GB1065767A - Process for preparing carbodiimides - Google Patents
Process for preparing carbodiimidesInfo
- Publication number
- GB1065767A GB1065767A GB40496/63A GB4049663A GB1065767A GB 1065767 A GB1065767 A GB 1065767A GB 40496/63 A GB40496/63 A GB 40496/63A GB 4049663 A GB4049663 A GB 4049663A GB 1065767 A GB1065767 A GB 1065767A
- Authority
- GB
- United Kingdom
- Prior art keywords
- atoms
- carbon atoms
- isothiourea
- alkyl
- aryl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C267/00—Carbodiimides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
- C07C2601/14—The ring being saturated
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Carbodiimides are prepared by thermally decomposing N,N1 - disubstituted S - alkyl-isothioureas of the formula <FORM:1065767/C2/1> or <FORM:1065767/C2/2> wherein R and R1 each represents primary, secondary or tertiary alkyl, cycloalkyl, aralkyl, or aryl, R and R1 being so chosen that not more than one represents aryl, and the total number of hydrogen atoms attached to the two carbon atoms linked directly to the nitrogen atoms of the isothiourea group is not greater than 2 or not greater than 1 when one of R and R1 is aryl, R111 represents cycloalkyl or primary, secondary or tertiary alkyl, R11 represents an aliphatic or cycloaliphatic hydrocarbon chain containing at least 3 carbon atoms and optionally interrupted by oxygen atoms, sulphur atoms or nitrogen-free hetero groups separated from the nearest isothiourea groups by at least 2 carbon atoms, R11 and R111 being so selected that a total of at most 2 hydrogen atoms are attached to the 2 carbon atoms linked directly to the nitrogen atoms of each isothiourea group, and n represents a positive integer, preferably 1. The thermal decomposition may be carried out in the presence of a high-boiling inert organic solvent, and the crude reaction product obtained may be purified by a treatment with active aluminium oxide. A suitable substituted S-alkyl isothiourea starting material is prepared by reacting ethylene glycol - bis - (gamma - aminopropylether) with tertiary - butyl mustard oil, followed by S-methylation of the product with dimethyl sulphate.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEF38041A DE1173460B (en) | 1962-10-13 | 1962-10-13 | Process for the preparation of carbodiimides |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1065767A true GB1065767A (en) | 1967-04-19 |
Family
ID=7097191
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB40496/63A Expired GB1065767A (en) | 1962-10-13 | 1963-10-14 | Process for preparing carbodiimides |
Country Status (5)
Country | Link |
---|---|
AT (1) | AT246114B (en) |
BE (1) | BE638620A (en) |
CH (1) | CH427778A (en) |
DE (1) | DE1173460B (en) |
GB (1) | GB1065767A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2017172313A1 (en) * | 2016-03-31 | 2017-10-05 | Dow Global Technologies Llc | Biscarbodiimides and polycarbodiimides and method for their preparation |
-
0
- BE BE638620D patent/BE638620A/xx unknown
-
1962
- 1962-10-13 DE DEF38041A patent/DE1173460B/en active Pending
-
1963
- 1963-10-10 CH CH1243563A patent/CH427778A/en unknown
- 1963-10-11 AT AT816263A patent/AT246114B/en active
- 1963-10-14 GB GB40496/63A patent/GB1065767A/en not_active Expired
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2017172313A1 (en) * | 2016-03-31 | 2017-10-05 | Dow Global Technologies Llc | Biscarbodiimides and polycarbodiimides and method for their preparation |
CN108884025A (en) * | 2016-03-31 | 2018-11-23 | 陶氏环球技术有限责任公司 | Dual-carbodiimide and poly- carbodiimide and preparation method thereof |
KR20180132677A (en) * | 2016-03-31 | 2018-12-12 | 다우 글로벌 테크놀로지스 엘엘씨 | Biscarbodiimide and polycarbodiimide and a process for their preparation |
US11104641B2 (en) | 2016-03-31 | 2021-08-31 | Dow Global Technologies Llc | Biscarbodiimides and polycarbodiimides and method for their preparation |
KR102488760B1 (en) | 2016-03-31 | 2023-01-16 | 다우 글로벌 테크놀로지스 엘엘씨 | Biscarbodiimide and polycarbodiimide and method for their preparation |
Also Published As
Publication number | Publication date |
---|---|
CH427778A (en) | 1967-01-15 |
BE638620A (en) | |
DE1173460B (en) | 1964-07-09 |
AT246114B (en) | 1966-04-12 |
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