GB1033948A - Treating synthetic polymer fibres, particularly acrylic fibres, to improve their light stability - Google Patents

Treating synthetic polymer fibres, particularly acrylic fibres, to improve their light stability

Info

Publication number
GB1033948A
GB1033948A GB44681/63A GB4468163A GB1033948A GB 1033948 A GB1033948 A GB 1033948A GB 44681/63 A GB44681/63 A GB 44681/63A GB 4468163 A GB4468163 A GB 4468163A GB 1033948 A GB1033948 A GB 1033948A
Authority
GB
United Kingdom
Prior art keywords
fibres
acrylonitrile
synthetic polymer
copolymer
salt
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB44681/63A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Monsanto Co
Original Assignee
Monsanto Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Monsanto Co filed Critical Monsanto Co
Publication of GB1033948A publication Critical patent/GB1033948A/en
Expired legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/70—Material containing nitrile groups
    • D06P3/76—Material containing nitrile groups using basic dyes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
    • C08K5/41—Compounds containing sulfur bound to oxygen
    • C08K5/42—Sulfonic acids; Derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/18—Homopolymers or copolymers of nitriles
    • C08L33/20—Homopolymers or copolymers of acrylonitrile
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F11/00—Chemical after-treatment of artificial filaments or the like during manufacture
    • D01F11/04—Chemical after-treatment of artificial filaments or the like during manufacture of synthetic polymers
    • D01F11/06—Chemical after-treatment of artificial filaments or the like during manufacture of synthetic polymers of macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/02—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D01F6/16—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds from polymers of unsaturated carboxylic acids or unsaturated organic esters, e.g. polyacrylic esters, polyvinyl acetate
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/02—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D01F6/18—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds from polymers of unsaturated nitriles, e.g. polyacrylonitrile, polyvinylidene cyanide
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/28—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D01F6/38—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds comprising unsaturated nitriles as the major constituent
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/44—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds
    • D01F6/54—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds of polymers of unsaturated nitriles
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
    • D06P1/5207—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • D06P1/525—Polymers of unsaturated carboxylic acids or functional derivatives thereof
    • D06P1/5257—(Meth)acrylic acid
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/62—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds with sulfate, sulfonate, sulfenic or sulfinic groups
    • D06P1/621—Compounds without nitrogen
    • D06P1/622—Sulfonic acids or their salts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Organic Chemistry (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Toxicology (AREA)
  • Artificial Filaments (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Chemical Treatment Of Fibers During Manufacturing Processes (AREA)

Abstract

1,033,948. Treating synthetic polymer fibres. MONSANTO CO. Nov. 12, 1963 [Nov. 19, 1962], No. 44681/63. Heading B5B. Synthetic polymer fibres which have been formed by a wet spinning process, particularly acrylic fibres, are treated while they are still in their gel state with a solution of a naphthalene disulphonic acid or of an alkali metal salt thereof. The fibres may be composed of at least 80% acrylonitrile and up to 20% of another mono-olefinic monomer copolymerizable therewith, e.g. a copolymer of 94% acrylonitrile and 6% vinyl acetate. They may be composed of a blend of 88% of a copolymer of 94% acrylonitrile and 6% vinyl acetate and 12% of a copolymer of 50% acrylonitrile and 50% methyl vinylpyridine, all percentages being by weight. The acrylic fibres may be wet spun in a conventional manner and may be treated with the sulphonic acid or its salt by the addition of the sulphonic acid or its salt to the conventional finish bath. The process stabilizes the fibres against ultra-violet light and improves their basic dye uptake.
GB44681/63A 1962-11-19 1963-11-12 Treating synthetic polymer fibres, particularly acrylic fibres, to improve their light stability Expired GB1033948A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US23878162A 1962-11-19 1962-11-19
US238736A US3281260A (en) 1962-11-19 1962-11-19 Process for treating acrylonitrile fibers with ultra-violet light stabilizer

Publications (1)

Publication Number Publication Date
GB1033948A true GB1033948A (en) 1966-06-22

Family

ID=26931909

Family Applications (2)

Application Number Title Priority Date Filing Date
GB44415/63A Expired GB1028867A (en) 1962-11-19 1963-11-11 Method for treating synthetic polymer fibres, particularly acrylic fibres, to improve their dyeing characteristics
GB44681/63A Expired GB1033948A (en) 1962-11-19 1963-11-12 Treating synthetic polymer fibres, particularly acrylic fibres, to improve their light stability

Family Applications Before (1)

Application Number Title Priority Date Filing Date
GB44415/63A Expired GB1028867A (en) 1962-11-19 1963-11-11 Method for treating synthetic polymer fibres, particularly acrylic fibres, to improve their dyeing characteristics

Country Status (10)

Country Link
US (1) US3281260A (en)
JP (1) JPS4815209B1 (en)
BE (2) BE640143A (en)
CH (2) CH437623A (en)
DE (2) DE1494666A1 (en)
DK (2) DK111426B (en)
GB (2) GB1028867A (en)
LU (2) LU44820A1 (en)
NL (2) NL300694A (en)
SE (2) SE317155B (en)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3380798A (en) * 1962-11-19 1968-04-30 Monsanto Co Preparation of dyeable acrylonitrile polymer fibers using 4, 4'-diaminostilbene-2, 2'-disulfonic acid
US3718428A (en) * 1970-12-21 1973-02-27 Gaf Corp Alcoholic composition of a cationic dye-alkyl aryl sulfonic acid complex and process of dyeing therewith
JPS5334572Y2 (en) * 1972-09-07 1978-08-25
JPS512556B2 (en) * 1972-11-14 1976-01-27
JPH01292112A (en) * 1988-02-10 1989-11-24 Basf Corp Stabilized polyacrylonitrile fiber and its production
JPH0219577A (en) * 1988-07-04 1990-01-23 Nippon Saafuakutanto Kogyo Kk Level dyeing agent composition for reactive dye
TW334457B (en) * 1994-01-21 1998-06-21 Dsm Nv Coloured polymer composition

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2210962A (en) * 1939-05-18 1940-08-13 Sharples Solvents Corp Sulphonic acids of aromatic compounds
US2423972A (en) * 1944-02-03 1947-07-15 Monsanto Chemicals Oleyl esters of sulphobenzoic acids
BE487570A (en) * 1947-09-04
US2597708A (en) * 1948-12-30 1952-05-20 American Cyanamid Co Antistatic agent, treatment of shaped articles therewith, and treated articles
US2626877A (en) * 1951-08-17 1953-01-27 American Cyanamid Co Treatment of articles comprising a vinyl resin with an antistatic agent and treated articles
BE512733A (en) * 1951-08-17 1900-01-01
BE565446A (en) * 1957-03-06
CH483276A (en) * 1959-09-23 1969-12-31 Ciba Geigy Use of 2-phenyl-benzazoles as a protective agent against ultraviolet radiation outside the textile industry

Also Published As

Publication number Publication date
US3281260A (en) 1966-10-25
LU44820A1 (en) 1964-05-15
DE1494666A1 (en) 1969-12-11
LU44821A1 (en) 1964-05-15
DK111426B (en) 1968-08-19
SE316564B (en) 1969-10-27
CH437623A (en) 1967-06-15
CH437624A (en) 1967-06-15
DE1494667A1 (en) 1970-12-03
SE317155B (en) 1969-11-10
BE640143A (en) 1964-05-19
NL300695A (en)
GB1028867A (en) 1966-05-11
JPS4815209B1 (en) 1973-05-12
DK111038B (en) 1968-05-13
BE640144A (en) 1964-05-19
NL300694A (en)

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