GB1064064A - Aminosilicone-containing vinyl halide polymer coating compositions - Google Patents
Aminosilicone-containing vinyl halide polymer coating compositionsInfo
- Publication number
- GB1064064A GB1064064A GB3743363A GB3743363A GB1064064A GB 1064064 A GB1064064 A GB 1064064A GB 3743363 A GB3743363 A GB 3743363A GB 3743363 A GB3743363 A GB 3743363A GB 1064064 A GB1064064 A GB 1064064A
- Authority
- GB
- United Kingdom
- Prior art keywords
- vinyl
- aminopropyl
- chloride
- polyvinyl chloride
- dioctyl phthalate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
- C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
- C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
- C09D127/04—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C09D127/06—Homopolymers or copolymers of vinyl chloride
Abstract
Coating compositions comprise an organic solvent and a preformed mixture of a film forming vinyl halide polymer and an amino organo (hydrocarbonoxy) silane of formula <FORM:1064064/C3/1> where Z is hydrogen or a monovalent hydrocarbon radical which may contain an amino, hydroxy or hydrocarbonoxy substituent, R1 is a divalent hydrocarbon radical R11 is a monovalent hydrocarbon radical, the <FORM:1064064/C3/2> group is attached to the silicon atom through at least three successive carbon atoms of the group R1, a is 1, 2 or 3, b is 0, 1 or 2 and (a + b) is 1, 2 or 3; an amino organo siloxane consisting of units of formula <FORM:1064064/C3/3> or a siloxane containing 0.1 to 99.9 mole per cent of said units and 99.9 to 0.1 mole per cent of units of formula <FORM:1064064/C3/4> , where R111 is a monovalent hydrocarbon radical and C is 0, 1, 2 or 3. The vinyl halide polymer may be a homopolymer of vinyl chloride or vinyl fluoride, or a copolymer thereof with vinyl alkanoates and benzoate, vinylidene halides, alkyl acrylates, alkyl methacrylates, dialkyl maleates, dialkyl fumarates, alkenyl cyanides, tetrahaloethylenes, unsaturated amides, aralkenes, alkenes, alkenyl alkyl ethers, alkenyl alkyl ketones and alkenyl heterocyclic compounds. Extensive lists of suitable silicon compounds are given. The mixtures may be dissolved in an organic solvent or dispersed in a plasticizer to give a plastisol. The polymer and silicon compound may be dry blended before incorporation in the solvent or plasticizer, or the silicon compound may be added to a latex of the polymer and the resulting dispersion spray dried. The compositions may be applied to metals and cured to form adherent coatings. Examples describe coating compositions comprising (I and II) polyvinyl chloride, vinyl chloride-vinyl acetate copolymer, d -aminopropyl siloxane, titanium and antimony oxides, dioctylphthalate, diisobutyl ketone, toluene and mixed hydrocarbons; (III-V) polyvinyl chloride and d -aminopropyl siloxane; (VI) polyvinyl chloride, titanium and antimony oxides, dioctyl phthalate, vinyl chloride-vinyl acetate copolymer, methyl isobutyl ketone, diisobutyl ketone, hydrocarbons and d -aminopropyl triethoxysilane, aminoethylaminopropyl trimethoxysilane or aminopropyl-aminopropyltrimethoxysilane; polyvinyl chloride, vinyl chloride-vinyl acetate copolymer, titanium and antimony oxides, dioctyl phthalate, diisobutyl ketone, toluene, hydrocarbons and (VII) d -aminopropyltriethoxysilane, and (VIII) (CH3)2C[C6H4OCH2CH(CH)OSi <FORM:1064064/C3/5> <FORM:1064064/C3/6> or <FORM:1064064/C3/7> (IX) polyvinyl chloride, dioctylphthalate, didecyl phthalate, titanium dioxide and d -aminopropyl triethoxysilane; (X) vinyl chloride-vinyl acetate copolymer, titanium dioxide, aluminium powder, dioctyl phthalate, tricresyl phosphate, methyl isobutyl ketone, toluene, antimony oxide and d -aminopropyl triethoxysilane; (XI) polyvinyl chloride, vinyl chloride-vinyl acetate copolymer, titanium and antimony oxides, dioctyl phthalate, diisobutyl ketone, toluene, hydrocarbons and aminoethyl aminopropyl triethoxysilane; (XII) polyvinyl chloride, dioctyl phthalate, diisobutyl ketone, xylene, naphtha and d -aminopropyl triethoxysilane; and (XIII) copolymers of vinyl chloride with vinylidene chloride or dibutyl fumarate, titanium dioxide, dioctyl phthalate, methyl isobutyl ketone, toluene and d -aminopropyl triethoxysilane, aminoethyl aminopropyl trimethoxysilane or aminopropyl aminopropyl trimethoxysilane.ALSO:Coating compositions comprising an organic solvent and a preformed mixture of a film forming vinyl halide polymer and an amino organo (hydrocarbonoxy) silane of formula <FORM:1064064/B1-B2/1> where Z is hydrogen or monovalent hydrocarbon which may contain an amino, hydroxy or hydrocarbonoxy substituent, R' is a divalent hydrocarbon radical, R'' is a monovalent hydrocarbon radical, the <FORM:1064064/B1-B2/2> group is attached to the silicon atom through at least three successive carbon atoms of the group R', a is 1, 2 or 3, b is 0, 1 or 2 and (a+b) is 1, 2 or 3; an amino organo siloxane consisting of units of formula <FORM:1064064/B1-B2/3> or a siloxane containing 0.1 to 99.9 mole per cent of said units and 99.9 to 0.1 mole per cent of units of formula <FORM:1064064/B1-B2/4> where R''' is a monovalent hydrocarbon radical and C is 0, 1, 2 or 3; may be applied to metal substrates and cured to give adherent coatings. The compositions may be applied in the form of solutions, organosols or plastisols, by brushing, dipping, knife coating, roller coating, spraying or flooding to aluminium, magnesium, iron, copper, chromium, nickel, lead, tin, zinc, tin solder, brass, bronze and steel, which may be pretreated, e.g. phosphated. The polymer may be a polymer or copolymer of vinyl chloride or vinyl fluoride. Many suitable comonomers and amino silanes and siloxanes are listed and examples describe the coating of chromated steel and chromated aluminium with a composition comprising (I) polyvinyl chloride, a vinyl chloride-vinyl acetate copolymer, g -aminopropyl siloxane, titanium and antimony oxides, dioctyl phthalate, diisobutyl ketone, toluene and mixed hydrocarbons; steel with a composition comprising (VI) polyvinyl chloride, a vinyl chloride-vinyl acetate copolymer, titanium and antimony oxides, dioctyl phthalate, methyl isobutyl ketone, diisobutyl ketone, hydrocarbons, and g -aminopropyl triethoxysilane, aminoethyl aminopropyl trimethoxysilane or amino propyl aminopropyl triethoxysilane; cold rolled steel and phosphated aluminium with compositions comprising polyvinyl chloride, a vinyl chloride-vinyl acetate copolymer, titanium and antimony oxides, dioctyl phthalate, diisobutyl ketone, toluene, hydrocarbons and (VII) g -aminopropyl triethoxysilane and (VIII) (CH3)2 C[C6H4O-CH2CH (CH3) OSi (OC2H5)2 CH2CH2CH2NH2]2, CH3NH CH2 CH (CH3) CH2Si (OC2H5)3 or NH2CH2CH2 NH CH2CH (CH3) CH2Si (OC2H5)3; and cold rolled steel with compositions comprising (IX) polyvinyl chloride, dioctyl phthalate, didecyl phthalate, titanium dioxide and g -aminopropyl triethoxysilane, (X) a vinyl chloride-vinyl acetate copolymer, titanium dioxide, aluminium, dioctyl phthalate, tricresyl phosphate, methyl isobutyl ketone, toluene, antimony oxide and g -aminopropyl triethoxysilane, (XI) polyvinyl chloride, a vinyl chloride-vinyl acetate copolymer, titanium and antimony oxides dioctyl phthalate, diisobutyl ketone, toluene, hydrocarbons and aminoethylaminopropyl triethoxy silane; (XII) polyvinyl chloride, dioctyl phthalte, diisobutyl ketone, xylene, naphtha and g -aminopropyl triethoxysilane; and (XIII) copolymers of vinyl chloride with vinylidene chloride or dibutyl fumarate, titanium dioxide, dioctyl phthalte, methyl isobutyl ketone, toluene and g -aminopropyl triethoxy silane, aminoethylaminopropyl triethoxysilane or aminopropylaminopropyl triethoxysilane.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEU0010168 | 1963-09-30 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1064064A true GB1064064A (en) | 1967-04-05 |
Family
ID=7567095
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB3743363A Expired GB1064064A (en) | 1963-09-30 | 1963-09-24 | Aminosilicone-containing vinyl halide polymer coating compositions |
Country Status (2)
Country | Link |
---|---|
DE (1) | DE1494534A1 (en) |
GB (1) | GB1064064A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2482972A1 (en) * | 1980-05-23 | 1981-11-27 | Sumitomo Light Metal Ind | COATING COMPOSITION FOR PROTECTING THE INNER SURFACE OF TUBES IN HEAT EXCHANGERS |
EP1597183A1 (en) | 2003-02-27 | 2005-11-23 | N.V. Bekaert S.A. | An elevator rope |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3030556A1 (en) * | 1979-08-14 | 1981-03-26 | Daikin Kogyo Co., Ltd., Osaka | FLUORELASTOMER WATER-BASED PAINT AND COATING AGENT |
FR2792226B1 (en) | 1999-04-16 | 2001-10-05 | Univ Neuchatel | METHOD FOR DEPOSITING A ADHESIVE LAYER OF PVC AND ELECTRODE OBTAINED ACCORDING TO THIS METHOD |
-
1963
- 1963-09-24 GB GB3743363A patent/GB1064064A/en not_active Expired
- 1963-09-30 DE DE19631494534 patent/DE1494534A1/en active Pending
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2482972A1 (en) * | 1980-05-23 | 1981-11-27 | Sumitomo Light Metal Ind | COATING COMPOSITION FOR PROTECTING THE INNER SURFACE OF TUBES IN HEAT EXCHANGERS |
EP1597183A1 (en) | 2003-02-27 | 2005-11-23 | N.V. Bekaert S.A. | An elevator rope |
Also Published As
Publication number | Publication date |
---|---|
DE1494534A1 (en) | 1969-12-11 |
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