GB1064116A - Ultra-violet absorbing compositions - Google Patents
Ultra-violet absorbing compositionsInfo
- Publication number
- GB1064116A GB1064116A GB13124/63A GB1312463A GB1064116A GB 1064116 A GB1064116 A GB 1064116A GB 13124/63 A GB13124/63 A GB 13124/63A GB 1312463 A GB1312463 A GB 1312463A GB 1064116 A GB1064116 A GB 1064116A
- Authority
- GB
- United Kingdom
- Prior art keywords
- group
- alkyl
- hydrogen
- represent
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Dermatology (AREA)
- Cosmetics (AREA)
Abstract
The invention comprises compounds of the general formula <FORM:1064116/C2/1> wherein W represents hydrogen or a COZ group; Y and Z, which may be the same or different, each represent an OR3 group, where R3 represents hydrogen or an alkyl or alkoxy alkyl group, or an OB group, where B represents a dermatologically acceptable cationic group; and R1 and R2, which may be the same or different, each represent hydrogen or an alkyl or aralkyl group, or together represent a straight or branched chain alkylene group, optionally interrupted by a hetero atom, the values of W, Y, R1 and R2 being chosen so that when <FORM:1064116/C2/2> is a NH2 group in the para position and W is hydrogen, then Y is not an ethoxy or butoxy group, and when R1 and R2 are both methyl and the group <FORM:1064116/C2/3> is in the para position, then W is not hydrogen when Y is a hydroxy, methoxy or ethoxy group and W is not a carbethoxy group when Y is an ethoxy group. The substituted malonates may be made by condensing an appropriate aminobenzaldehyde with an appropriate ester of malonic acid, for example by heating the reactants in solution in a mutual solvent in the presence of at least one condensation catalyst, for example piperidine. The ester may be hydrolysed and converted to the acid or salt. If the desired product contains a primary amino group, the group must be protected, for example, with an acetyl group, which is removed after the condensation. The substituted cinnamates may be made by condensing an aminobenzaldehyde with an ester of acetic acid in a mutual solvent, in the presence of a condensation catalyst, for example sodium metal or sodium hydride. If the acid is required, it may be obtained by hydrolysis of the ester, or alternatively by condensing an aminobenzaldehyde with malonic acid. The salt may be obtained from the acid. A primary amino group must be protected as above.ALSO:An ultra-violet absorbing composition for topical application comprising a dermatologically acceptable liquid or semi-liquid carrier having dissolved or dispersed therein a proportion of at least one compound of the general formula: <FORM:1064116/A5-A6/1> wherein W represents hydrogen or a COZ group; Y and Z, which may be the same or different, each represent an OR3 group, where R3 represents hydrogen or an alkyl or alkoxy-alkyl group, or an OB group, where B represents a dermatologically acceptable cationic group; and R1 and R2, which may be the same or different, each represent hydrogen or an alkyl or aralkyl group, or together represent a straight or branched chain alkylene group, optionally interrupted by a hetero atom, the resultant composition being such as to form on topical application a film or coating on the skin. The sunscreening compositions may take the form of cosmetic oils, alcoholic solutions, lotions, lipstick, ointments, creams and other emulsified products. The compositions may also contain at least one other dermatologically acceptable ultra-violet absorbing compound to enhance the total ultra-violet absorbing properties. Examples of second sunscreening compounds are isobutyl dimethylaminobenzoate, menthyl salicylate and alkoxyalkyl p-methoxycinnamates, preferably having four to six carbons in the alkoxyalkyl group.
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB13124/63A GB1064116A (en) | 1963-04-03 | 1963-04-03 | Ultra-violet absorbing compositions |
DE19641492274 DE1492274A1 (en) | 1963-04-03 | 1964-03-28 | Cosmetic creams and lotions for topical use and processes for the preparation of new compounds that can be used as protective substances against ultraviolet rays |
US356159A US3390051A (en) | 1963-04-03 | 1964-03-31 | Dialkylaminocinnamates and dialkylbenzalmalonates in ultraviolet absorbing compositios and methods |
CH427564A CH430056A (en) | 1963-04-03 | 1964-04-03 | Ultraviolet absorbing composition for local applications |
DK166464AA DK114645B (en) | 1963-04-03 | 1964-04-03 | Means for protecting the skin from ultra-violet radiation. |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB13124/63A GB1064116A (en) | 1963-04-03 | 1963-04-03 | Ultra-violet absorbing compositions |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1064116A true GB1064116A (en) | 1967-04-05 |
Family
ID=10017265
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB13124/63A Expired GB1064116A (en) | 1963-04-03 | 1963-04-03 | Ultra-violet absorbing compositions |
Country Status (5)
Country | Link |
---|---|
US (1) | US3390051A (en) |
CH (1) | CH430056A (en) |
DE (1) | DE1492274A1 (en) |
DK (1) | DK114645B (en) |
GB (1) | GB1064116A (en) |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0100651A1 (en) * | 1982-08-03 | 1984-02-15 | VAN DYK & COMPANY, INC. | Dialkyl malonates as organic suncreen adjuvants |
GB2155467A (en) * | 1984-02-14 | 1985-09-25 | Graesser Lab | Ultra-violet absorbing dimethylaminocinnamates and compositions containing said compounds |
US4726942A (en) * | 1983-02-03 | 1988-02-23 | L'oreal | Cosmetic composition for protection against ultraviolet radiation and its use for this purpose |
WO1988002251A1 (en) * | 1986-09-26 | 1988-04-07 | Ici Australia Operations Proprietary Limited | Sunscreen compositions and compounds for use therein |
US5000946A (en) * | 1986-09-26 | 1991-03-19 | Graham Bird | Sunscreen compositions and compounds for use therein |
EP0790243A1 (en) | 1996-02-12 | 1997-08-20 | L'oreal | Derivatives of s-triazine as UV filters |
WO2019022131A1 (en) * | 2017-07-26 | 2019-01-31 | 三井化学株式会社 | Polymerizable composition for optical material, optical material, and application for same |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3692819A (en) * | 1969-09-29 | 1972-09-19 | Ciba Geigy Corp | Tertiary aminoacids |
DE2155495A1 (en) * | 1971-11-09 | 1973-05-10 | Bayer Ag | METHOD FOR PREPARING BENZYLIDENE COMPOUNDS |
LU65622A1 (en) * | 1972-06-29 | 1974-01-04 | ||
DE2652034A1 (en) * | 1976-11-15 | 1978-05-24 | Basf Ag | LIGHT PROTECTION AGENTS |
US5237089A (en) * | 1986-02-07 | 1993-08-17 | Basf Aktiengesellschaft | Nitro or amino substituted phenylalkyl or phenylalkenyl carboxylic acid derivatives |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2798881A (en) * | 1954-11-12 | 1957-07-09 | Du Pont | 4-(aminoaryl)-1, 3-butadiene-2-carbonitriles and their preparation |
-
1963
- 1963-04-03 GB GB13124/63A patent/GB1064116A/en not_active Expired
-
1964
- 1964-03-28 DE DE19641492274 patent/DE1492274A1/en active Granted
- 1964-03-31 US US356159A patent/US3390051A/en not_active Expired - Lifetime
- 1964-04-03 CH CH427564A patent/CH430056A/en unknown
- 1964-04-03 DK DK166464AA patent/DK114645B/en unknown
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0100651A1 (en) * | 1982-08-03 | 1984-02-15 | VAN DYK & COMPANY, INC. | Dialkyl malonates as organic suncreen adjuvants |
US4726942A (en) * | 1983-02-03 | 1988-02-23 | L'oreal | Cosmetic composition for protection against ultraviolet radiation and its use for this purpose |
GB2155467A (en) * | 1984-02-14 | 1985-09-25 | Graesser Lab | Ultra-violet absorbing dimethylaminocinnamates and compositions containing said compounds |
US4592906A (en) * | 1984-02-14 | 1986-06-03 | Graesser Laboratories, Ltd. | Ultra-violet absorbing compounds and compositions containing said compounds |
WO1988002251A1 (en) * | 1986-09-26 | 1988-04-07 | Ici Australia Operations Proprietary Limited | Sunscreen compositions and compounds for use therein |
US5000946A (en) * | 1986-09-26 | 1991-03-19 | Graham Bird | Sunscreen compositions and compounds for use therein |
EP0790243A1 (en) | 1996-02-12 | 1997-08-20 | L'oreal | Derivatives of s-triazine as UV filters |
WO2019022131A1 (en) * | 2017-07-26 | 2019-01-31 | 三井化学株式会社 | Polymerizable composition for optical material, optical material, and application for same |
JPWO2019022131A1 (en) * | 2017-07-26 | 2020-01-09 | 三井化学株式会社 | Polymerizable composition for optical material, optical material and use thereof |
CN110914322A (en) * | 2017-07-26 | 2020-03-24 | 三井化学株式会社 | Polymerizable composition for optical material, and use thereof |
US11472943B2 (en) | 2017-07-26 | 2022-10-18 | Mitsui Chemicals, Inc. | Polymerizable composition for optical material, optical material, and application thereof |
Also Published As
Publication number | Publication date |
---|---|
DK114645B (en) | 1969-07-21 |
DE1492274A1 (en) | 1969-11-06 |
CH430056A (en) | 1967-02-15 |
US3390051A (en) | 1968-06-25 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
GB1064116A (en) | Ultra-violet absorbing compositions | |
US3275520A (en) | Methods for protecting the skin against actinic radiations | |
US3551443A (en) | 2-phenylbenzoxazole derivatives | |
US4675422A (en) | Organometallic compounds | |
US2329406A (en) | Water soluble condensation product and process for making the same | |
BR8704388A (en) | COMPOSITION, SUBSTANCE FOR PAINTING AND PROCESS FOR THE PREPARATION OF COMPOUNDS | |
CA1064049A (en) | Salts of alkanolamine esters of para dialkylaminobenzoic acid and their use as sun-screening agents | |
JPS5645464A (en) | Substituted oxiranecarboxylic acid* drug containing it* its manufacture and alphaamethylenecarboxylic acid and drug containing alphaamethylenecarboxylic acid | |
US4724174A (en) | Applications for hydrophobic organo aluminum compounds | |
JPH03501127A (en) | N-alkoxyalkylamides and cosmetic treatment compositions using the same | |
JPS6052150B2 (en) | Method for producing photochrome compound | |
US3663606A (en) | Organic imino-compounds | |
GB1376248A (en) | Ultraviolet radiation screening compositions | |
US3414650A (en) | Sunscreening methods | |
US3880875A (en) | Ultraviolet absorbing 2-(2-hydroxyphenyl) 2H-1,2,3-triazole derivatives | |
US4921942A (en) | Organometallic compounds | |
DE2821016C3 (en) | Zinc powder and an optionally partially hydrolyzed silicic acid ester coating agent for ferrous metals | |
JPS63270647A (en) | Cationic cinnamate ester halide | |
US4104368A (en) | Composition and method for protecting skin and hair | |
US3336357A (en) | alpha-alkenylbenzylidene-malononitriles | |
US3375271A (en) | Sun-screening compounds | |
JPS5935941B2 (en) | UV absorber | |
GB1153994A (en) | Hydroxyphenyl Anthranilic Acid Derivatives Capable of Absorbing 'Ultra-Violet Light and Compositions containing them | |
JPH0578334A (en) | P-aminocinnamic acid-substituted triazine | |
US3272810A (en) | Alpha-cyano-beta, beta-diphenylacrylamide compounds |