GB1056712A - Electrolytic cell - Google Patents

Electrolytic cell

Info

Publication number
GB1056712A
GB1056712A GB1088/64A GB108864A GB1056712A GB 1056712 A GB1056712 A GB 1056712A GB 1088/64 A GB1088/64 A GB 1088/64A GB 108864 A GB108864 A GB 108864A GB 1056712 A GB1056712 A GB 1056712A
Authority
GB
United Kingdom
Prior art keywords
cell
spacers
electrodes
electrolyte
side walls
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1088/64A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hooker Chemical Corp
Original Assignee
Hooker Chemical Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hooker Chemical Corp filed Critical Hooker Chemical Corp
Publication of GB1056712A publication Critical patent/GB1056712A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/02Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form
    • C25B11/036Bipolar electrodes
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/17Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof
    • C25B9/19Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof with diaphragms

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)

Abstract

<PICT:1056712/C6-C7/1> <PICT:1056712/C6-C7/2> An electrolytic cell comprises a base, a pair of opposide end walls as 4 and a pair of opposed side walls 1, bi-polar electrodes 3 extending between the side walls, pairs of spacers 7 secured to opposite side walls with the electrodes 3 slotted between each two successive spacers, and fluid permeable diaphragms 5 supported at opposite side edges by a pair of spacers and disposed between each adjacent pair of electrodes. As shown, the spacers are secured to the walls by engagement in recesses therein and frame members 8 secured to the diaphragm, which may be of woven glass, PVC or PTFE, or less desirably asbestos paper are cemented into grooves in the base of the cell and also are sealed into the cell cover 11, while the diaphragm side edges are held in slots in the spacers by plastic rods pressed into the slots. The electrodes 3, which may be of graphite or platinised titanium, are located in the cell by splines 9 fitting into grooves in the cell bottom, side walls and cover, which cover may be formed of separate strips sealed to the diaphragm top frames and electrode splines, and end electrodes as 6 are connected to a D.C. source. For electrolyzing e.g. at 90 DEG C. hydrochloric acid to yield chlorine and hydrogen, the cell casing may be of rigid PVC, hard rubber or a chlorinated polyester and may have external reinforcing metal bands, or may be of concrete or cement coated internally with such corrosion resistant materials. Electrolyte containing the chlorine and hydrogen evolved is withdrawn by gas lift along pipes 13, 17 respectively to gas separating chambers 21, 22 respectively, the degassed electrolyte being returned to cell via pipes 15, 19. Weir barriers 23 extending to the bottoms of chambers 21, 22 provide for electrical isolation of the various electrolyte streams. Hydrochloric acid is added to the electrolyte in chamber 21 and part of the depleted acid electrolyte is allowed to overflow from chamber 22, the depleted acid being concentrated and subsequently returned to the cell.
GB1088/64A 1963-01-09 1964-01-09 Electrolytic cell Expired GB1056712A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US250331A US3324023A (en) 1963-01-09 1963-01-09 Bipolar electrolytic cell for the production of gases

Publications (1)

Publication Number Publication Date
GB1056712A true GB1056712A (en) 1967-01-25

Family

ID=22947299

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1088/64A Expired GB1056712A (en) 1963-01-09 1964-01-09 Electrolytic cell

Country Status (4)

Country Link
US (1) US3324023A (en)
DE (1) DE1467067B2 (en)
GB (1) GB1056712A (en)
NL (1) NL6400085A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1998030736A1 (en) * 1997-01-10 1998-07-16 Bayer Aktiengesellschaft Wall-covering for electrolytic cells

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3405051A (en) * 1964-10-27 1968-10-08 Huron Nassau Ltd Electrolytic cell container
US3503858A (en) * 1964-11-26 1970-03-31 Huron Nassau Ltd Continuous electrolytic cell process
US3655539A (en) * 1967-02-15 1972-04-11 Diamond Shamrock Corp Soluble chromate purification by electrolysis
US3639223A (en) * 1970-09-18 1972-02-01 Standard Chemical Ltd Chlorate cell
US3856651A (en) * 1971-08-12 1974-12-24 Ppg Industries Inc Apparatus for producing uniform anolyte heads in the individual cells of a bipolar electrolyzer
US3755108A (en) * 1971-08-12 1973-08-28 Ppg Industries Inc Method of producing uniform anolyte heads in the individual cells of a bipolar electrolyzer
US3926534A (en) * 1974-01-02 1975-12-16 Kobe Inc Turbine
JPS587716B2 (en) * 1975-09-11 1983-02-10 三井金属鉱業株式会社 Denkaisou
FR2435537A1 (en) * 1978-08-22 1980-04-04 Creusot Loire ELECTROLYSIS CELL FOR GAS PRODUCTION
JPS57174479A (en) * 1981-04-20 1982-10-27 Tokuyama Soda Co Ltd Unit electrolytic cell
US4402809A (en) * 1981-09-03 1983-09-06 Ppg Industries, Inc. Bipolar electrolyzer
CA1258250A (en) * 1985-01-25 1989-08-08 Colin W. Oloman Perforated bipole electrochemical reactor
GB8506092D0 (en) * 1985-03-08 1985-04-11 Minnesota Mining & Mfg Photographic materials & colour proofing system
WO1998000584A1 (en) * 1996-06-28 1998-01-08 E.I. Du Pont De Nemours And Company Electrochemical cell having split fluid and current feed

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1415466A (en) * 1920-06-01 1922-05-09 Pechkranz Rodolphe Electrolyzer
US1579138A (en) * 1924-07-18 1926-03-30 Elek Zitats Ag Vormals Schucke Electrolytic cell
US1793136A (en) * 1925-07-01 1931-02-17 Ig Farbenindustrie Ag Electrolytic cell
DE585596C (en) * 1931-11-18 1933-10-10 Siemens & Halske Akt Ges Water decomposer of the filter press type
CH206961A (en) * 1938-08-06 1939-09-15 Oerlikon Maschf Electrolyser cell with external electrolyte circulation, especially for water decomposition.
US2719822A (en) * 1952-01-10 1955-10-04 Universal Oil Prod Co Production of chlorine from hydrogen chloride
US2858263A (en) * 1954-08-25 1958-10-28 Dow Chemical Co Diaphragm type electrolytic cell
US2871179A (en) * 1955-04-01 1959-01-27 Lonza Ag Electrolytic water decomposer
US3117066A (en) * 1960-11-01 1964-01-07 Ionics Electrolytic process for producing halogen gases and the apparatus therefor
US3247090A (en) * 1962-09-17 1966-04-19 Pittsburgh Plate Glass Co Electrolytic cell

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1998030736A1 (en) * 1997-01-10 1998-07-16 Bayer Aktiengesellschaft Wall-covering for electrolytic cells
US6200437B1 (en) 1997-01-10 2001-03-13 Bayer Aktiengesellschaft Wall-covering for electrolytic cells

Also Published As

Publication number Publication date
DE1467067B2 (en) 1970-04-09
US3324023A (en) 1967-06-06
DE1467067A1 (en) 1969-01-09
NL6400085A (en) 1964-07-10

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