GB1006779A - Resin compositions - Google Patents
Resin compositionsInfo
- Publication number
- GB1006779A GB1006779A GB2978962A GB2978962A GB1006779A GB 1006779 A GB1006779 A GB 1006779A GB 2978962 A GB2978962 A GB 2978962A GB 2978962 A GB2978962 A GB 2978962A GB 1006779 A GB1006779 A GB 1006779A
- Authority
- GB
- United Kingdom
- Prior art keywords
- monomer
- weight
- parts
- epoxy
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F20/62—Monocarboxylic acids having ten or more carbon atoms; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D157/00—Coating compositions based on unspecified polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Paints Or Removers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Paper (AREA)
Abstract
A composition comprises (a) at least 50 parts by weight of an interpolymer of a monomer mixture consisting of (1) 2-30% by weight of at least one acid monomer of the formula: <FORM:1006779/C3/1> where R is hydrogen, a halogen atom or an alkyl group containing 1 to 4 carbon atoms, (2) 2-40% by weight of a nitrile monomer selected from acrylonitrile, methacrylonitrile and mixtures thereof, and (3) the balance at least one ethylenically unsaturated monomer interpolymerizable with said acid monomer and said nitrile monomer, and (b) less than 50 parts by weight of an epoxy compound containing a plurality of epoxy groups of the structure: <FORM:1006779/C3/2> said component (b) being present in an amount sufficient to provide an average of at least 0.4 epoxy group per carboxyl group of component (a). Monomer (1) is preferably acrylic or methacrylic acid and monomer (3) is exemplified by one or more of styrene, methyl methacrylate, ethyl acrylate, vinyl butyl ether, and vinyl methyl ketone. Epoxy compounds exemplified are an epichlorohydrin bisphenol A condensate, the diglycidyl ether of bisphenol A, the triglycidyl ether of glycerine, and the diglycidyl ether of ethylene glycol. The compositions are preferably used in the form of solutions in organic solvents, although a moulding powder comprising 50 parts of wood flour, 10 parts of epoxy compound, and 50 parts of acrylic acid terpolymer is exemplified. Other ingredients such as titanium dioxide and etherified amino-plast resins may be included. The acrylic acid terpolymer is preferably made by a process which comprises adding a mixture of the said monomers to an organic solvent maintained at a temperature of at least 80 DEG C. in the presence of at least 0.25% by weight (calculated on the total weight of monomers) of a monomer-soluble free-radical-generating catalyst, the rate of addition of the said monomers being such that the monomers are polymerized at substantially the rate at which they are being added to the solvent. Specified initiators are tertiary butyl perbenzoate ditertiary butyl peroxide and benzoyl peroxide. Polymerization may take place in the presence of sulphur dioxide or a diene sulphone.ALSO:Metal surfaces, particularly phosphatized or untreated steel panels, paper, cardboard, leather, glass, porcelain &c. may be coated with, or webs of paper or fabric, particularly glass fibre fabric, may be impregnated with a composition comprising (a) at least 50 parts by weight of an interpolymer of a monomer mixture consisting of (1) 2-30% by weight of at least one acid monomer of the formula: <FORM:1006779/B1-B2/1> where R is hydrogen, a halogen atom or an alkyl group containing 1-4 carbon atoms, (2) 2-40% by weight of a nitrile monomer selected from acrylonitrile, methacrylonitrile or mixtures thereof, and (3) the balance at least one ethylenically unsaturated monomer interpolymerizable with said acid monomer and said nitrile monomer, and (b) less than 50 parts by weight of an epoxy compound containing a plurality of epoxy groups of the structure: <FORM:1006779/B1-B2/2> said component (b) being present in an amount sufficient to provide an average of at least 0,4 epoxy group per carboxyl group of component (a). Monomer (1) is preferably acrylic or methacrylic acid and monomer (3) is exemplified by one or more of styrene, methyl methacrylate, ethyl acrylate, vinyl butyl ether, and vinyl methyl ketone. The compositions are preferably sprayed on to the substrate in the form of solutions in conventional organic solvents. Fillers and pigments such as titanium dioxide may be present.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US12900761A | 1961-08-03 | 1961-08-03 | |
US12895061A | 1961-08-03 | 1961-08-03 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1006779A true GB1006779A (en) | 1965-10-06 |
Family
ID=26827103
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB2978962A Expired GB1006779A (en) | 1961-08-03 | 1962-08-02 | Resin compositions |
Country Status (3)
Country | Link |
---|---|
DE (1) | DE1233590B (en) |
FR (1) | FR1333272A (en) |
GB (1) | GB1006779A (en) |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL227404A (en) * | 1957-05-01 |
-
1962
- 1962-08-02 GB GB2978962A patent/GB1006779A/en not_active Expired
- 1962-08-02 DE DEM53780A patent/DE1233590B/en active Pending
- 1962-08-03 FR FR906034A patent/FR1333272A/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
DE1233590B (en) | 1967-02-02 |
FR1333272A (en) | 1963-07-26 |
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