GB1005377A - Aqueous emulsions of acrylic ester copolymers - Google Patents
Aqueous emulsions of acrylic ester copolymersInfo
- Publication number
- GB1005377A GB1005377A GB216463A GB216463A GB1005377A GB 1005377 A GB1005377 A GB 1005377A GB 216463 A GB216463 A GB 216463A GB 216463 A GB216463 A GB 216463A GB 1005377 A GB1005377 A GB 1005377A
- Authority
- GB
- United Kingdom
- Prior art keywords
- acrylic acid
- butyl acrylate
- allyl
- acrylate
- mono
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F28/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a bond to sulfur or by a heterocyclic ring containing sulfur
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
Abstract
Aqueous copolymer emulsions are obtained by polymerizing, in aqueous emulsion or dispersion, a monomer mixture comprising at least 15% by weight of one or more acrylate esters of the formula CH2=CH-COOR where R is an alkyl group containing from 1 to 10 carbon atoms or a substituted alkyl group containing from 1 to 12 carbon atoms; 0.02 to 5.0% by weight of a substance capable of yielding in aqueous solution an anion of the formula <FORM:1005377/C3/1> where R1 is hydrogen or a methyl group; the remainder, if any, of the monomer mixture being one or more ethylenically unsaturated monomers copolymerizable with the other components. Where the aforementioned acrylate ester comprises a substituted alkyl group, the substituent may be an aryl, carboalkoxy, hydroxy, cyano, halo, nitro, amido, amino, aryloxy, alkoxy or polyalkoxy group. The substance yielding the specified anion is generally an alkali metal or ammonium salt of mono-allyl or mono-methallyl sulphosuccinate. Optional comonomers include vinyl esters; alkyl a -substituted acrylates; acrylonitrile and methacrylonitrile; styrene and substituted styrene; vinyl chloride and vinylidene chloride; acrylamide and methacrylamide; ethylenically unsaturated carboxylic acids, such as acrylic, methacrylic and itaconic acids; and mono- and di-alkyl itaconates, maleates and fumarates. The polymerization is effected with the aid of initiators such as salts of perdisulphuric acid, e.g. ammonium persulphate, organic peroxides or hydroperoxides, hydrogen peroxide, and azo compounds such as azo diisobutyronitrile; these can be used in conjunction with reducing agents such as sulphites and bisulphites, sulphoxylates, polyamines and ferrous iron complexes. Conventional anionic or non-ionic surfactants or emulsifiers may be used for the emulsion polymerization process. Other ingredients which may be present are electrolytes, pH adjusters, sequestering agents for polyvalent metal-ions, plasticizers, solvents and molecular weight modifiers. The monomers used may be added in portions or continuously during polymerization in order to obtain better control of the reaction and of the copolymer particle size. Films and laminar articles can be cast from the copolymer emulsions. Examples describe the preparation of emulsions of copolymers of disodium allyl sulphosuccinate with (i) n-butyl acrylate, acrylonitrile and acrylic acid, (ii) n-butyl acrylate and acrylic acid, (iii) n-butyl acrylate, (iv) 2-ethylhexyl acrylate and acrylic acid, (v) n-butyl acrylate, styrene and acrylic acid, (vi) n-butyl acrylate, methyl methacrylate and acrylic acid, (vii) n-butyl acrylate, vinyl acetate and acrylic acid.ALSO:Salts of monoallyl or monomethallyl sulphosuccinates are prepared by esterifying maleic anhydride with one, or a little more than one, molecular proportion of allyl or methallyl alcohol and then adding to the monoester an aqueous solution of a bisulphite or sulphite, e.g. an alkali metal or ammonium bisulphite or sulphite. An example describes the preparation of disodium allyl sulphosuccinate. The salts are used in the preparation of emulsion copolymers (see Division C3).
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB216463A GB1005377A (en) | 1963-01-17 | 1963-01-17 | Aqueous emulsions of acrylic ester copolymers |
BE642185A BE642185A (en) | 1963-01-17 | 1964-01-07 | |
DE19641520682 DE1520682B2 (en) | 1963-01-17 | 1964-01-15 | Process for the preparation of alkyl acrylate copolymers |
CH41864A CH434754A (en) | 1963-01-17 | 1964-01-15 | Emulsion of a copolymer and process for preparing such an emulsion |
NL6400227A NL6400227A (en) | 1963-01-17 | 1964-01-15 | |
FR960671A FR1394790A (en) | 1963-01-17 | 1964-01-17 | Improvements relating to olefinic polymer compositions |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB216463A GB1005377A (en) | 1963-01-17 | 1963-01-17 | Aqueous emulsions of acrylic ester copolymers |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1005377A true GB1005377A (en) | 1965-09-22 |
Family
ID=9734707
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB216463A Expired GB1005377A (en) | 1963-01-17 | 1963-01-17 | Aqueous emulsions of acrylic ester copolymers |
Country Status (5)
Country | Link |
---|---|
BE (1) | BE642185A (en) |
CH (1) | CH434754A (en) |
DE (1) | DE1520682B2 (en) |
GB (1) | GB1005377A (en) |
NL (1) | NL6400227A (en) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3922464A (en) * | 1972-05-26 | 1975-11-25 | Minnesota Mining & Mfg | Removable pressure-sensitive adhesive sheet material |
US4604414A (en) * | 1983-03-31 | 1986-08-05 | Sumitomo Chemical Company, Limited | Antistatic acrylic resin composition and method for the production thereof |
-
1963
- 1963-01-17 GB GB216463A patent/GB1005377A/en not_active Expired
-
1964
- 1964-01-07 BE BE642185A patent/BE642185A/xx unknown
- 1964-01-15 NL NL6400227A patent/NL6400227A/xx unknown
- 1964-01-15 DE DE19641520682 patent/DE1520682B2/en active Pending
- 1964-01-15 CH CH41864A patent/CH434754A/en unknown
Also Published As
Publication number | Publication date |
---|---|
CH434754A (en) | 1967-04-30 |
DE1520682A1 (en) | 1969-04-17 |
DE1520682B2 (en) | 1971-01-21 |
BE642185A (en) | 1964-05-04 |
NL6400227A (en) | 1964-07-20 |
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