GB1061475A - Process for alkylating, alkenylating, arylating and reducing salts of silver, mercury, copper and gold - Google Patents
Process for alkylating, alkenylating, arylating and reducing salts of silver, mercury, copper and goldInfo
- Publication number
- GB1061475A GB1061475A GB11255/64A GB1125564A GB1061475A GB 1061475 A GB1061475 A GB 1061475A GB 11255/64 A GB11255/64 A GB 11255/64A GB 1125564 A GB1125564 A GB 1125564A GB 1061475 A GB1061475 A GB 1061475A
- Authority
- GB
- United Kingdom
- Prior art keywords
- organo
- compounds
- aryl
- alkyl
- alkenyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000003839 salts Chemical class 0.000 title abstract 5
- 229910052737 gold Chemical class 0.000 title abstract 3
- 239000010931 gold Chemical class 0.000 title abstract 3
- 229910052709 silver Inorganic materials 0.000 title abstract 3
- 229910052802 copper Inorganic materials 0.000 title abstract 2
- 239000010949 copper Chemical class 0.000 title abstract 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical class [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 title abstract 2
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical class [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 title abstract 2
- 239000004332 silver Substances 0.000 title abstract 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical class [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 title 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical class [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 title 1
- 230000002152 alkylating effect Effects 0.000 title 1
- 229910052753 mercury Inorganic materials 0.000 title 1
- DDFHBQSCUXNBSA-UHFFFAOYSA-N 5-(5-carboxythiophen-2-yl)thiophene-2-carboxylic acid Chemical compound S1C(C(=O)O)=CC=C1C1=CC=C(C(O)=O)S1 DDFHBQSCUXNBSA-UHFFFAOYSA-N 0.000 abstract 4
- 125000000217 alkyl group Chemical group 0.000 abstract 4
- 125000003342 alkenyl group Chemical group 0.000 abstract 3
- 125000003118 aryl group Chemical group 0.000 abstract 3
- -1 aryl trifluorosilane Chemical compound 0.000 abstract 3
- 239000002253 acid Substances 0.000 abstract 2
- ORMNPSYMZOGSSV-UHFFFAOYSA-N dinitrooxymercury Chemical compound [Hg+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ORMNPSYMZOGSSV-UHFFFAOYSA-N 0.000 abstract 2
- ZELCNSAUMHNSSU-UHFFFAOYSA-N 3,5-diamino-2-[(4-sulfamoylphenyl)diazenyl]benzoic acid Chemical compound OC(=O)C1=CC(N)=CC(N)=C1N=NC1=CC=C(S(N)(=O)=O)C=C1 ZELCNSAUMHNSSU-UHFFFAOYSA-N 0.000 abstract 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 abstract 1
- 125000006193 alkinyl group Chemical group 0.000 abstract 1
- 125000005741 alkyl alkenyl group Chemical group 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- BERDEBHAJNAUOM-UHFFFAOYSA-N copper(I) oxide Inorganic materials [Cu]O[Cu] BERDEBHAJNAUOM-UHFFFAOYSA-N 0.000 abstract 1
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 abstract 1
- KRFJLUBVMFXRPN-UHFFFAOYSA-N cuprous oxide Chemical compound [O-2].[Cu+].[Cu+] KRFJLUBVMFXRPN-UHFFFAOYSA-N 0.000 abstract 1
- 229940112669 cuprous oxide Drugs 0.000 abstract 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 abstract 1
- 229910052731 fluorine Inorganic materials 0.000 abstract 1
- 239000011737 fluorine Substances 0.000 abstract 1
- DRXYRSRECMWYAV-UHFFFAOYSA-N mercury(I) nitrate Inorganic materials [Hg+].[O-][N+]([O-])=O DRXYRSRECMWYAV-UHFFFAOYSA-N 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 229940008718 metallic mercury Drugs 0.000 abstract 1
- 150000002739 metals Chemical class 0.000 abstract 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 1
- 150000002902 organometallic compounds Chemical class 0.000 abstract 1
- 150000003961 organosilicon compounds Chemical class 0.000 abstract 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 1
- 239000010944 silver (metal) Substances 0.000 abstract 1
- KGWNTHHPMKEAIK-UHFFFAOYSA-N trifluoro(phenyl)silane Chemical compound F[Si](F)(F)C1=CC=CC=C1 KGWNTHHPMKEAIK-UHFFFAOYSA-N 0.000 abstract 1
- ATVLVRVBCRICNU-UHFFFAOYSA-N trifluorosilicon Chemical compound F[Si](F)F ATVLVRVBCRICNU-UHFFFAOYSA-N 0.000 abstract 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F1/00—Compounds containing elements of Groups 1 or 11 of the Periodic Table
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F1/00—Compounds containing elements of Groups 1 or 11 of the Periodic Table
- C07F1/08—Copper compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F3/00—Compounds containing elements of Groups 2 or 12 of the Periodic Table
- C07F3/10—Mercury compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/12—Organo silicon halides
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/494—Silver salt compositions other than silver halide emulsions; Photothermographic systems ; Thermographic systems using noble metal compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
Abstract
Alkyl, alkenyl and aryl compounds of Hg, Cu, Ag and Au are obtained by reacting salts of these compounds with an alkyl, alkenyl or aryl trifluorosilane or with a salt of an alkyl, alkenyl or aryl pentafluorosilicic acid, possibly in the presence of ammonium fluoride. Methyl, ethyl, phenyl and vinyl compounds are specified.ALSO:Metallic mercury copper, silver and gold are obtained when salts of these metals are reacted with alkyl, alkinyl or aryl trifluorosilanes or with a salt of an alkyl alkenyl or aryl pentafluorosilicic acid, possible in the presence of ammonium fluoride, thus forming unstable intermediate organo-metallic compounds.ALSO:Cuprous oxide is formed when copper sulphate is reacted with phenyl trifluorosilane. Mercuric nitrate is formed when mercurous nitrate is reacted with an organo trifluorosilane.ALSO:In a process in which organo-trifluorosilanes and possibly the corresponding organo-pentafluoro-silicates are formed by reacting non-fluorine containing trifunctional organo-silicon compounds (one Si per mol) with a metallic or ammonium fluoride, the compounds CH2:CH.SiF3 or PhSiF3 or possibly the corresponding organo-pentafluorosilicates are prepared by reacting CH2:CH.Si(OH)2(ONa) or Ph.Si(OH)2(ONa) with a metallic or ammonium fluoride.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR968535A FR1389872A (en) | 1964-03-24 | 1964-03-24 | Process of alkylation, alkenylation and arylation with reduction by trifunctional organosilanes |
| FR985140A FR86528E (en) | 1964-03-24 | 1964-08-13 | Process of alkylation, alkenylation and arylation with reduction by trifunctional organosilanes |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1061475A true GB1061475A (en) | 1967-03-15 |
Family
ID=26206635
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB11255/64A Expired GB1061475A (en) | 1964-03-24 | 1964-03-17 | Process for alkylating, alkenylating, arylating and reducing salts of silver, mercury, copper and gold |
Country Status (3)
| Country | Link |
|---|---|
| BE (2) | BE646473A (en) |
| FR (1) | FR86528E (en) |
| GB (1) | GB1061475A (en) |
-
1964
- 1964-03-17 GB GB11255/64A patent/GB1061475A/en not_active Expired
- 1964-04-13 BE BE646473A patent/BE646473A/xx unknown
- 1964-08-13 FR FR985140A patent/FR86528E/en not_active Expired
- 1964-09-04 BE BE652668A patent/BE652668A/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| BE652668A (en) | 1964-12-31 |
| FR86528E (en) | 1966-02-25 |
| BE646473A (en) | 1964-07-31 |
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