GB1042891A - Bis-triazinylamino-stilbene derivatives and their use as optical brighteners - Google Patents

Bis-triazinylamino-stilbene derivatives and their use as optical brighteners

Info

Publication number
GB1042891A
GB1042891A GB4333/63A GB433363A GB1042891A GB 1042891 A GB1042891 A GB 1042891A GB 4333/63 A GB4333/63 A GB 4333/63A GB 433363 A GB433363 A GB 433363A GB 1042891 A GB1042891 A GB 1042891A
Authority
GB
United Kingdom
Prior art keywords
radical
primary
aliphatic amine
group
secondary aliphatic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB4333/63A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hoechst AG
Original Assignee
Hoechst AG
Farbwerke Hoechst AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hoechst AG, Farbwerke Hoechst AG filed Critical Hoechst AG
Publication of GB1042891A publication Critical patent/GB1042891A/en
Expired legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
    • D06L4/00—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
    • D06L4/60—Optical bleaching or brightening
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D251/00—Heterocyclic compounds containing 1,3,5-triazine rings
    • C07D251/02—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings
    • C07D251/12—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members
    • C07D251/26—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with only hetero atoms directly attached to ring carbon atoms
    • C07D251/40—Nitrogen atoms
    • C07D251/54—Three nitrogen atoms
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/40—Dyes ; Pigments
    • C11D3/42—Brightening agents ; Blueing agents
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/30—Luminescent or fluorescent substances, e.g. for optical bleaching

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Detergent Compositions (AREA)
  • Paper (AREA)

Abstract

Detergent compositions comprise optical brightening agents of the general formula <FORM:1042891/C4-C5/1> wherein Z represents a hydrogen atom or a group imparting solubility in water, R1 represents a hydrogen atom or an alkyl or alkoxy radical, and X represents an -NH2 group or the radical of a primary or secondary aliphatic amine, with the proviso that when R1=H and Z=a sulphonic acid group then X=-NH2 or the radical of a primary or secondary aliphatic amine containing a sulphonic or carboxylic acid group. Other components specified in examples are (i) sodium silicate, sodium hydroxide solution, alkylaryl sulphonate and hydrogen peroxide solution, and (ii) the condensation product of oleyl alcohol and about 10 mols. of ethylene oxide, polyphosphate, soap powder, sodium metasilicate, sodium perborate, magnesium silicate, carboxymethylcellulose and a conventional filler, e.g. sodium or potassium sulphate or carbonate. Reference has been directed by the Comptroller to Specification 987,922.ALSO:The invention comprises compounds of the general formula <FORM:1042891/C2/1> in which Z represents a hydrogen atom or a group imparting solubility in water, R1 represents a hydrogen atom or an alkyl or alkoxy radical, and X represents an -NH2 group or the radical of a primary or secondary aliphatic amine, with the proviso that when R1 = H and Z = a sulphonic acid group then X = -NH2 or the radical of a primary or secondary aliphatic amine containing a sulphonic or carboxylic acid group. The compounds may be prepared by reacting together, in any desired sequence, cyanuric chloride, an amino-stilbene derivative, an aminoaryl-b -hydroxyethylsulphone or an aminoaryl-b -hydroxyethylsulphone containing substituents in the ring, and a primary or secondary aliphatic amine. Examples are given. Reference has been directed by the Comptroller to Specification 987,922.ALSO:Optical brightening agents of the general formula <FORM:1042891/D1-D2/1> which Z represents a hydrogen atom or a group imparting solubility in water, R1 represents a hydrogen atom or an alkyl or alkoxy radical, and X represents an -NH2 group or the radical of a primary or secondary aliphatic amine, with the proviso that when R1=H and Z=a sulphonic acid group then p X=-NH2 or the radical of a primary or secondary aliphatic amine containing a sulphonic or carboxylic acid group, may be employed for the optical brightening of foils, films, felts or textile materials for example fibres, filaments, flocks, fabrics or knit fabrics made of natural, regenerated or synthetic materials, as well as of leather and paper. Especially good effects are obtained with natural or regenerated cellulose. The brightening agents may be used in association with detergents or rinsing or finishing agents or they may be added to the materials to be brightened during the production of such materials, for example, they may be added to wash lyes, brightening baths, bleaching baths and paper pulp. Examples describe the use of the compounds to brighten (1) bleached cotton fabric, (2) desized crude cotton fabric, (3) paper, (4) polycaprolactam fabric, (5) white cotton poplin, (6) bleached nettle cloth, (7) bleached wool flannel, and (8) bleached cotton poplin impregnated with a urea-formaldehyde precondensation product and ammonium nitrate, the condensation of the resin being completed subsequently at 150 DEG C. to give a crease-resistant material. Reference has been directed by Comptroller to Specification 987,922.
GB4333/63A 1962-02-01 1963-02-01 Bis-triazinylamino-stilbene derivatives and their use as optical brighteners Expired GB1042891A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEF35895A DE1237525B (en) 1962-02-01 1962-02-01 Optical brightener

Publications (1)

Publication Number Publication Date
GB1042891A true GB1042891A (en) 1966-09-14

Family

ID=7096209

Family Applications (1)

Application Number Title Priority Date Filing Date
GB4333/63A Expired GB1042891A (en) 1962-02-01 1963-02-01 Bis-triazinylamino-stilbene derivatives and their use as optical brighteners

Country Status (5)

Country Link
BE (1) BE627915A (en)
CH (1) CH441212A (en)
DE (1) DE1237525B (en)
DK (1) DK104782C (en)
GB (1) GB1042891A (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1469218B1 (en) * 1964-06-30 1971-09-08 Hoechst Ag 4,4'-bis-triazinylamino-stilbene compounds and their use as reactive optical brightening agents

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1098485B (en) * 1957-06-05 1961-02-02 Bayer Ag Whitening agents
NL230056A (en) * 1957-07-30

Also Published As

Publication number Publication date
CH441212A (en) 1967-04-29
BE627915A (en) 1963-08-01
DK104782C (en) 1966-07-04
DE1237525B (en) 1967-03-30

Similar Documents

Publication Publication Date Title
ES356804A1 (en) Polysulfonated bis-s-triazinylamino-stilbene-2,2&#39;-disulfonic acids
RU2241703C2 (en) Method for preparing liquid composition containing stilbene compounds
GB681642A (en) New derivatives of 4:4-diaminostilbene-2:2-disulphonic acid and their manufacture and use
US3897347A (en) Washing agents containing a textile softener and process of washing and softening textiles
US2956898A (en) Certification of correction
GB767162A (en) Polyamino polycarboxylic acid chelating agents
GB828545A (en) Process for the optical brightening of materials composed of polyester resins
US2763650A (en) Derivatives of x
GB1042891A (en) Bis-triazinylamino-stilbene derivatives and their use as optical brighteners
US3309363A (en) Das triazine brightener
US3081265A (en) Washing cotton fabrics
US3356524A (en) Process for treating and brightening cellulose fibers
US3579511A (en) Triazole compounds,processes for their manufacture and use
US2805999A (en) Detergent compositions containing derivatives of 4:4&#39;-diaminostilbene-disulfonic acid
GB924762A (en) New derivatives of 1,4-bis-styryl-benzene and optical brightening therewith
GB1114570A (en) Derivatives of aminostilbene and their use as reactive optical brighteners
GB824659A (en) Process for the optical brightening of fibres of polyacrylonitrile
GB976822A (en) New bistriazinylaminostilbene derivatives
US3745036A (en) Optical brightening composition and method of brightening fibres made of cellulose and polyamide
US3682900A (en) Stilbene derivatives
US3318874A (en) Nh- hsc n n xxnh -ch -ch=ch- sosna sosna chs cha soaxchjxchsxoh
SU473370A3 (en) Optical bleaching of textile materials
GB1110666A (en) Improvements in the bleaching and washing of textile materials
GB1007641A (en) Bis-triazinylamino-stilbene disulphonic acid derivatives
GB894744A (en) Bis-triazinylamino-stilbene derivatives