GB1000522A - Novel esters and their use as perfumery components - Google Patents
Novel esters and their use as perfumery componentsInfo
- Publication number
- GB1000522A GB1000522A GB1618263A GB1618263A GB1000522A GB 1000522 A GB1000522 A GB 1000522A GB 1618263 A GB1618263 A GB 1618263A GB 1618263 A GB1618263 A GB 1618263A GB 1000522 A GB1000522 A GB 1000522A
- Authority
- GB
- United Kingdom
- Prior art keywords
- compounds
- reaction
- methyl
- acrylate
- hydrogen
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B9/00—Essential oils; Perfumes
- C11B9/0026—Essential oils; Perfumes compounds containing an alicyclic ring not condensed with another ring
- C11B9/0034—Essential oils; Perfumes compounds containing an alicyclic ring not condensed with another ring the ring containing six carbon atoms
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Fats And Perfumes (AREA)
Abstract
The invention consists of compounds having the general formula <FORM:1000522/C2/1> in which R1, R2 and R3 are the same different and are hydrogen or methyl, n is one or two, and the symbols R represent independently either a hydrogen atom or with the adjacent symbol R, a single bond and especially the compounds wherein the group <FORM:1000522/C2/2> is acrylyl, methacrylyl, angelyl, tiglyl, crotonyl or seneciyl, and the group <FORM:1000522/C2/3> is isopropylcyclohexylmethyl, perillyl, cuminyl or 2 - (4 - iso - propenyl - 1 - cyclohex - 1 - enyl) ethyl. The compounds are made by reaction of the alcohol of the formula <FORM:1000522/C2/4> with a compound of the formula <FORM:1000522/C2/5> in which X is a chlorine or bromine atom, hydroxyl or a lower alkoxyl radical and particularly by the reaction of the alcohol with an acid chloride or bromide in an inert solvent medium and in the presence of sufficient of a tertiary organic base to combine with a hydrochloric acid formed in the reaction, or by the reaction of the alcohol with an ester at the boiling point in the presence of a transesterification catalyst, preferably in the presence of a polymerization inhibitor. In the examples the following compounds are prepared: cuminyl acrylate and methacrylate, 4-isopropyl crylohexyl-methyl acrylate methacrylate, crotonate; perillyl acrylate, crotonate, methacrylate, 2-methyl but-2-enoate; homoperillyl acrylate. The stabilizer employed in the preparation is hydroquinone.ALSO:Perfumery compositions comprise one or more of the compounds of the general formula <FORM:1000522/A5-A6/1> in which R1, R2 and R3 are the same or different and are hydrogen or methyl, n is one or two and R represent independently either hydrogen or with an adjacent R, a single bond, or with other perfumes together with any of the conventional adjuvants e.g. organic or aqueous solvents.
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR895545A FR1329008A (en) | 1962-04-25 | 1962-04-25 | New esters of perillic alcohol |
FR928313A FR1359789A (en) | 1963-03-18 | 1963-03-18 | New cuminyl esters |
FR928797A FR1359884A (en) | 1963-03-21 | 1963-03-21 | New esters of 4-isopropyl cyclohexylmethyl |
FR930290A FR1363955A (en) | 1963-04-03 | 1963-04-03 | Homoperillyl alken-2 oates |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1000522A true GB1000522A (en) | 1965-08-04 |
Family
ID=27445419
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB1618263A Expired GB1000522A (en) | 1962-04-25 | 1963-04-24 | Novel esters and their use as perfumery components |
Country Status (3)
Country | Link |
---|---|
CH (1) | CH435520A (en) |
DE (1) | DE1203256B (en) |
GB (1) | GB1000522A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2017197444A (en) * | 2016-04-25 | 2017-11-02 | 国立研究開発法人農業・食品産業技術総合研究機構 | Ferrisia virgata sex attractant |
CN109071726A (en) * | 2016-06-03 | 2018-12-21 | 可泰克斯公司 | Copolymer with thickening and suspension property |
-
1963
- 1963-04-24 CH CH514163A patent/CH435520A/en unknown
- 1963-04-24 GB GB1618263A patent/GB1000522A/en not_active Expired
- 1963-04-25 DE DE1963R0035024 patent/DE1203256B/en active Pending
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2017197444A (en) * | 2016-04-25 | 2017-11-02 | 国立研究開発法人農業・食品産業技術総合研究機構 | Ferrisia virgata sex attractant |
CN109071726A (en) * | 2016-06-03 | 2018-12-21 | 可泰克斯公司 | Copolymer with thickening and suspension property |
US10835475B2 (en) | 2016-06-03 | 2020-11-17 | Coatex | Copolymer having thickening and suspension properties |
CN109071726B (en) * | 2016-06-03 | 2021-07-16 | 可泰克斯公司 | Copolymers with thickening and suspending properties |
Also Published As
Publication number | Publication date |
---|---|
CH435520A (en) | 1967-05-15 |
DE1203256B (en) | 1965-10-21 |
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