GB1044045A - Process for the preparation of fluorochloromethanes - Google Patents

Process for the preparation of fluorochloromethanes

Info

Publication number
GB1044045A
GB1044045A GB27890/63A GB2789063A GB1044045A GB 1044045 A GB1044045 A GB 1044045A GB 27890/63 A GB27890/63 A GB 27890/63A GB 2789063 A GB2789063 A GB 2789063A GB 1044045 A GB1044045 A GB 1044045A
Authority
GB
United Kingdom
Prior art keywords
products
cf2cl2
cfcl3
catalyst
operated
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB27890/63A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Edison SpA
Original Assignee
Edison SpA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Edison SpA filed Critical Edison SpA
Publication of GB1044045A publication Critical patent/GB1044045A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00Preparation of halogenated hydrocarbons
    • C07C17/093Preparation of halogenated hydrocarbons by replacement by halogens
    • C07C17/10Preparation of halogenated hydrocarbons by replacement by halogens of hydrogen atoms
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/584Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Fluorochloromethanes are obtained by the catalytic reaction between methane, chlorine and hydrogen fluoride in two different zones, one operated at 350-500 DEG C., where mainly chlorination occurs, and the other operated at 200-350 DEG C. where mainly fluorination occurs, either zone coming first; in the presence of a gaseous recycling mixture comprising one or more chlorinated or chlorofluorinated compounds which are intermediates, main products or by-products. The higher temperature zone may contain active carbon and/or a halide of a metal of variable valency as catalyst, and the lower temperature zone may contain a metal oxide or salt as catalyst. Specified products for recycle are CCl4, CHCl3, CH2Cl2, CH3Cl, CFCl3, CF2Cl2, CF3Cl, CHFCl2, CHF2Cl, C2Cl4, C2Cl6 and C2HCl3. The main recovered products in examples are CF2Cl2 and CFCl3.
GB27890/63A 1962-07-17 1963-07-15 Process for the preparation of fluorochloromethanes Expired GB1044045A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
IT1439362 1962-07-17

Publications (1)

Publication Number Publication Date
GB1044045A true GB1044045A (en) 1966-09-28

Family

ID=11145028

Family Applications (1)

Application Number Title Priority Date Filing Date
GB27890/63A Expired GB1044045A (en) 1962-07-17 1963-07-15 Process for the preparation of fluorochloromethanes

Country Status (9)

Country Link
AT (1) AT259533B (en)
BE (1) BE635068A (en)
CH (1) CH456555A (en)
DE (1) DE1289839C2 (en)
DK (1) DK106668C (en)
ES (1) ES290036A1 (en)
FR (1) FR1367087A (en)
GB (1) GB1044045A (en)
NL (2) NL295414A (en)

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1026291B (en) * 1952-06-12 1958-03-20 Nat Smelting Co Ltd Process for the production of difluorodichloromethane

Also Published As

Publication number Publication date
AT259533B (en) 1968-01-25
NL295414A (en) 1965-04-26
BE635068A (en) 1964-01-17
DK106668C (en) 1967-03-06
DE1289839B (en) 1969-02-27
CH456555A (en) 1968-07-31
DE1289839C2 (en) 1975-02-20
ES290036A1 (en) 1963-08-16
NL136585C (en) 1900-01-01
FR1367087A (en) 1964-07-17

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