GB1032945A - The preparation of heteroblock copolymers - Google Patents
The preparation of heteroblock copolymersInfo
- Publication number
- GB1032945A GB1032945A GB1214864A GB1214864A GB1032945A GB 1032945 A GB1032945 A GB 1032945A GB 1214864 A GB1214864 A GB 1214864A GB 1214864 A GB1214864 A GB 1214864A GB 1032945 A GB1032945 A GB 1032945A
- Authority
- GB
- United Kingdom
- Prior art keywords
- polymerization
- ethylene
- monomer
- carried out
- block copolymers
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
- C08F297/08—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
- C08F297/083—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins the monomers being ethylene or propylene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
- C08F297/08—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Graft Or Block Polymers (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
Block copolymers of ethylene with higher alpha-olefins are made by a process in which a first monomer is polymerized in a polymerization zone and is then transferred to another polymerization zone where it is contacted with a second monomer to add a further polymer block to it. The polymerization may be carried out in an apparatus consisting of two polymerization reactors through which the polymerized material is continuously circulated, polymerization of ethylene occuring in one reactor and polymerization of a different olefin in the other. The examples describe making ethylene-propylene block copolymers with the aid of a titanium trichloride-aluminium diethyl chloride catalyst, polymerization being carried out in the gaseous phase.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IT626163 | 1963-03-27 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1032945A true GB1032945A (en) | 1966-06-15 |
Family
ID=11120996
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB1214864A Expired GB1032945A (en) | 1963-03-27 | 1964-03-23 | The preparation of heteroblock copolymers |
Country Status (3)
Country | Link |
---|---|
GB (1) | GB1032945A (en) |
NL (1) | NL6402946A (en) |
SE (1) | SE320195B (en) |
Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0079000A1 (en) * | 1981-11-07 | 1983-05-18 | BASF Aktiengesellschaft | Process for the preparation of ethylene-propylene polymers of the block copolymer type |
EP0092099A2 (en) * | 1982-04-17 | 1983-10-26 | BASF Aktiengesellschaft | Process for the preparation of propene-ethene polymers of the so-called block polymer type |
EP0125590A2 (en) * | 1983-05-13 | 1984-11-21 | BASF Aktiengesellschaft | Process for the preparation of propylene ethylene polymers |
EP0125593A2 (en) * | 1983-05-13 | 1984-11-21 | BASF Aktiengesellschaft | Process for the preparation of a propylene-ethylene block polymer |
EP0131268A2 (en) * | 1983-07-09 | 1985-01-16 | BASF Aktiengesellschaft | Process for the preparation of propylene-ethylene block copolymers |
EP0355603A2 (en) * | 1988-08-13 | 1990-02-28 | BASF Aktiengesellschaft | Process for the preparation of propylene-ethylene copolymers of the type called shock-modified polypropylene |
US5147928A (en) * | 1989-02-11 | 1992-09-15 | Juergen Kerth | Preparation of propylene-ethylene copolymers |
US5218047A (en) * | 1990-06-19 | 1993-06-08 | Basf Aktiengesellschaft | Polymer blends of propylene copolymers and polyethylene |
EP0702038A1 (en) | 1994-09-15 | 1996-03-20 | BASF Aktiengesellschaft | Highly flexible propylene-ethylene copolymers |
US5519090A (en) * | 1991-06-12 | 1996-05-21 | Basf Aktiengesellschaft | High-flow blend of different propylene polymers |
EP0775713A2 (en) | 1995-11-21 | 1997-05-28 | Basf Aktiengesellschaft | Copolymers of propylene and C2-C10-alkenes |
EP0775714A2 (en) | 1995-11-21 | 1997-05-28 | Basf Aktiengesellschaft | Propylene copolymers |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2312511A1 (en) * | 1975-05-27 | 1976-12-24 | Naphtachimie Sa | DRY POLYMERIZATION OF OLEFINS IN SERIAL REACTORS |
-
1964
- 1964-03-19 NL NL6402946A patent/NL6402946A/xx unknown
- 1964-03-23 GB GB1214864A patent/GB1032945A/en not_active Expired
- 1964-03-26 SE SE3858/64A patent/SE320195B/xx unknown
Cited By (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0079000A1 (en) * | 1981-11-07 | 1983-05-18 | BASF Aktiengesellschaft | Process for the preparation of ethylene-propylene polymers of the block copolymer type |
US4455405A (en) * | 1981-11-07 | 1984-06-19 | Basf Aktiengesellschaft | Preparation of propylene/ethylene block copolymers |
EP0092099A2 (en) * | 1982-04-17 | 1983-10-26 | BASF Aktiengesellschaft | Process for the preparation of propene-ethene polymers of the so-called block polymer type |
US4454299A (en) * | 1982-04-17 | 1984-06-12 | Basf Aktiengesellschaft | Preparation of propylene/ethylene block copolymers |
EP0092099A3 (en) * | 1982-04-17 | 1985-07-03 | Basf Aktiengesellschaft | Process for the preparation of propene-ethene polymers of the so-called block polymer type |
EP0125590A3 (en) * | 1983-05-13 | 1985-07-03 | BASF Aktiengesellschaft | Process for the preparation of propylene ethylene polymers |
EP0125593A3 (en) * | 1983-05-13 | 1985-07-03 | BASF Aktiengesellschaft | Process for the preparation of a propylene-ethylene block polymer |
EP0125593A2 (en) * | 1983-05-13 | 1984-11-21 | BASF Aktiengesellschaft | Process for the preparation of a propylene-ethylene block polymer |
EP0125590A2 (en) * | 1983-05-13 | 1984-11-21 | BASF Aktiengesellschaft | Process for the preparation of propylene ethylene polymers |
EP0131268A2 (en) * | 1983-07-09 | 1985-01-16 | BASF Aktiengesellschaft | Process for the preparation of propylene-ethylene block copolymers |
EP0131268A3 (en) * | 1983-07-09 | 1985-07-03 | Basf Aktiengesellschaft | Process for the preparation of propylene-ethylene block copolymers |
EP0355603A3 (en) * | 1988-08-13 | 1991-11-27 | BASF Aktiengesellschaft | Process for the preparation of propylene-ethylene copolymers of the type called shock-modified polypropylene |
EP0355603A2 (en) * | 1988-08-13 | 1990-02-28 | BASF Aktiengesellschaft | Process for the preparation of propylene-ethylene copolymers of the type called shock-modified polypropylene |
US5147928A (en) * | 1989-02-11 | 1992-09-15 | Juergen Kerth | Preparation of propylene-ethylene copolymers |
US5218047A (en) * | 1990-06-19 | 1993-06-08 | Basf Aktiengesellschaft | Polymer blends of propylene copolymers and polyethylene |
US5519090A (en) * | 1991-06-12 | 1996-05-21 | Basf Aktiengesellschaft | High-flow blend of different propylene polymers |
EP0702038A1 (en) | 1994-09-15 | 1996-03-20 | BASF Aktiengesellschaft | Highly flexible propylene-ethylene copolymers |
EP0775713A2 (en) | 1995-11-21 | 1997-05-28 | Basf Aktiengesellschaft | Copolymers of propylene and C2-C10-alkenes |
EP0775714A2 (en) | 1995-11-21 | 1997-05-28 | Basf Aktiengesellschaft | Propylene copolymers |
Also Published As
Publication number | Publication date |
---|---|
NL6402946A (en) | 1964-09-28 |
SE320195B (en) | 1970-02-02 |
DE1520373B2 (en) | 1972-10-26 |
DE1520373A1 (en) | 1970-04-02 |
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