GB1037367A - A process for the production of solvent-resistant textile coatings - Google Patents
A process for the production of solvent-resistant textile coatingsInfo
- Publication number
- GB1037367A GB1037367A GB20985/65A GB2098565A GB1037367A GB 1037367 A GB1037367 A GB 1037367A GB 20985/65 A GB20985/65 A GB 20985/65A GB 2098565 A GB2098565 A GB 2098565A GB 1037367 A GB1037367 A GB 1037367A
- Authority
- GB
- United Kingdom
- Prior art keywords
- cross
- linking
- acid
- solvent
- condensation products
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
- D06M15/267—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof of unsaturated carboxylic esters having amino or quaternary ammonium groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0025—Crosslinking or vulcanising agents; including accelerators
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Paints Or Removers (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Phenolic Resins Or Amino Resins (AREA)
Abstract
Solvent-resistant textile coatings are prepared by applying to a textile a solution of a copolymer in an organic solvent, which copolymer contains 90 to 99% by weight of an ester of acrylic acid with a monohydric alcohol having 2 to 4 carbon atoms, 0.5 to 5% by weight of 2-hydroxy-n-propyl methacrylate and 0.5 to 5% by weight of acrylic acid and/or methacrylic acid in polymerized form and which solution contains a cross-linking agent which is able to react with the hydroxyl and/or carboxylic acid groups of the polymer to form a cross-linked product, and then reacting the polymer and cross-linking agent with each other. The copolymers used are preferably prepared by copolymerizing the appropriate monomers in solution in an organic solvent below 85 DEG C. using as initiator azodiisobutyronitrile, benzoyl peroxide, lauroyl peroxide, dichlorobenzoyl peroxide, t-butyl perisobutyrate, dicyclohexyl peroxy-dicarbonate or mixtures thereof, e.g. azodiisobutyronitrile plus benzoyl peroxide. Suitable cross-linking agents include condensation products of formaldehyde with urea, thiourea, ethylene or propylene urea, aminotriazines, e.g. melamine, guanamines and ethers thereof; di- and poly-isocyanates; masked isocyanates; polymers or copolymers containing optionally etherified N - methylol - acrylamide groupings; and phenol-formaldehyde condensation products. Cross-linking is preferably completed, during or after evaporation of the solvent, at 30 DEG to 150 DEG C. When formaldehyde condensation products are used for cross-linking, a free acid such as oxalic or maleic acid may be included in the coating compositions. The compositions may be pigmented with organic pigments or inorganic pigments, e.g. kaolin, titanium dioxide, iron oxide, chromium oxide and silica.ALSO:Solvent-resistant textile coatings are prepared by applying to a textile a solution of a copolymer in an organic solvent, which copolymer contains 90 to 99% by weight of an ester of acrylic acid with a monohydric alcohol having 2 to 4 carbon atoms, 0.5 to 5% by weight of 2-hydroxy-n-propyl methacrylate and 0.5 to 5% by weight of acrylic acid and/or methacrylic acid in polymerized form and which solution contains a cross-linking agent which is able to react with the hydroxyl and/or carboxylic acid groups of the polymer to form a cross-linked product, and then reacting the polymer and cross-linking agent with each other. Suitable cross-linking agents include condensation products of formaldehyde with urea, thiourea, ethylene or propylene urea, amino-triazines, e.g. melamine, quanamines and ethers thereof; di- and poly-isocyanates; masked isocyanates; polymers or copolymers containing optionally etherified N-methylol-acrylamide groupings; and phenol-formaldehyde condensation products. Cross-linking is preferably completed, during or after evaporation of the solvent, at 30 to 150 DEG C., for example by passing the coated fabric through an optionally heated drying panel. When formaldehyde condensation products are used for cross-linking, a free acid such as oxalic acid or maleic acid may be included in the coating compositions. The compositions may be pigmented with organic pigments or inorganic pigments, e.g. kaolin, titanium dioxide, iron oxide, chromium oxide and silica. Textiles which may be treated include cotton, polyamide, polyester and polyester-cotton fabrics, which may be coated with the polymer solutions by means of a floating knife or rubber blanket coater. More than one coating may be applied, and cotton or blended cotton fabrics may be calendered before or after the first coat is applied. The treated textiles may subsequently be coated with hydrophobic agents, e.g. silicone-based impregnating agents, and those based on paraffin or perfluorocarboxylic acid/chromium complexes, or hydrophobic agents modified by masked isocyanates.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEF42913A DE1247259B (en) | 1964-05-19 | 1964-05-19 | Process for the production of solvent-resistant textile coatings |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1037367A true GB1037367A (en) | 1966-07-27 |
Family
ID=7099317
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB20985/65A Expired GB1037367A (en) | 1964-05-19 | 1965-05-18 | A process for the production of solvent-resistant textile coatings |
Country Status (9)
Country | Link |
---|---|
AT (1) | AT252865B (en) |
BE (1) | BE662797A (en) |
DE (1) | DE1247259B (en) |
DK (1) | DK109637C (en) |
ES (1) | ES313006A1 (en) |
FR (1) | FR1433012A (en) |
GB (1) | GB1037367A (en) |
NL (1) | NL6506308A (en) |
SE (1) | SE308290B (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1989001500A1 (en) * | 1987-08-10 | 1989-02-23 | Desoto, Inc. | Thermosetting size press composition |
CN114438774A (en) * | 2022-03-08 | 2022-05-06 | 罗莱生活科技股份有限公司 | Self-cleaning cotton fiber and preparation method thereof |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3327016C2 (en) * | 1983-07-27 | 1986-09-25 | Mechanische Leinenweberei Laichingen Dr. R. Woernle GmbH & Co, 7903 Laichingen | Tarpaulin fabric and process for its manufacture |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1124465B (en) * | 1957-05-18 | 1962-03-01 | Roehm & Haas Gmbh | Process for synthetic resin finishing of textile structures |
-
1964
- 1964-05-19 DE DEF42913A patent/DE1247259B/en active Pending
-
1965
- 1965-03-24 AT AT265765A patent/AT252865B/en active
- 1965-04-21 BE BE662797D patent/BE662797A/xx not_active Expired
- 1965-04-23 FR FR14456A patent/FR1433012A/en not_active Expired
- 1965-05-03 SE SE5764/65A patent/SE308290B/xx unknown
- 1965-05-17 ES ES0313006A patent/ES313006A1/en not_active Expired
- 1965-05-18 NL NL6506308A patent/NL6506308A/xx unknown
- 1965-05-18 DK DK249065AA patent/DK109637C/en active
- 1965-05-18 GB GB20985/65A patent/GB1037367A/en not_active Expired
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1989001500A1 (en) * | 1987-08-10 | 1989-02-23 | Desoto, Inc. | Thermosetting size press composition |
CN114438774A (en) * | 2022-03-08 | 2022-05-06 | 罗莱生活科技股份有限公司 | Self-cleaning cotton fiber and preparation method thereof |
Also Published As
Publication number | Publication date |
---|---|
AT252865B (en) | 1967-03-10 |
ES313006A1 (en) | 1966-02-01 |
NL6506308A (en) | 1965-11-22 |
DE1247259B (en) | 1967-08-17 |
BE662797A (en) | 1965-08-17 |
SE308290B (en) | 1969-02-10 |
FR1433012A (en) | 1966-03-25 |
DK109637C (en) | 1968-05-27 |
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