GB1047768A - A method of copolymerising maleic anhydride with olefins - Google Patents
A method of copolymerising maleic anhydride with olefinsInfo
- Publication number
- GB1047768A GB1047768A GB49713/63A GB4971363A GB1047768A GB 1047768 A GB1047768 A GB 1047768A GB 49713/63 A GB49713/63 A GB 49713/63A GB 4971363 A GB4971363 A GB 4971363A GB 1047768 A GB1047768 A GB 1047768A
- Authority
- GB
- United Kingdom
- Prior art keywords
- maleic anhydride
- sulphinic acid
- olefine
- olefins
- chelate compound
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F22/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides or nitriles thereof
- C08F22/04—Anhydrides, e.g. cyclic anhydrides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Copolymers of maleic anhydride and a C2- 4 olefine are prepared by copolymerizing the monomers at a superatmospheric pressure and at a temperature of 50-80 DEG C. in an inert organic solvent and in the presence of a polymerization initiator comprising an organic redox system comprising an organic peroxide and either a sulphinic acid or a chelate compound containing a central atom of variable valency. The olefine may be propylene or isobutylene. The peroxide may be benzoyl, 4,41-tetrachlorobenzoyl, methylethyl-ketone or cyclohexanone peroxides. The sulphinic acid may be p-toluene-sulphinic acid and the chelate compound may be ferrous acetyl-acetonate. The organic solvent may be an aromatic hydrocarbon, e.g. benzene, or an aliphatic ether.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT997862A AT242361B (en) | 1962-12-21 | 1962-12-21 | Process for the copolymerization of maleic anhydride with olefins |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1047768A true GB1047768A (en) | 1966-11-09 |
Family
ID=3618908
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB49713/63A Expired GB1047768A (en) | 1962-12-21 | 1963-12-17 | A method of copolymerising maleic anhydride with olefins |
Country Status (4)
Country | Link |
---|---|
AT (1) | AT242361B (en) |
CH (1) | CH428229A (en) |
FR (1) | FR1378491A (en) |
GB (1) | GB1047768A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1997006191A1 (en) * | 1995-08-10 | 1997-02-20 | Camelot Superabsorbents Limited | Process for the production of water-absorbing compositions |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3846383A (en) * | 1972-07-13 | 1974-11-05 | Kuraray Co | Method for producing copolymers |
-
1962
- 1962-12-21 AT AT997862A patent/AT242361B/en active
-
1963
- 1963-11-27 CH CH1451863A patent/CH428229A/en unknown
- 1963-12-17 GB GB49713/63A patent/GB1047768A/en not_active Expired
- 1963-12-19 FR FR957761A patent/FR1378491A/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1997006191A1 (en) * | 1995-08-10 | 1997-02-20 | Camelot Superabsorbents Limited | Process for the production of water-absorbing compositions |
Also Published As
Publication number | Publication date |
---|---|
CH428229A (en) | 1967-01-15 |
AT242361B (en) | 1965-09-10 |
FR1378491A (en) | 1964-11-13 |
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