GB1000322A - Mass polymerisation process - Google Patents

Mass polymerisation process

Info

Publication number
GB1000322A
GB1000322A GB3515963A GB3515963A GB1000322A GB 1000322 A GB1000322 A GB 1000322A GB 3515963 A GB3515963 A GB 3515963A GB 3515963 A GB3515963 A GB 3515963A GB 1000322 A GB1000322 A GB 1000322A
Authority
GB
United Kingdom
Prior art keywords
vinyl chloride
monomeric material
polymer
lauroyl
specified
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3515963A
Inventor
Lyle Eugene Perrins
Frank Bebbington
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Imperial Chemical Industries Ltd
Original Assignee
Imperial Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Imperial Chemical Industries Ltd filed Critical Imperial Chemical Industries Ltd
Priority to GB3515963A priority Critical patent/GB1000322A/en
Publication of GB1000322A publication Critical patent/GB1000322A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/02Polymerisation in bulk
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F14/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F14/02Monomers containing chlorine
    • C08F14/04Monomers containing two carbon atoms
    • C08F14/06Vinyl chloride

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

Polymer in the form of a transparent block is produced from ethylenically unsaturated monomeric material which is not a solvent for, and has a lower specific gravity than, the polymer produced therefrom, by a process in which the monomeric material is heated at a temperature below 90 DEG C. in admixture with a monomer-soluble radical polymerization catalyst while subjected to a pressure in excess of the vapour pressure normally exerted by the monomeric material under the polymerization conditions. The process may be effected batchwise or continuously. Specified monomers are vinyl chloride, vinylidene chloride and acrylonitrile. Specified catalysts are acetyl, benzoyl, lauroyl and caproyl peroxides, peresters and azobisiso-butyronitrile; and chain transfer agents, cross-linking agents, plasticizers, fillers, lubricants and pigments may also be present. In Examples (1) and (2) vinyl chloride and (3) a mixture of vinyl chloride and vinyl acetate are polymerized in the presence of lauroyl peroxide.
GB3515963A 1963-09-05 1963-09-05 Mass polymerisation process Expired GB1000322A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB3515963A GB1000322A (en) 1963-09-05 1963-09-05 Mass polymerisation process

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB3515963A GB1000322A (en) 1963-09-05 1963-09-05 Mass polymerisation process

Publications (1)

Publication Number Publication Date
GB1000322A true GB1000322A (en) 1965-08-04

Family

ID=10374515

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3515963A Expired GB1000322A (en) 1963-09-05 1963-09-05 Mass polymerisation process

Country Status (1)

Country Link
GB (1) GB1000322A (en)

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