GB1032754A - Improvements in or relating to the steam reforming of hydrocarbons and catalysts therefor - Google Patents

Improvements in or relating to the steam reforming of hydrocarbons and catalysts therefor

Info

Publication number
GB1032754A
GB1032754A GB47453/62A GB4745362A GB1032754A GB 1032754 A GB1032754 A GB 1032754A GB 47453/62 A GB47453/62 A GB 47453/62A GB 4745362 A GB4745362 A GB 4745362A GB 1032754 A GB1032754 A GB 1032754A
Authority
GB
United Kingdom
Prior art keywords
catalyst
hydraulic binding
steam reforming
hydrocarbons
hydrocarbon
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB47453/62A
Inventor
Dennis Albert Dowden
Phineas Davies
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Imperial Chemical Industries Ltd
Original Assignee
Imperial Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Imperial Chemical Industries Ltd filed Critical Imperial Chemical Industries Ltd
Priority to GB47453/62A priority Critical patent/GB1032754A/en
Publication of GB1032754A publication Critical patent/GB1032754A/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/755—Nickel
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/40—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts characterised by the catalyst
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1005—Arrangement or shape of catalyst
    • C01B2203/1011—Packed bed of catalytic structures, e.g. particles, packing elements
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1047—Group VIII metal catalysts
    • C01B2203/1052—Nickel or cobalt catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1047—Group VIII metal catalysts
    • C01B2203/1064—Platinum group metal catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1076—Copper or zinc-based catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1082—Composition of support materials
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)

Abstract

In a process for the steam reforming of hydrocarbons boiling at temperatures up to 350 DEG C., the hydrocarbon is passed with steam at elevated temperature over a catalyst comprising Ni and/or one or more platinum group metals, from 2-49% of Cu, Ag or An or a compound thereof and a refractory support material. Additionally the catalyst may contain an hydraulic binding agent. The hydrocarbon may be normally liquid having B.pt 30-220 DEG C. or a liquefied petroleum gas. Preferably they contain no or at most 5% aromatics. Examples are given in which petroleum naphtha B.pt 30-170 DEG C. is reformed at S.V. 10 liquid v/v catalyst/hours and a stream ratio of 5.ALSO:A hydroforming catalyst comprises Ni and/or one or more Pt group metals, form 2-4% of Cu, Ag or Au or a compound thereof and a refractory support comprising at least in part a hydraulic binding agent. Refractory supports are defined as oxides Be, Mg, Ca, Sr, Ba, Al, Ce, Si, Ti, Zr, Th, V, W, Mu or Cr. Hydraulic binding agents mentioned are "Ciment Fondu" (Registered Trade Mark) and Portland Cement. Examples are given.
GB47453/62A 1962-12-17 1962-12-17 Improvements in or relating to the steam reforming of hydrocarbons and catalysts therefor Expired GB1032754A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB47453/62A GB1032754A (en) 1962-12-17 1962-12-17 Improvements in or relating to the steam reforming of hydrocarbons and catalysts therefor

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB47453/62A GB1032754A (en) 1962-12-17 1962-12-17 Improvements in or relating to the steam reforming of hydrocarbons and catalysts therefor

Publications (1)

Publication Number Publication Date
GB1032754A true GB1032754A (en) 1966-06-15

Family

ID=10445021

Family Applications (1)

Application Number Title Priority Date Filing Date
GB47453/62A Expired GB1032754A (en) 1962-12-17 1962-12-17 Improvements in or relating to the steam reforming of hydrocarbons and catalysts therefor

Country Status (1)

Country Link
GB (1) GB1032754A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4060498A (en) * 1972-06-02 1977-11-29 Hitachi, Ltd. Process for steam reforming of hydrocarbons
EP0640560A1 (en) * 1993-08-27 1995-03-01 Haldor Topsoe A/S Process for the steam reforming of hydrocarbons
EP0884274A1 (en) * 1997-06-10 1998-12-16 Haldor Topsoe A/S Process for steam reforming of hydrocarbons
EP1486577A1 (en) * 2003-06-12 2004-12-15 Haldor Topsoe A/S Fuel cell and anode
EP1759764A1 (en) * 2005-08-11 2007-03-07 Toda Kogyo Corporation Catalyst containing alumina, Cerium and more than 10% (expressed as oxide) by weight of either Strontium and/or Barium for treating NOx-containing exhaust gas.

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4060498A (en) * 1972-06-02 1977-11-29 Hitachi, Ltd. Process for steam reforming of hydrocarbons
EP0640560A1 (en) * 1993-08-27 1995-03-01 Haldor Topsoe A/S Process for the steam reforming of hydrocarbons
AU673451B2 (en) * 1993-08-27 1996-11-07 Haldor Topsoe A/S Process for the steam reforming of hydrocarbons
EP0884274A1 (en) * 1997-06-10 1998-12-16 Haldor Topsoe A/S Process for steam reforming of hydrocarbons
AU738898B2 (en) * 1997-06-10 2001-09-27 Haldor Topsoe A/S Process for steam reforming of hydrocarbons
EP1486577A1 (en) * 2003-06-12 2004-12-15 Haldor Topsoe A/S Fuel cell and anode
EP1759764A1 (en) * 2005-08-11 2007-03-07 Toda Kogyo Corporation Catalyst containing alumina, Cerium and more than 10% (expressed as oxide) by weight of either Strontium and/or Barium for treating NOx-containing exhaust gas.

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