 A GB1071795 A GB 1071795A
Authority
GB
United Kingdom
Prior art keywords
parts
styrene
latex
terpolymer
sodium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB36008/64A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Morton Salt Co
Original Assignee
Morton Salt Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US329873A external-priority patent/US3340217A/en
Application filed by Morton Salt Co filed Critical Morton Salt Co
Publication of GB1071795A publication Critical patent/GB1071795A/en
Expired legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/227—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated
    • D06M15/233—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated aromatic, e.g. styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/02—Monomers containing only one unsaturated aliphatic radical
    • C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F212/06—Hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F22/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides or nitriles thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
    • C11D3/3761—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in solid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
    • C11D3/3765—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in liquid compositions
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
    • C08F220/32—Esters containing oxygen in addition to the carboxy oxygen containing epoxy radicals
    • C08F220/325—Esters containing oxygen in addition to the carboxy oxygen containing epoxy radicals containing glycidyl radical, e.g. glycidyl (meth)acrylate

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Textile Engineering (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Detergent Compositions (AREA)

Abstract

A stabilized opacified detergent composition comprises 100 parts of a surface active agent and 0.2-14 parts (based on the polymer solids) of a cross-linked terpolymer latex which comprises 78-96 parts of styrene or a methylated styrene, 1-20 parts of acrylic, methacrylic or itaconic acids, 1-20 parts of glycidyl acrylate or methacrylate and up to two parts of divinylbenzene (per 100 parts of terpolymer). The composition may contain 3.6-83 parts of an alcohol (per 100 parts of surface active agent). The surface active agent may be sodium dodecyl sulphonate, alkali salts of complex organic phosphate esters, alkyl aryl sulphonates, sodium lauryl (ether sulphates or sulphate), octyl and nonyl phenoxy polyethylenoxy ethanols, polyoxyalkylene ethanols, polyoxyethylene sorbitan fatty acids or fatty acid alkanolamides. In examples opacified liquid detergents comprised (1) nonyl phenol polyethyleneoxyethanol, lauric diethanolamine, sodium alkyl aryl sulphonate, ethyl alcohol, water, dilute H2SO4 to adjust the pH to 7 and the above terpolymer latex; (2) ethyl or isopropyl alcohol, the ammonium salt of the sulphate ester of an alkylphenoxypolyethylenoxy-ethanol, lauric diethanolamide, an alkyl aryl sulphonate, water, dilute H2SO4 to adjust the pH to from 6.5 to 7.5, the above terpolymer latex and optionally nonylphenoxy polyethylenoxy-ethanol; and (3) ethyl alcohol, sodium xylene sulphonate, octyl phenoxy polyethylenoxy-ethanol, lauric diethanolamide, an alkyl aryl sulphonate, water, H2SO4 as in (2) and the above terpolymer latex.ALSO:A cross-linked terpolymer latex comprises 78-96 parts of styrene or a methylated styrene (e.g. vinyl toluene), 1-20 parts of acrylic, methacrylic or itaconic acids, 1-20 parts of glycidyl acrylcate or methacrylate and up to two parts of divinylbenzene (per 100 parts terpolymer). The latex is resistant to coagulation by methanol and may have an average particle size of less than 0.5 micron. The latex may be prepared by adding to an aqueous solution of sodium bicarbonate (as buffer) and the ammonium salt of the sulphate ester of an alkylphenoxypoly(ethyleneoxy)ethanol a catalyst, e.g. ammonium persulphate, and then a first monomer fraction consisting of a major portion of the styrene and the unsaturated acid and all of the divinylbenzene which is then polymerized and followed by a second fraction consisting of the remainder of the styrene unsaturated acid and the glycidyl monomer. The terpolymer may be neutralized, e.g. with diethanolamine or sodium hydroxide.
GB36008/64A 1963-12-11 1964-09-02 Cross-linked interpolymer latex and compositions comprising the same Expired GB1071795A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US329873A US3340217A (en) 1963-12-11 1963-12-11 Crosslinked interpolymer latex of styrene, an unsaturated carboxylic acid, an unsaturated glycidyl compound and divinyl-benzene
US635280A US3382177A (en) 1963-12-11 1967-03-09 Stabilized opaque detergent composition

Publications (1)

Publication Number Publication Date
GB1071795A true GB1071795A (en) 1967-06-14

Family

ID=26987017

Family Applications (1)

Application Number Title Priority Date Filing Date
GB36008/64A Expired GB1071795A (en) 1963-12-11 1964-09-02 Cross-linked interpolymer latex and compositions comprising the same

Country Status (8)

Country Link
US (1) US3382177A (en)
BE (1) BE652923A (en)
DE (1) DE1570897A1 (en)
FR (1) FR1416414A (en)
GB (1) GB1071795A (en)
LU (1) LU46898A1 (en)
NL (2) NL6410258A (en)
SE (2) SE320194B (en)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1617119A1 (en) * 1966-11-18 1971-02-18 Henkel & Cie Gmbh Low-foaming stain treatment agent for textiles
US4746455A (en) * 1986-06-27 1988-05-24 Kao Corporation Liquid detergent composition for clothing articles
US6869028B2 (en) 2000-06-14 2005-03-22 The Procter & Gamble Company Spraying device
US7381279B2 (en) * 2000-06-14 2008-06-03 The Procter & Gamble Company Article for deionization of water
US7264678B2 (en) * 2000-06-14 2007-09-04 The Procter & Gamble Company Process for cleaning a surface

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3060124A (en) * 1956-12-28 1962-10-23 Monsanto Chemicals Liquid detergent gel compositions having stability against separation
US3156655A (en) * 1960-08-02 1964-11-10 Lever Brothers Ltd Heavy duty liquid detergent composition
US3235505A (en) * 1961-09-20 1966-02-15 Monsanto Co Detergent processes
BE632186A (en) * 1962-05-11

Also Published As

Publication number Publication date
SE323761B (en) 1970-05-11
NL6410258A (en) 1965-06-14
LU46898A1 (en) 1965-03-08
NL131012C (en)
BE652923A (en) 1965-03-10
FR1416414A (en) 1965-11-05
SE320194B (en) 1970-02-02
US3382177A (en) 1968-05-07
DE1570897A1 (en) 1970-04-30

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