GB1040809A - Improvements in or relating to the manufacture of a non-oxidizing gas - Google Patents

Improvements in or relating to the manufacture of a non-oxidizing gas

Info

Publication number
GB1040809A
GB1040809A GB48661/64A GB4866164A GB1040809A GB 1040809 A GB1040809 A GB 1040809A GB 48661/64 A GB48661/64 A GB 48661/64A GB 4866164 A GB4866164 A GB 4866164A GB 1040809 A GB1040809 A GB 1040809A
Authority
GB
United Kingdom
Prior art keywords
water
ammonia
coil
catalyst
gas mixture
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB48661/64A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Societe Chimique de la Grande Paroisse Azote et Produits Chimiques
Original Assignee
Societe Chimique de la Grande Paroisse Azote et Produits Chimiques
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Societe Chimique de la Grande Paroisse Azote et Produits Chimiques filed Critical Societe Chimique de la Grande Paroisse Azote et Produits Chimiques
Publication of GB1040809A publication Critical patent/GB1040809A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/74Methods of treatment in inert gas, controlled atmosphere, vacuum or pulverulent material
    • C21D1/76Adjusting the composition of the atmosphere
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/14Production of inert gas mixtures; Use of inert gases in general
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B21/00Nitrogen; Compounds thereof
    • C01B21/02Preparation of nitrogen
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/04Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of inorganic compounds, e.g. ammonia
    • C01B3/047Decomposition of ammonia
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/36Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/10Process efficiency

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Thermal Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Catalysts (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Separation Of Gases By Adsorption (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

<PICT:1040809/C1/1> A non-oxidizing gas mixture containing at least 80% by volume of nitrogen is produced by (a) burning a hydrocarbon in air (b) decomposing gaseous ammonia by heat using part of the heat produced in (a), (c) mixing the gases obtained at the end of steps (a) and (b) and eliminating free oxygen from the mixture by reaction of the oxygen with hydrogen present in the mixture in the presence of a catalyst. The hydrocarbon may be burned in the presence of 1 to 3% excess air. The gas may contain hydrogen and/or carbon monoxide and/or methane. The hydrocarbon may be propane. Air is compressed in blower 2 and passed through flowmeter 4 to burner 5. Propane supplied at 8 is fed through coil 9 of vaporizer 10, through pressure regulating device 12, through flowmeter 6 into burner 5. From burner 5 the combustion gases are discharged into chamber 14 lined with refractory material which contains ammonia cracking device 16. The combustion gases pass into vaporizer 10 where they heat the water serving as heating fluid for the vaporizer coils and are themselves cooled, into coil 17 of water cooler 18 and into gasometer 20. Water trap 24 permits condensed water to be removed. Liquid ammonia introduced at 26 is vaporized in coil 27 of vaporizer 10, expanded in pressure regulating device 28, fed through flowmeter 30 and sent to ammonia cracking device 16 wherein ammonia is decomposed into hydrogen and nitrogen in the presence of a catalyst say based on iron or nickel by the heat produced in burning propane. The gas leaving the cracking device is mixed at 32 with the combustion gases leaving coil 17. The gas mixture is compressed in compressor 34 and passed to column 36 which is lined with rings over which trickles water supplied by pump 38. The water absorbs CO2 and leaves the column at 40. The gas mixture then enters apparatus 42 which contains a platinum group metal catalyst, e.g. a palladium catalyst which causes oxygen and hydrogen in the gas mixture to react. The catalyst may be heated to 300 DEG C. The gas mixture then passes through coil 43 of cooler 18 at the outlet of which an automatic purifier 44 discharges condensed water, and fed to adsorber 50 or 52 filled with say artificial zeolite to remove residual carbon dioxide and water. One of the adsorbers may be for purifying while the other is being regenerated. Regeneration may be effected by lowering the pressure by connecting the adsorber to the gasometer and flushing with a current of gas to be purified. Gases of the following composition may be obtained: 90% N2 + 10% H2; 98% N2 + 2% H2; 96% N2 4% CO; 96% N2 + 2% CO + 2% CH4. The carbon dioxide content may be less than 0.10%, and the dewpoint - 70 DEG C. A tank of solid caustic soda at the outlet of the adsorber or finishing the regeneration of the adsorbers in vacuo lowers the CO2 content further. Mixtures containing CO2 may be obtained by stopping the cracking of the ammonia and the operation of the adsorbers and by moderating or preventing the introduction of water into column 36. The gases may be used in metallurgical reactions such as bright annealing and cementation.
GB48661/64A 1963-12-13 1964-11-30 Improvements in or relating to the manufacture of a non-oxidizing gas Expired GB1040809A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR957115A FR1399584A (en) 1963-12-13 1963-12-13 Process for the production, from ammonia gas and fumes from the combustion of a hydrocarbon, of an inert or reducing atmosphere mainly containing nitrogen

Publications (1)

Publication Number Publication Date
GB1040809A true GB1040809A (en) 1966-09-01

Family

ID=8818806

Family Applications (1)

Application Number Title Priority Date Filing Date
GB48661/64A Expired GB1040809A (en) 1963-12-13 1964-11-30 Improvements in or relating to the manufacture of a non-oxidizing gas

Country Status (6)

Country Link
BE (1) BE656827A (en)
DE (1) DE1442899A1 (en)
ES (1) ES306902A1 (en)
FR (1) FR1399584A (en)
GB (1) GB1040809A (en)
NL (1) NL6414472A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2171984A (en) * 1985-03-04 1986-09-10 Boc Group Plc Separation of a gas mixture

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2171984A (en) * 1985-03-04 1986-09-10 Boc Group Plc Separation of a gas mixture
US4733526A (en) * 1985-03-04 1988-03-29 The Boc Group Plc Separation of gas mixture

Also Published As

Publication number Publication date
BE656827A (en) 1965-06-08
FR1399584A (en) 1965-05-21
ES306902A1 (en) 1965-04-01
NL6414472A (en) 1965-06-14
DE1442899A1 (en) 1969-12-11

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