GB1047768A - A method of copolymerising maleic anhydride with olefins - Google Patents

A method of copolymerising maleic anhydride with olefins

Info

Publication number
GB1047768A
GB1047768A GB49713/63A GB4971363A GB1047768A GB 1047768 A GB1047768 A GB 1047768A GB 49713/63 A GB49713/63 A GB 49713/63A GB 4971363 A GB4971363 A GB 4971363A GB 1047768 A GB1047768 A GB 1047768A
Authority
GB
United Kingdom
Prior art keywords
maleic anhydride
sulphinic acid
olefine
olefins
chelate compound
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB49713/63A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Osterreichische Stickstoffwerke AG
Patheon Austria GmbH and Co KG
Original Assignee
Chemie Linz AG
Osterreichische Stickstoffwerke AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chemie Linz AG, Osterreichische Stickstoffwerke AG filed Critical Chemie Linz AG
Publication of GB1047768A publication Critical patent/GB1047768A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F22/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides or nitriles thereof
    • C08F22/04Anhydrides, e.g. cyclic anhydrides
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

Copolymers of maleic anhydride and a C2- 4 olefine are prepared by copolymerizing the monomers at a superatmospheric pressure and at a temperature of 50-80 DEG C. in an inert organic solvent and in the presence of a polymerization initiator comprising an organic redox system comprising an organic peroxide and either a sulphinic acid or a chelate compound containing a central atom of variable valency. The olefine may be propylene or isobutylene. The peroxide may be benzoyl, 4,41-tetrachlorobenzoyl, methylethyl-ketone or cyclohexanone peroxides. The sulphinic acid may be p-toluene-sulphinic acid and the chelate compound may be ferrous acetyl-acetonate. The organic solvent may be an aromatic hydrocarbon, e.g. benzene, or an aliphatic ether.
GB49713/63A 1962-12-21 1963-12-17 A method of copolymerising maleic anhydride with olefins Expired GB1047768A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
AT997862A AT242361B (en) 1962-12-21 1962-12-21 Process for the copolymerization of maleic anhydride with olefins

Publications (1)

Publication Number Publication Date
GB1047768A true GB1047768A (en) 1966-11-09

Family

ID=3618908

Family Applications (1)

Application Number Title Priority Date Filing Date
GB49713/63A Expired GB1047768A (en) 1962-12-21 1963-12-17 A method of copolymerising maleic anhydride with olefins

Country Status (4)

Country Link
AT (1) AT242361B (en)
CH (1) CH428229A (en)
FR (1) FR1378491A (en)
GB (1) GB1047768A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1997006191A1 (en) * 1995-08-10 1997-02-20 Camelot Superabsorbents Limited Process for the production of water-absorbing compositions

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3846383A (en) * 1972-07-13 1974-11-05 Kuraray Co Method for producing copolymers

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1997006191A1 (en) * 1995-08-10 1997-02-20 Camelot Superabsorbents Limited Process for the production of water-absorbing compositions

Also Published As

Publication number Publication date
CH428229A (en) 1967-01-15
AT242361B (en) 1965-09-10
FR1378491A (en) 1964-11-13

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