GB1003346A - Method for the preparation of ª‰-hydroxy lower alkyl acrylates and methacrylates - Google Patents
Method for the preparation of ª‰-hydroxy lower alkyl acrylates and methacrylatesInfo
- Publication number
- GB1003346A GB1003346A GB20805/63A GB2080563A GB1003346A GB 1003346 A GB1003346 A GB 1003346A GB 20805/63 A GB20805/63 A GB 20805/63A GB 2080563 A GB2080563 A GB 2080563A GB 1003346 A GB1003346 A GB 1003346A
- Authority
- GB
- United Kingdom
- Prior art keywords
- oxide
- acrylate
- methacrylates
- preparation
- lower alkyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/40—Regeneration or reactivation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/06—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing polymers
- B01J31/08—Ion-exchange resins
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/24—Preparation of carboxylic acid esters by reacting carboxylic acids or derivatives thereof with a carbon-to-oxygen ether bond, e.g. acetal, tetrahydrofuran
- C07C67/26—Preparation of carboxylic acid esters by reacting carboxylic acids or derivatives thereof with a carbon-to-oxygen ether bond, e.g. acetal, tetrahydrofuran with an oxirane ring
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/40—Substitution reactions at carbon centres, e.g. C-C or C-X, i.e. carbon-hetero atom, cross-coupling, C-H activation or ring-opening reactions
- B01J2231/48—Ring-opening reactions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/40—Substitution reactions at carbon centres, e.g. C-C or C-X, i.e. carbon-hetero atom, cross-coupling, C-H activation or ring-opening reactions
- B01J2231/49—Esterification or transesterification
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
- B01J31/0235—Nitrogen containing compounds
- B01J31/0239—Quaternary ammonium compounds
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/584—Recycling of catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
b -Hydroxyalkyl esters of acrylic or methacrylic acids are made by the esterification of the corresponding acid with an alkylene oxide preferably C2 to C4 in the presence of a quaternary ammonium group containing anion exchange resins, the moisture content of which is not in excess of 40% wt/wt. The alkylene oxide may contain a halogen atom or an aromatic nucleus and preferred materials include ethylene oxide, propylene oxide, styrene oxide epichlorohydrins. The examples describe the syntheses of b -hydroxy ethyl acrylate and methacrylate, b -hydroxypropyl acrylate, 3-chloro - 2 - hydroxypropyl acrylate and 2-phenyl-2-hydroxyethyl acrylate.
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
BE632940D BE632940A (en) | 1963-05-24 | ||
NL136048D NL136048C (en) | 1963-05-24 | ||
GB20805/63A GB1003346A (en) | 1963-05-24 | 1963-05-24 | Method for the preparation of ª‰-hydroxy lower alkyl acrylates and methacrylates |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB20805/63A GB1003346A (en) | 1963-05-24 | 1963-05-24 | Method for the preparation of ª‰-hydroxy lower alkyl acrylates and methacrylates |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1003346A true GB1003346A (en) | 1965-09-02 |
Family
ID=10151971
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB20805/63A Expired GB1003346A (en) | 1963-05-24 | 1963-05-24 | Method for the preparation of ª‰-hydroxy lower alkyl acrylates and methacrylates |
Country Status (3)
Country | Link |
---|---|
BE (1) | BE632940A (en) |
GB (1) | GB1003346A (en) |
NL (1) | NL136048C (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4069242A (en) | 1969-02-06 | 1978-01-17 | The Dow Chemical Company | Process for preparation of β-hydroxy esters by reaction of organic carboxylic acids and vicinal epoxides |
EP1029847A1 (en) * | 1999-02-17 | 2000-08-23 | Nippon Shokubai Co., Ltd. | Process for producing hydroxyalkyl (meth)acrylates |
US6660881B2 (en) * | 2000-08-18 | 2003-12-09 | Nippon Shokubai Co., Ltd. | Process for producing (meth)acrylic ester |
-
0
- NL NL136048D patent/NL136048C/xx active
- BE BE632940D patent/BE632940A/xx unknown
-
1963
- 1963-05-24 GB GB20805/63A patent/GB1003346A/en not_active Expired
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4069242A (en) | 1969-02-06 | 1978-01-17 | The Dow Chemical Company | Process for preparation of β-hydroxy esters by reaction of organic carboxylic acids and vicinal epoxides |
EP1029847A1 (en) * | 1999-02-17 | 2000-08-23 | Nippon Shokubai Co., Ltd. | Process for producing hydroxyalkyl (meth)acrylates |
US6384267B1 (en) | 1999-02-17 | 2002-05-07 | Nippon Shokubai Co., Ltd. | Process for producing hydroxyalkyl (METH) acrylates |
US6660881B2 (en) * | 2000-08-18 | 2003-12-09 | Nippon Shokubai Co., Ltd. | Process for producing (meth)acrylic ester |
Also Published As
Publication number | Publication date |
---|---|
BE632940A (en) | 1900-01-01 |
NL136048C (en) | 1900-01-01 |
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