GB1038432A - Novel oxidation catalyst compositions - Google Patents

Novel oxidation catalyst compositions

Info

Publication number
GB1038432A
GB1038432A GB241365A GB241365A GB1038432A GB 1038432 A GB1038432 A GB 1038432A GB 241365 A GB241365 A GB 241365A GB 241365 A GB241365 A GB 241365A GB 1038432 A GB1038432 A GB 1038432A
Authority
GB
United Kingdom
Prior art keywords
catalyst
oxidation catalyst
ag4p2o7
catalyst compositions
oxidation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB241365A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Goodrich Corp
Original Assignee
BF Goodrich Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BF Goodrich Corp filed Critical BF Goodrich Corp
Publication of GB1038432A publication Critical patent/GB1038432A/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/185—Phosphorus; Compounds thereof with iron group metals or platinum group metals
    • B01J27/1853—Phosphorus; Compounds thereof with iron group metals or platinum group metals with iron, cobalt or nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/16—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr
    • B01J27/18—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr with metals other than Al or Zr
    • B01J27/1802—Salts or mixtures of anhydrides with compounds of other metals than V, Nb, Ta, Cr, Mo, W, Mn, Tc, Re, e.g. phosphates, thiophosphates
    • B01J27/1817—Salts or mixtures of anhydrides with compounds of other metals than V, Nb, Ta, Cr, Mo, W, Mn, Tc, Re, e.g. phosphates, thiophosphates with copper, silver or gold
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C07C45/35—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Acrolein and methacrolein are produced from propylene and isobutylene respectively by oxidation at 400-600 DEG C. in the presence of a catalyst comprising Ag4P2O7, Cu2P2 O7 and Fe2(P2O7)3. Examples describe reaction conditions, starting material ratios and yields. If desired inert diluents e.g. steam, inert gases or alkanes may be used.ALSO:An oxidation catalyst comprises Ag4P2O7, Cu2P2O7 and Fe2(P2O7)3. The catalyst may be prepared conventionally and support on SiO2, diatomaceous earth, kieselguhr, clay alumina, silicon carbide or ZrO2. The catalyst, depending on mesh size may be used in fixed or fluidized beds.
GB241365A 1964-01-20 1965-01-20 Novel oxidation catalyst compositions Expired GB1038432A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US33857964A 1964-01-20 1964-01-20

Publications (1)

Publication Number Publication Date
GB1038432A true GB1038432A (en) 1966-08-10

Family

ID=23325321

Family Applications (1)

Application Number Title Priority Date Filing Date
GB241365A Expired GB1038432A (en) 1964-01-20 1965-01-20 Novel oxidation catalyst compositions

Country Status (7)

Country Link
BE (1) BE658501A (en)
CH (1) CH426759A (en)
DE (1) DE1266745B (en)
ES (1) ES308315A1 (en)
GB (1) GB1038432A (en)
NL (1) NL6500728A (en)
SE (1) SE320058B (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4742035A (en) * 1980-12-31 1988-05-03 The Standard Oil Co. Mixed metal phosphorus oxide catalysts for the oxidative dehydrogenation of carboxylic acids
US4864057A (en) * 1980-12-31 1989-09-05 Pedersen S Erik Dehydrogenation of carboxylic acids with mixed metal phosphorus oxide catalysts

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1137427B (en) * 1962-10-04 Knapsack Ag Process for the production of acrolein
BE617523A (en) *
FR1208444A (en) * 1957-06-21 1960-02-23 Bayer Ag Acrolein production process
DE1125901B (en) * 1959-12-19 1962-03-22 Knapsack Ag Process for the production of acrolein
AT225179B (en) * 1960-07-09 1963-01-10 Ruhrchemie Ag Process for the preparation of aliphatic unsaturated aldehydes
FR1303183A (en) * 1961-07-24 1962-09-07 Shell Int Research Process for preparing unsaturated aldehydes

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4742035A (en) * 1980-12-31 1988-05-03 The Standard Oil Co. Mixed metal phosphorus oxide catalysts for the oxidative dehydrogenation of carboxylic acids
US4864057A (en) * 1980-12-31 1989-09-05 Pedersen S Erik Dehydrogenation of carboxylic acids with mixed metal phosphorus oxide catalysts

Also Published As

Publication number Publication date
SE320058B (en) 1970-02-02
CH426759A (en) 1966-12-31
BE658501A (en) 1965-07-19
DE1266745B (en) 1968-04-25
NL6500728A (en) 1965-07-21
ES308315A1 (en) 1965-06-01

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