GB1066458A - Unsaturated sulphonic acids and salts thereof - Google Patents

Unsaturated sulphonic acids and salts thereof

Info

Publication number
GB1066458A
GB1066458A GB33497/64A GB3349764A GB1066458A GB 1066458 A GB1066458 A GB 1066458A GB 33497/64 A GB33497/64 A GB 33497/64A GB 3349764 A GB3349764 A GB 3349764A GB 1066458 A GB1066458 A GB 1066458A
Authority
GB
United Kingdom
Prior art keywords
salts
sulphonic acids
formula
acids
valence
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB33497/64A
Inventor
George Leon Broussalian
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Monsanto Co
Original Assignee
Monsanto Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Monsanto Co filed Critical Monsanto Co
Publication of GB1066458A publication Critical patent/GB1066458A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C11D1/143—Sulfonic acid esters

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Detergent Compositions (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Detergent compositions, particularly washing-up and laundry compositions, comprise unsaturated sulphonic acids and salts of formula <FORM:1066458/C4-C5/1> where R and R1 are each H or a C1-21 hydrophobic organic group which may contain substituents, the arithmetic sum of the number of carbon atoms in R plus R1 being 7 to 21, M is H, NH4 or an alkali or alkaline earth metal, including Mg, and x is the valence of M. The usual anionic, nonionic or ampholytic surfactants, builders, anti-redeposition agents, optical brighteners and bleaching agents may be present.ALSO:The invention comprises unsaturated sulphonic acids and salts of formula <FORM:1066458/C2/1> where R and R1 are each H or a C1- 21 hydrophobic organic group, the arithmetic sum of the number of carbon atoms in R plus R1 being 7 to 21, M is H, NH4 or an alkali or alkaline earth metal, including Mg, and x is the valence of M. The sulphonic acids are preferably prepared by reacting an olefinic compound of formula R-CH2-CH = CHR1, preferably dissolved in a neutral, anhydrous solvent, with SO3 or a complex of SO3 with a nitrogen-free organic substance at a temperature below 15 DEG C., and decomposing the resulting sultone by warming above 15 DEG C., preferably in the presence of a Lewis base solvent. Alternatively R-CH = CH-CHBrR1 may be reacted with a bisulphite. The salts are prepared by neutralizing the acids.
GB33497/64A 1963-08-15 1964-08-17 Unsaturated sulphonic acids and salts thereof Expired GB1066458A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US302440A US3346629A (en) 1963-08-15 1963-08-15 Process for preparing beta-ethylenically unsaturated organic sulfonates

Publications (1)

Publication Number Publication Date
GB1066458A true GB1066458A (en) 1967-04-26

Family

ID=23167740

Family Applications (1)

Application Number Title Priority Date Filing Date
GB33497/64A Expired GB1066458A (en) 1963-08-15 1964-08-17 Unsaturated sulphonic acids and salts thereof

Country Status (8)

Country Link
US (1) US3346629A (en)
AU (1) AU403871B2 (en)
BE (1) BE651783A (en)
DE (1) DE1299791B (en)
FR (1) FR1411808A (en)
GB (1) GB1066458A (en)
LU (1) LU46754A1 (en)
NL (1) NL6409378A (en)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA787878A (en) * 1965-01-04 1968-06-18 F. Pflaumer Phillip Detergent composition
US3332877A (en) * 1965-01-04 1967-07-25 Procter & Gamble Detergent composition
US3332880A (en) * 1965-01-04 1967-07-25 Procter & Gamble Detergent composition
GB1171617A (en) * 1966-03-18 1969-11-26 Unilever Ltd Toilet Bar
US3487104A (en) * 1966-04-28 1969-12-30 Gulf Research Development Co Process for preparing alkene sulfonates
US3462525A (en) * 1966-09-15 1969-08-19 Colgate Palmolive Co Dental compositions comprising long-chain olefin sulfonates
US3332878A (en) * 1966-12-05 1967-07-25 Procter & Gamble Detergent composition having synergistic sudsing properties containing amides and sulfonate-containing detergents
US3332879A (en) * 1966-12-05 1967-07-25 Procter & Gamble Ternary synergistic sudsing detergent compositions
US3565809A (en) * 1967-11-27 1971-02-23 Chevron Res Alpha olefin sulfonate detergent compositions
US3637512A (en) * 1968-07-22 1972-01-25 Continental Oil Co Hydrocarbon solvent composition
US3676372A (en) * 1968-10-24 1972-07-11 Chevron Res Hydrogenated olefin sulfonate-fatty acid amide detergent compositions
US3819519A (en) * 1968-11-27 1974-06-25 Chevron Res Foam circulation fluids
US3673122A (en) * 1969-03-27 1972-06-27 Chevron Res Hydrogenated olefin sulfonate detergent bars
GB8900023D0 (en) * 1989-01-03 1989-03-01 Shell Int Research Detergent composition
JP6224390B2 (en) 2012-09-20 2017-11-01 花王株式会社 Internal olefin sulfonate composition and detergent composition containing the same
US9622952B2 (en) 2013-02-13 2017-04-18 Kao Corporation Internal olefin sulfonate composition

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2240920A (en) * 1941-05-06 Sulphonation of organic compounds
US2303212A (en) * 1939-05-26 1942-11-24 Solvay Process Co Soap composition
US2243331A (en) * 1939-08-29 1941-05-27 Shell Dev Sulphonate
US2337552A (en) * 1940-08-15 1943-12-28 Du Pont Purification of saturated hydrocarbon sulphonic acids
DE899939C (en) * 1943-03-04 1953-12-17 Boehme Fettchemie G M B H Process for the production of chlorinated or brominated sultones
US2789133A (en) * 1954-07-13 1957-04-16 Rohm & Haas Alkoxypentenyl sulfonates
US2894912A (en) * 1954-09-21 1959-07-14 Lever Brothers Ltd Isethionate detergent bar
US2807642A (en) * 1954-12-31 1957-09-24 Universal Oil Prod Co Method of sulfonation to produce inorganic salt-free product
FR1307710A (en) * 1960-12-09 1962-10-26 Hoechst Ag Process for the preparation of beta-hydroxy-alpha-sulfonic acid anhydrides and their derivatives

Also Published As

Publication number Publication date
AU403871B2 (en) 1970-06-25
US3346629A (en) 1967-10-10
NL6409378A (en) 1965-02-16
LU46754A1 (en) 1965-02-12
DE1299791B (en) 1969-07-24
AU4811064A (en) 1966-02-17
BE651783A (en) 1965-02-15
FR1411808A (en) 1965-09-24

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