GB1000322A - Mass polymerisation process - Google Patents
Mass polymerisation processInfo
- Publication number
- GB1000322A GB1000322A GB3515963A GB3515963A GB1000322A GB 1000322 A GB1000322 A GB 1000322A GB 3515963 A GB3515963 A GB 3515963A GB 3515963 A GB3515963 A GB 3515963A GB 1000322 A GB1000322 A GB 1000322A
- Authority
- GB
- United Kingdom
- Prior art keywords
- vinyl chloride
- monomeric material
- polymer
- lauroyl
- specified
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/02—Polymerisation in bulk
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F14/02—Monomers containing chlorine
- C08F14/04—Monomers containing two carbon atoms
- C08F14/06—Vinyl chloride
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Polymer in the form of a transparent block is produced from ethylenically unsaturated monomeric material which is not a solvent for, and has a lower specific gravity than, the polymer produced therefrom, by a process in which the monomeric material is heated at a temperature below 90 DEG C. in admixture with a monomer-soluble radical polymerization catalyst while subjected to a pressure in excess of the vapour pressure normally exerted by the monomeric material under the polymerization conditions. The process may be effected batchwise or continuously. Specified monomers are vinyl chloride, vinylidene chloride and acrylonitrile. Specified catalysts are acetyl, benzoyl, lauroyl and caproyl peroxides, peresters and azobisiso-butyronitrile; and chain transfer agents, cross-linking agents, plasticizers, fillers, lubricants and pigments may also be present. In Examples (1) and (2) vinyl chloride and (3) a mixture of vinyl chloride and vinyl acetate are polymerized in the presence of lauroyl peroxide.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB3515963A GB1000322A (en) | 1963-09-05 | 1963-09-05 | Mass polymerisation process |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB3515963A GB1000322A (en) | 1963-09-05 | 1963-09-05 | Mass polymerisation process |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1000322A true GB1000322A (en) | 1965-08-04 |
Family
ID=10374515
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB3515963A Expired GB1000322A (en) | 1963-09-05 | 1963-09-05 | Mass polymerisation process |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB1000322A (en) |
-
1963
- 1963-09-05 GB GB3515963A patent/GB1000322A/en not_active Expired
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