GB1003346A - Method for the preparation of ª‰-hydroxy lower alkyl acrylates and methacrylates - Google Patents

Method for the preparation of ª‰-hydroxy lower alkyl acrylates and methacrylates

Info

Publication number
GB1003346A
GB1003346A GB20805/63A GB2080563A GB1003346A GB 1003346 A GB1003346 A GB 1003346A GB 20805/63 A GB20805/63 A GB 20805/63A GB 2080563 A GB2080563 A GB 2080563A GB 1003346 A GB1003346 A GB 1003346A
Authority
GB
United Kingdom
Prior art keywords
oxide
acrylate
methacrylates
preparation
lower alkyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB20805/63A
Inventor
Charles Roy Bearden
Sampse Richard Horgis
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Chemical Co
Original Assignee
Dow Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to BE632940D priority Critical patent/BE632940A/xx
Priority to NL136048D priority patent/NL136048C/xx
Application filed by Dow Chemical Co filed Critical Dow Chemical Co
Priority to GB20805/63A priority patent/GB1003346A/en
Publication of GB1003346A publication Critical patent/GB1003346A/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/06—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing polymers
    • B01J31/08—Ion-exchange resins
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/24—Preparation of carboxylic acid esters by reacting carboxylic acids or derivatives thereof with a carbon-to-oxygen ether bond, e.g. acetal, tetrahydrofuran
    • C07C67/26—Preparation of carboxylic acid esters by reacting carboxylic acids or derivatives thereof with a carbon-to-oxygen ether bond, e.g. acetal, tetrahydrofuran with an oxirane ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/40—Substitution reactions at carbon centres, e.g. C-C or C-X, i.e. carbon-hetero atom, cross-coupling, C-H activation or ring-opening reactions
    • B01J2231/48—Ring-opening reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/40—Substitution reactions at carbon centres, e.g. C-C or C-X, i.e. carbon-hetero atom, cross-coupling, C-H activation or ring-opening reactions
    • B01J2231/49—Esterification or transesterification
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235—Nitrogen containing compounds
    • B01J31/0239—Quaternary ammonium compounds
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

b -Hydroxyalkyl esters of acrylic or methacrylic acids are made by the esterification of the corresponding acid with an alkylene oxide preferably C2 to C4 in the presence of a quaternary ammonium group containing anion exchange resins, the moisture content of which is not in excess of 40% wt/wt. The alkylene oxide may contain a halogen atom or an aromatic nucleus and preferred materials include ethylene oxide, propylene oxide, styrene oxide epichlorohydrins. The examples describe the syntheses of b -hydroxy ethyl acrylate and methacrylate, b -hydroxypropyl acrylate, 3-chloro - 2 - hydroxypropyl acrylate and 2-phenyl-2-hydroxyethyl acrylate.
GB20805/63A 1963-05-24 1963-05-24 Method for the preparation of ª‰-hydroxy lower alkyl acrylates and methacrylates Expired GB1003346A (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
BE632940D BE632940A (en) 1963-05-24
NL136048D NL136048C (en) 1963-05-24
GB20805/63A GB1003346A (en) 1963-05-24 1963-05-24 Method for the preparation of ª‰-hydroxy lower alkyl acrylates and methacrylates

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB20805/63A GB1003346A (en) 1963-05-24 1963-05-24 Method for the preparation of ª‰-hydroxy lower alkyl acrylates and methacrylates

Publications (1)

Publication Number Publication Date
GB1003346A true GB1003346A (en) 1965-09-02

Family

ID=10151971

Family Applications (1)

Application Number Title Priority Date Filing Date
GB20805/63A Expired GB1003346A (en) 1963-05-24 1963-05-24 Method for the preparation of ª‰-hydroxy lower alkyl acrylates and methacrylates

Country Status (3)

Country Link
BE (1) BE632940A (en)
GB (1) GB1003346A (en)
NL (1) NL136048C (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4069242A (en) 1969-02-06 1978-01-17 The Dow Chemical Company Process for preparation of β-hydroxy esters by reaction of organic carboxylic acids and vicinal epoxides
EP1029847A1 (en) * 1999-02-17 2000-08-23 Nippon Shokubai Co., Ltd. Process for producing hydroxyalkyl (meth)acrylates
US6660881B2 (en) * 2000-08-18 2003-12-09 Nippon Shokubai Co., Ltd. Process for producing (meth)acrylic ester

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4069242A (en) 1969-02-06 1978-01-17 The Dow Chemical Company Process for preparation of β-hydroxy esters by reaction of organic carboxylic acids and vicinal epoxides
EP1029847A1 (en) * 1999-02-17 2000-08-23 Nippon Shokubai Co., Ltd. Process for producing hydroxyalkyl (meth)acrylates
US6384267B1 (en) 1999-02-17 2002-05-07 Nippon Shokubai Co., Ltd. Process for producing hydroxyalkyl (METH) acrylates
US6660881B2 (en) * 2000-08-18 2003-12-09 Nippon Shokubai Co., Ltd. Process for producing (meth)acrylic ester

Also Published As

Publication number Publication date
BE632940A (en) 1900-01-01
NL136048C (en) 1900-01-01

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