GB1057297A - Process for the manufacture of composite structures from rayon textile materials and copolymers of mono-olefines - Google Patents

Process for the manufacture of composite structures from rayon textile materials and copolymers of mono-olefines

Info

Publication number
GB1057297A
GB1057297A GB7632/64A GB763264A GB1057297A GB 1057297 A GB1057297 A GB 1057297A GB 7632/64 A GB7632/64 A GB 7632/64A GB 763264 A GB763264 A GB 763264A GB 1057297 A GB1057297 A GB 1057297A
Authority
GB
United Kingdom
Prior art keywords
phenol
propene
butene
partially unsaturated
amorphous copolymer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB7632/64A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hoechst AG
Original Assignee
Hoechst AG
Farbwerke Hoechst AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hoechst AG, Farbwerke Hoechst AG filed Critical Hoechst AG
Publication of GB1057297A publication Critical patent/GB1057297A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
    • C08J5/06—Reinforcing macromolecular compounds with loose or coherent fibrous material using pretreated fibrous materials
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/18—Introducing halogen atoms or halogen-containing groups
    • C08F8/20—Halogenation
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
    • C09J123/26—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers modified by chemical after-treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/16—Ethene-propene or ethene-propene-diene copolymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
    • C08L2666/14—Macromolecular compounds according to C08L59/00 - C08L87/00; Derivatives thereof
    • C08L2666/16—Addition or condensation polymers of aldehydes or ketones according to C08L59/00 - C08L61/00; Derivatives thereof

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Reinforced Plastic Materials (AREA)
  • Drying Of Solid Materials (AREA)

Abstract

In the manufacture of rubber articles from saturated amorphous copolymers of ethane and propene or butene (1) satisfactory adhesion of the rayon cord threads or fabrics used for reinforcement is obtained by a process comprising (1) impregnating the rayon cord thread or fabric with an aqueous dispersion containing (a) a reactive di- or polymethylol phenol resin obtained from a phenol and formaldehyde and (b) a partially unsaturated amorphous copolymer optained by reacting a copolymer of ethene and propene or butene (1) with an N-bromodicarboxylic acid imide, e.g. N-bromo-succinimide, or an N-bromo-carboxylic acid amide, (2) embedding the impregnated materials after drying in a vulcanizable mixture of a partially unsaturated amorphous copolymer of the kind described under (1) (b) which also contains sulphur and accelerators, (3) applying to the composite structure a vulcanisable mixture of the saturated amorphous copolymer of ethene and propene or butene-(1) and at least one peroxide, e.g. dicumyl peroxide or tert, butyl cumyl, peroxide, and sulphur to bring about cross-linking and (4) vulcanizing the composite-structure while imparting to it a final shape. The mixture of the partially unsaturated amorphous copolymer used in step (2) of the process may also contain active or inactive fillers, process oils, pigments and tackifiers. Suitable vulcanization accelerators are zinc dimethyl dithiocarbaminate, 2-mercapto benzothiazole, N-cyclohexyl-2-benzothiazyl sulphene amide, tetramethyl thiuram mono- or di-sulphide, di-phenyl guanidine, morpholine or morpholine disulphide. The di or polymethylol phenol resin may be made from phenol, an alkyl phenol, pyrogallol or resorcinol and may be added as the resin precondensate or formed in situ.
GB7632/64A 1963-02-22 1964-02-24 Process for the manufacture of composite structures from rayon textile materials and copolymers of mono-olefines Expired GB1057297A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEF39084A DE1245119B (en) 1963-02-22 1963-02-22 Process for the production of composite bodies from rayon, cord twine or fabric and copolymers of ethylene and propylene or butylene

Publications (1)

Publication Number Publication Date
GB1057297A true GB1057297A (en) 1967-02-01

Family

ID=7097614

Family Applications (1)

Application Number Title Priority Date Filing Date
GB7632/64A Expired GB1057297A (en) 1963-02-22 1964-02-24 Process for the manufacture of composite structures from rayon textile materials and copolymers of mono-olefines

Country Status (11)

Country Link
AT (1) AT260519B (en)
BE (1) BE644250A (en)
CH (1) CH435711A (en)
DE (1) DE1245119B (en)
DK (1) DK104999C (en)
FI (1) FI41868B (en)
GB (1) GB1057297A (en)
LU (1) LU45447A1 (en)
NL (1) NL6401416A (en)
NO (1) NO115683B (en)
SE (1) SE303990B (en)

Also Published As

Publication number Publication date
AT260519B (en) 1968-03-11
DK104999C (en) 1966-08-01
CH435711A (en) 1967-05-15
LU45447A1 (en) 1964-04-18
DE1245119B (en) 1967-07-20
SE303990B (en) 1968-09-16
NO115683B (en) 1968-11-11
FI41868B (en) 1969-12-01
BE644250A (en) 1964-08-24
NL6401416A (en) 1964-08-24

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