GB1033030A - Preparation of inorganic and organic salts - Google Patents
Preparation of inorganic and organic saltsInfo
- Publication number
- GB1033030A GB1033030A GB3018463A GB3018463A GB1033030A GB 1033030 A GB1033030 A GB 1033030A GB 3018463 A GB3018463 A GB 3018463A GB 3018463 A GB3018463 A GB 3018463A GB 1033030 A GB1033030 A GB 1033030A
- Authority
- GB
- United Kingdom
- Prior art keywords
- sodium
- amine
- acid
- anion exchanger
- prepared
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/41—Preparation of salts of carboxylic acids
- C07C51/412—Preparation of salts of carboxylic acids by conversion of the acids, their salts, esters or anhydrides with the same carboxylic acid part
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/0086—Processes carried out with a view to control or to change the pH-value; Applications of buffer salts; Neutralisation reactions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J47/00—Ion-exchange processes in general; Apparatus therefor
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/62—Methods of preparing sulfites in general
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B25/00—Phosphorus; Compounds thereof
- C01B25/16—Oxyacids of phosphorus; Salts thereof
- C01B25/26—Phosphates
- C01B25/30—Alkali metal phosphates
- C01B25/301—Preparation from liquid orthophosphoric acid or from an acid solution or suspension of orthophosphates
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B25/00—Phosphorus; Compounds thereof
- C01B25/16—Oxyacids of phosphorus; Salts thereof
- C01B25/46—Preparation involving solvent-solvent extraction
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
- C01D5/00—Sulfates or sulfites of sodium, potassium or alkali metals in general
- C01D5/14—Preparation of sulfites
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
A metal or ammonium salt of an acid HX which has a dissociation constant higher than 1 x 10-6 is prepared by reacting either HX in the presence of a water-insoluble weak base anion exchanger, or said anion exchanger in the form of a salt with HX, with a metal or ammonium salt of an acid HY, HY having a dissociation constant greater than that of HX. Specified acids HX are sulphurous and phosphoric acids, the metal salts of HY may be sodium chloride, nitrate or sulphate and other specified metal ions are Li, K and Cs. The anion exchanger may be a liquid amine containing 8-25 carbon atoms, and may be a tert.-alkyl primary amine, a secondary amine or a tertiary amine. Such liquid amines are preferably dissolved in an inert water-insoluble solvent, e.g. a hydrocarbon such as kerosene, in the concentration range 5-50%. Less desirably, solid anion exchangers, e.g. those prepared by chloromethylating and aminating a cross-linked aryl hydrocarbon polymer, particularly copolymers of styrene and divinyl benzene, or those prepared by the aminolysis of a cross-linked alkyl acrylate polymer, may be used. Sodium bisulphite may be prepared by agitating an aqueous solution of NaCl with a solvent solution of the amine present in e.g. 33% molar excess and bubbling SO2 through the mixture. The bisulphite may be recovered from the aqueous phase by evaporation, or converted to sodium sulphite by contacting the solution with the free base form of the amine. Sodium dihydrogen phosphate may be prepared by equilibrating phosphoric acid in, e.g., 30% solution with a 33% molar excess of amine and added the stoichiometric quantity of NaCl, or the three reagents may be mixed together. Partial conversion of NaH2PO4 to Na2HPO4 may be achieved by the process of the invention. The anion exchanger may be regenerated with sodium carbonate, sodium hydroxide or ammonia or, particularly in the case of the liquid resins, with an aqueous suspension of lime.ALSO:A metal or ammonium salt of an acid HX which has a dissociation constant higher than 1 x 10-6 is prepared by reacting either HX in the presence of a water-insoluble weak base anion exchanger, or said anion exchanger in the form of a salt with HX, with a metal or ammonium salt of an acid Hy, the dissociation constant of Hy being higher than that of HX. Examples describe the preparation of sodium acid tartrate, sodium citrate, sodium acid malate, sodium formate, sodium acetate and sodium succinate from stoichiometric amounts of sodium chloride solution and the appropriate acid using a 33% molar excess of the anion exchanger. Other metal salts of Hy may be sodium nitrate or sulphate. Other specified metal ions are Li, K and Cs. The anion exchanger may be a liquid amine having 8-25 carbon atoms, and may be a tert.-alkyl primary amine, or a secondary amine, or a tertiary amine. Such liquid amines are preferably dissolved in an inert water-insoluble solvent, e.g. a hydrocarbon such as kerosene, in a concentration of 5-50%. Less desirably solid anion exchangers may be used, e.g. those prepared by chloromethylating and aminating a cross-linked aryl hydrocarbon polymer particularly co-polymers of styrene and divinylbenzene, or those prepared by the aminolysis of a crosslinked alkyl acrylate polymer. The exchangers may be regenerated with sodium carbonate, sodium hydroxide, ammonia or, particularly in the case of the liquid exchangers, an aqueous suspension of lime.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US25522263A | 1963-01-31 | 1963-01-31 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1033030A true GB1033030A (en) | 1966-06-15 |
Family
ID=22967375
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB3018463A Expired GB1033030A (en) | 1963-01-31 | 1963-07-30 | Preparation of inorganic and organic salts |
Country Status (5)
Country | Link |
---|---|
BE (1) | BE638465A (en) |
CH (1) | CH439249A (en) |
ES (1) | ES291597A1 (en) |
GB (1) | GB1033030A (en) |
NL (1) | NL299016A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0248256A2 (en) * | 1986-06-04 | 1987-12-09 | Haifa Chemicals Ltd. | Process for the manufacture of monopotassium phosphate |
WO2000018717A1 (en) * | 1998-09-25 | 2000-04-06 | Kemira Chemicals Oy | Method for manufacturing alkali metal or alkaline-earth metal formate |
EP1659197A1 (en) * | 2004-11-18 | 2006-05-24 | Nederlandse Organisatie voor toegepast-natuurwetenschappelijk onderzoek TNO | Process for the recovery of acids |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3443889A (en) * | 1964-08-17 | 1969-05-13 | Kaiser Aluminium Chem Corp | Method of synthesis of alkali metal salts |
US3318867A (en) * | 1964-08-20 | 1967-05-09 | Upjohn Co | Process for separating nitrogen-basic materials from aqueous solution |
-
0
- NL NL299016D patent/NL299016A/xx unknown
- BE BE638465D patent/BE638465A/xx unknown
-
1963
- 1963-07-30 GB GB3018463A patent/GB1033030A/en not_active Expired
- 1963-09-12 ES ES291597A patent/ES291597A1/en not_active Expired
- 1963-10-10 CH CH1242563A patent/CH439249A/en unknown
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0248256A2 (en) * | 1986-06-04 | 1987-12-09 | Haifa Chemicals Ltd. | Process for the manufacture of monopotassium phosphate |
EP0248256A3 (en) * | 1986-06-04 | 1988-03-23 | Haifa Chemicals Ltd. | Process for the manufacture of monopotassium phosphate |
WO2000018717A1 (en) * | 1998-09-25 | 2000-04-06 | Kemira Chemicals Oy | Method for manufacturing alkali metal or alkaline-earth metal formate |
US6492551B1 (en) | 1998-09-25 | 2002-12-10 | Kemira Chemicals Oy | Method for manufacturing alkali metal or alkaline-earth metal formate |
EP1659197A1 (en) * | 2004-11-18 | 2006-05-24 | Nederlandse Organisatie voor toegepast-natuurwetenschappelijk onderzoek TNO | Process for the recovery of acids |
WO2006054893A2 (en) * | 2004-11-18 | 2006-05-26 | Nederlandse Organisatie Voor Toegepast-Natuurwetenschappelijk Onderzoek Tno | Process for the recovery of acids |
WO2006054893A3 (en) * | 2004-11-18 | 2006-07-06 | Schappelijk Onderzoek Tno Nl O | Process for the recovery of acids |
Also Published As
Publication number | Publication date |
---|---|
CH439249A (en) | 1967-07-15 |
NL299016A (en) | |
ES291597A1 (en) | 1964-01-01 |
BE638465A (en) |
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