FR3110409A1 - "Cleaning compositions with a high proportion of natural components" - Google Patents
"Cleaning compositions with a high proportion of natural components" Download PDFInfo
- Publication number
- FR3110409A1 FR3110409A1 FR2105013A FR2105013A FR3110409A1 FR 3110409 A1 FR3110409 A1 FR 3110409A1 FR 2105013 A FR2105013 A FR 2105013A FR 2105013 A FR2105013 A FR 2105013A FR 3110409 A1 FR3110409 A1 FR 3110409A1
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- weight
- alkyl
- cosmetic composition
- composition according
- oligo
- Prior art date
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- 238000004140 cleaning Methods 0.000 title claims abstract description 13
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- 125000000217 alkyl group Chemical group 0.000 claims abstract description 26
- 229930182470 glycoside Natural products 0.000 claims abstract description 17
- 150000002338 glycosides Chemical class 0.000 claims abstract description 17
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 claims abstract description 16
- 229910021653 sulphate ion Inorganic materials 0.000 claims abstract description 15
- 108010076876 Keratins Proteins 0.000 claims abstract description 13
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- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 36
- 125000004432 carbon atom Chemical group C* 0.000 claims description 16
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 claims description 14
- DHMQDGOQFOQNFH-UHFFFAOYSA-M Aminoacetate Chemical compound NCC([O-])=O DHMQDGOQFOQNFH-UHFFFAOYSA-M 0.000 claims description 14
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 13
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- Cosmetics (AREA)
Abstract
La présente invention concerne une composition cosmétique de nettoyage et de soin des fibres kératiniques, en particulier des cheveux humains, qui comprend un alkylsulfate en C8-30, un alkyl(oligo)glycoside et de la triméthylglycine. La présente invention concerne également l’utilisation des compositions cosmétiques pour le nettoyage ou le soin des cheveux humains, en particulier l’utilisation sous forme de shampooing.The present invention relates to a cosmetic composition for cleaning and caring for keratin fibres, in particular human hair, which comprises a C8-30 alkyl sulphate, an alkyl (oligo)glycoside and trimethylglycine. The present invention also relates to the use of cosmetic compositions for cleaning or caring for human hair, in particular the use in the form of shampoo.
Description
La présente invention concerne des compositions cosmétiques pour le nettoyage et le soin des fibres kératiniques, en particulier des cheveux humains, les compositions cosmétiques comprenant des alkylsulfates, des alkyl(oligo)glycosides et de la triméthylglycine.The present invention relates to cosmetic compositions for cleaning and caring for keratin fibers, in particular human hair, the cosmetic compositions comprising alkylsulphates, alkyl (oligo) glycosides and trimethylglycine.
Les aspects environnementaux jouent un rôle de plus en plus important dans la fabrication des produits cosmétiques. Pour les consommateurs, une utilisation prudente des ressources et des procédés de fabrication économes en énergie sont particulièrement importants. Cependant, même dans la composition globale des produits cosmétiques, l’attention est de plus en plus portée sur une forte proportion d’ingrédients non polluants pour l’environnement, comme les microplastiques.Environmental aspects play an increasingly important role in the manufacture of cosmetic products. For consumers, prudent use of resources and energy-efficient manufacturing processes are particularly important. However, even in the overall makeup of cosmetics, attention is increasingly being paid to a high proportion of environmentally friendly ingredients, such as microplastics.
Dans le contexte d’une utilisation plus durable des matières premières et de l’énergie, il reste souhaitable de n’utiliser dans les produits cosmétiques que des matières premières cosmétiques disponibles à partir de matières premières renouvelables en utilisant le moins d’énergie possible. Une réduction de quantité ou même un échange complet de substances indésirables ou problématiques ne sera possible que s’il existe d’autres possibilités présentant également les propriétés souhaitées pour l’application.In the context of a more sustainable use of raw materials and energy, it remains desirable to use in cosmetic products only cosmetic raw materials available from renewable raw materials using as little energy as possible. A reduction in the quantity or even a complete exchange of undesirable or problematic substances will only be possible if there are other possibilities which also have the desired properties for the application.
Ces dernières années, par exemple, on a tenté de s’affranchir des tensioactifs et des émulsifiants alcoxylés dans les agents cosmétiques pour le traitement de la peau et/ou des cheveux, en particulier dans les agents nettoyants cosmétiques.In recent years, for example, attempts have been made to move away from alkoxylated surfactants and emulsifiers in cosmetic agents for the treatment of the skin and / or hair, in particular in cosmetic cleansing agents.
Dans DE 102014203267A1, on décrit des préparations nettoyantes qui comprennent au moins 95 % d’ingrédients d’origine naturelle.DE 102014203267A1 describes cleaning preparations which contain at least 95% of ingredients of natural origin.
Cependant, ces compositions n’étaient pas toujours totalement satisfaisantes en ce qui concerne les performances générales de soin.However, these compositions were not always completely satisfactory with regard to the general skincare performance.
L’objectif sur lequel est basée l’invention est de fournir un agent nettoyant cosmétique produit de manière économe en ressources et respectueuse de l’environnement et dont les performances, qui n’affectent pas les performances nettoyantes, sont améliorées.The object on which the invention is based is to provide a cosmetic cleaning agent produced in a resource-saving and environmentally friendly manner and the performance of which, which does not affect the cleaning performance, is improved.
L’objectif sur lequel est basée l’invention est atteint par un premier objet de l’invention qui est une composition cosmétique pour le nettoyage et le soin des fibres kératiniques, en particulier des cheveux humains, contenant :The objective on which the invention is based is achieved by a first object of the invention which is a cosmetic composition for cleaning and caring for keratin fibers, in particular human hair, containing:
a) au moins un alkylsulfate en C8-30,a) at least one C 8-30 alkyl sulphate,
b) au moins un alkyl(oligo)glycoside etb) at least one alkyl (oligo) glycoside and
c) de la triméthylglycine.c) trimethylglycine.
Les compositions cosmétiques selon l’invention présentent l’avantage que les cheveux traités avec celles-ci peuvent être démêlés très facilement à l’état sec et humide, et qu’ils présentent une élasticité et une douceur élevées après le séchage.The cosmetic compositions according to the invention have the advantage that the hair treated with them can be disentangled very easily in the dry and wet state, and that they exhibit high elasticity and softness after drying.
De plus, il a été possible de s’affranchir complètement des matières premières classiques pour les agents nettoyants cosmétiques d’origine synthétique ou à base d’huile minérale dans la fabrication des compositions selon l’invention.In addition, it has been possible to completely dispense with conventional raw materials for cosmetic cleaning agents of synthetic origin or based on mineral oil in the manufacture of the compositions according to the invention.
Les agents nettoyants cosmétiques selon l’invention contiennent, comme premier constituant essentiel, au moins un alkylsulfate en C8-C30comme tensioactif lavant.The cosmetic cleansing agents according to the invention contain, as the first essential constituent, at least one C 8 -C 30 alkyl sulphate as washing surfactant.
On a constaté que les alkylsulfates en C8-C30forment une mousse stable à pores fins même en petites quantités, et qu’ils sont particulièrement bien tolérés par la peau. C 8 -C 30 alkyl sulphates have been found to form a stable, fine-pored foam even in small amounts, and to be particularly well tolerated by the skin.
On préfère les alkylsulfates en C10-C24et on préfère particulièrement les alkylsulfates en C12-C18, car ces tensioactifs anioniques, également appelés « cocosulfates », sont obtenus à partir d’huile de coco naturelle et conviennent particulièrement comme ingrédients conformes à ECOCERT pour une utilisation dans les compositions selon l’invention.C 10 -C 24 alkyl sulphates are preferred and C 12 -C 18 alkyl sulphates are particularly preferred, since these anionic surfactants, also called "cocosulphates", are obtained from natural coconut oil and are particularly suitable as ingredients in accordance with the invention. to ECOCERT for use in the compositions according to the invention.
On préfère tout particulièrement les sels alcalins tels que les sels de potassium ou de sodium de cocosulfate. On préfère en particulier le cocosulfate de sodium (SCS).Most preferred are alkali metal salts such as potassium or sodium cocosulphate salts. Sodium cocosulfate (SCS) is particularly preferred.
Les compositions cosmétiques selon l’invention contiennent (par rapport à leur poids total) de préférence 1,0 à 15 % en poids, de manière préférée 1,5 à 10 % en poids et en particulier 2 à 7,5 % en poids d’au moins un alkylsulfate en C8-C30.The cosmetic compositions according to the invention contain (relative to their total weight) preferably 1.0 to 15% by weight, preferably 1.5 to 10% by weight and in particular 2 to 7.5% by weight of 'at least one C 8 -C 30 alkyl sulphate.
Un mode de réalisation préféré est caractérisé en ce que les compositions cosmétiques selon l’invention contiennent un alkylsulfate en C10-C24, de manière davantage préférée un alkylsulfate en C12-C18, le contre-ion étant un cation cosmétiquement acceptable, de préférence le sodium, l’alkylsulfate en C8-C30étant en particulier le cocosulfate de sodium (SCS).A preferred embodiment is characterized in that the cosmetic compositions according to the invention contain a C 10 -C 24 alkyl sulphate, more preferably a C 12 -C 18 alkyl sulphate, the counterion being a cosmetically acceptable cation, preferably sodium, the C 8 -C 30 alkylsulfate being in particular sodium cocosulfate (SCS).
Les compositions cosmétiques selon l’invention contiennent au moins un alkyl(oligo)glycoside comme deuxième constituant essentiel.The cosmetic compositions according to the invention contain at least one alkyl (oligo) glycoside as the second essential constituent.
On a découvert que l’association d’alkylsulfates en C8-C30avec des alkyl(oligo)glycosides permet de fournir des compositions extrêmement douces et respectueuses de la peau pour le traitement des fibres kératiniques, en particulier pour le nettoyage des cheveux, et qui présentent également d’excellentes quantités et propriétés de mousse, même utilisées en petites quantités.It has been discovered that the combination of C 8 -C 30 alkyl sulphates with alkyl (oligo) glycosides makes it possible to provide extremely gentle and skin-friendly compositions for the treatment of keratin fibers, in particular for cleaning the hair, and which also exhibit excellent foam amounts and properties even when used in small amounts.
Des alkyl(oligo)glycosides appropriés aux fins de la présente invention sont des composés de formule générale RO-[G]x, dans laquelle R représente un radical alkyle ou alcényle ayant 6 à 24 atomes de carbone, G représente un radical sucre ayant 5 ou 6 atomes de carbone et x représente des nombres entre 1 et 10. On peut les obtenir selon les procédés pertinents en chimie organique préparative.Alkyl (oligo) glycosides suitable for the purposes of the present invention are compounds of the general formula RO- [G] x , in which R represents an alkyl or alkenyl radical having 6 to 24 carbon atoms, G represents a sugar radical having 5 or 6 carbon atoms and x represents numbers between 1 and 10. They can be obtained by the relevant methods in preparative organic chemistry.
Les alkyl- et les alcényloligoglycosides peuvent être dérivés d’aldoses et de cétoses ayant 5 ou 6 atomes de carbone, de préférence du glucose. Les alkyl- et les alcényloligoglycosides préférés sont donc les alkyl- et les alcényloligoglucosides.Alkyl- and alkenyloligoglycosides can be derived from aldoses and ketoses having 5 or 6 carbon atoms, preferably glucose. The preferred alkyl- and alkenyloligoglycosides are therefore alkyl- and alkenyloligoglycosides.
L’indice x dans la formule générale RO-[G]xindique le degré d’oligomérisation (DP), c’est-à-dire la distribution des mono- et oligoglycosides, et représente un nombre compris entre 1 et 10. Alors que x dans la molécule individuelle doit toujours être un entier et surtout peut prendre les valeurs x = 1 à 6, la valeur x pour un alkyloligoglycoside spécifique est une variable mathématique déterminée analytiquement représentant généralement un nombre fractionnaire. On préfère les alkyl- et alcényloligoglycosides ayant un degré moyen d’oligomérisation x de 1,1 à 3.The index x in the general formula RO- [G] x indicates the degree of oligomerization (DP), that is to say the distribution of mono- and oligoglycosides, and represents a number between 1 and 10. Then that x in the individual molecule must always be an integer and above all can take the values x = 1 to 6, the value x for a specific alkyloligoglycoside is an analytically determined mathematical variable generally representing a fractional number. Preferred are alkyl- and alkenyloligoglycosides having an average degree of oligomerization x of 1.1 to 3.
Du point de vue de l’application, on préfère les alkyl- et les alcényloligoglycosides dont le degré d’oligomérisation est inférieur à 1,7, en particulier est compris entre 1,2 et 1,4.From the point of view of application, preferred are alkyl- and alkenyloligoglycosides whose degree of oligomerization is less than 1.7, in particular is between 1.2 and 1.4.
Les radicaux alkyle et alcényle R peuvent être dérivés d’alcools primaires ayant 6 à 24 atomes de carbone tels que l’alcool caproïque, l’alcool caprylique, l’alcool caprique, l’alcool laurylique, l’alcool myristylique, l’alcool cétylique, l’alcool palmoléylique, l’alcool stéarylique, l’alcool isostéarylique, l’alcool oléique, l’alcool élaidylique, l’alcool pétrosélinylique, l’alcool arachidylique, l’alcool gadoléylique, l’alcool béhénylique, l’alcool érucylique et l’alcool brassidylique ainsi que leurs mélanges industriels.The alkyl and alkenyl radicals R can be derived from primary alcohols having 6 to 24 carbon atoms such as caproic alcohol, capryl alcohol, capric alcohol, lauryl alcohol, myristyl alcohol, alcohol cetyl, palmoleyl alcohol, stearyl alcohol, isostearyl alcohol, oleic alcohol, elaidyl alcohol, petroselinyl alcohol, arachidyl alcohol, gadoleyl alcohol, behenyl alcohol, alcohol erucyl and brassidyl alcohol and their industrial mixtures.
On préfère les alkyloligoglucosides dans lesquels R représente des radicaux alkyle en C8-C18et qui présentent un degré d’oligomérisation de 1 à 3.Preferred are alkyloligoglucosides in which R represents C 8 -C 18 alkyl radicals and which exhibit a degree of oligomerization of 1 to 3.
On préfère particulièrement les alkyloligoglucosides connus sous le nom INCI Caprylyl/Capryl Glucoside, Decyl Glucoside et/ou Coco Glucoside.Particularly preferred are the alkyloligoglucosides known under the INCI name Caprylyl / Capryl Glucoside, Decyl Glucoside and / or Coco Glucoside.
On peut utiliser les alkyloligoglycosides dans les compositions cosmétiques selon l’invention de préférence en une quantité de 0,10 à 15 % en poids, de manière davantage préférée de 0,5 à 10 % en poids et de manière particulièrement préférée de 1 à 7,5 % en poids, par rapport au poids total de la composition cosmétique.The alkyloligoglycosides can be used in the cosmetic compositions according to the invention preferably in an amount of 0.10 to 15% by weight, more preferably from 0.5 to 10% by weight and particularly preferably from 1 to 7. , 5% by weight, relative to the total weight of the cosmetic composition.
Dans un mode de réalisation particulièrement préféré, les compositions cosmétiques selon l’invention contiennent des alkyl(oligo)glycosides de formule RO-[G]X, dans laquelle R représente un radical alkyle ayant 6 à 24 atomes de carbone, G représente un radical sucre ayant 5 ou 6 atomes de carbone et x (degré d’oligomérisation) représente un nombre de 1 à 10, de préférence des alkyl(oligo)glucosides avec un radical alkyle en C8-C18et un degré d’oligomérisation de 1 à 3, en particulier le Caprylyl/Capryl Glucoside et/ou le Coco Glucoside.In a particularly preferred embodiment, the cosmetic compositions according to the invention contain alkyl (oligo) glycosides of formula RO- [G] X , in which R represents an alkyl radical having 6 to 24 carbon atoms, G represents a radical sugar having 5 or 6 carbon atoms and x (degree of oligomerization) represents a number from 1 to 10, preferably alkyl (oligo) glucosides with a C 8 -C 18 alkyl radical and a degree of oligomerization of 1 to 3, in particular Caprylyl / Capryl Glucoside and / or Coco Glucoside.
Pour des propriétés optimales du produit, il est avantageux que le tensioactif anionique a) soit présent dans un certain rapport pondéral par rapport à l’alkyl(oligo)glycoside/les alkyl(oligo)glycosides. Un rapport pondéral entre l’/les alkylsulfate(s) en C8-30a) et l’/les alkyl(oligo)glycoside(s) b) de 3 : 1 à 1 : 1, de préférence de 2,5 : 1 à 1 : 1 et en particulier de 2 : 1 à 1 : 1 s’est avéré optimal.For optimum product properties, it is advantageous that the anionic surfactant a) is present in a certain weight ratio relative to the alkyl (oligo) glycoside / alkyl (oligo) glycosides. A weight ratio between the C 8-30 alkyl sulphate (s) a) and the alkyl (oligo) glycoside (s) b) of 3: 1 to 1: 1, preferably 2.5: 1 to 1: 1 and in particular 2: 1 to 1: 1 has been found to be optimal.
Dans un autre mode de réalisation préféré, les compositions cosmétiques selon l’invention sont par conséquent caractérisées en ce que le rapport pondéral entre l’/les alkylsulfate(s) en C8-30a) et l’/les alkyl(oligo)glycoside(s) b) est de 3 : 1 à 1 : 1, de préférence de 2,5 : 1 à 1 : 1 et en particulier de 2 : 1 à 1 : 1.In another preferred embodiment, the cosmetic compositions according to the invention are consequently characterized in that the weight ratio between the C 8-30 alkyl sulphate (s) and the alkyl (oligo) glycoside (s) b) is 3: 1 to 1: 1, preferably 2.5: 1 to 1: 1 and in particular 2: 1 to 1: 1.
Dans un autre mode de réalisation préféré, les compositions cosmétiques selon l’invention contiennent - par rapport à leur poids total -In another preferred embodiment, the cosmetic compositions according to the invention contain - relative to their total weight -
- 1,00 à 15 % en poids d’au moins un alkylsulfate en C8-30,- 1.00 to 15% by weight of at least one C 8-30 alkyl sulphate,
- 0,10 à 15 % en poids d’au moins un alkyl(oligo)glycoside,- 0.10 to 15% by weight of at least one alkyl (oligo) glycoside,
- 0,01 à 5 % en poids de triméthylglycine.- 0.01 to 5% by weight of trimethylglycine.
En combinaison avec les tensioactifs a) et b), la triméthylglycine a un effet de stabilisation de la mousse et de réduction de l’irritation, et permet de réduire la quantité de tensioactif tout en conservant de bonnes quantités et propriétés de mousse.In combination with the surfactants a) and b), trimethylglycine has a foam stabilizing and irritation reducing effect, and allows the amount of surfactant to be reduced while retaining good amounts and foam properties.
En outre, la triméthylglycine est connue comme principe actif hydratant dans les agents cosmétiques et sert également de composant de conditionnement des cheveux dans les compositions selon l’invention - en particulier comme principe actif renforçant les fibres capillaires.In addition, trimethylglycine is known as a moisturizing active ingredient in cosmetic agents and also serves as a hair conditioning component in compositions according to the invention - in particular as an active ingredient strengthening hair fibers.
La triméthylglycine est utilisée dans les compositions cosmétiques selon l’invention de préférence en une proportion en poids de 0,01 à 5 % en poids, de manière davantage préférée de 0,05 à 4 % en poids et en particulier de 0,1 à 3 % en poids, par rapport au poids total des compositions.Trimethylglycine is used in the cosmetic compositions according to the invention preferably in a proportion by weight of 0.01 to 5% by weight, more preferably from 0.05 to 4% by weight and in particular from 0.1 to 3% by weight, relative to the total weight of the compositions.
Les compositions cosmétiques selon l’invention se présentent de préférence dans une base aqueuse. Cela signifie de préférence une teneur en eau d’au moins 70 % en poids, de manière davantage préférée d’au moins 75 % en poids et de manière particulièrement préférée d’au moins 80 % en poids (par rapport au poids total des compositions cosmétiques).The cosmetic compositions according to the invention are preferably provided in an aqueous base. This preferably means a water content of at least 70% by weight, more preferably at least 75% by weight and particularly preferably at least 80% by weight (based on the total weight of the compositions cosmetics).
On peut ajouter d’autres ingrédients peu solubles ou insolubles aux compositions cosmétiques selon l’invention, dans la phase aqueuse, sans devoir utiliser de composés alcoxylés ou de stabilisants polymériques pour leur solubilisation et/ou leur stabilisation.Other sparingly soluble or insoluble ingredients can be added to the cosmetic compositions according to the invention, in the aqueous phase, without having to use alkoxylated compounds or polymeric stabilizers for their solubilization and / or stabilization.
Dans un mode de réalisation préféré, les compositions cosmétiques selon l’invention sont sensiblement exemptes de composés alcoxylés.In a preferred embodiment, the cosmetic compositions according to the invention are substantially free from alkoxylated compounds.
Dans un autre mode de réalisation préféré, les compositions cosmétiques selon l’invention sont sensiblement exemptes de stabilisants polymères, en particulier exemptes de polymères à base acrylique.In another preferred embodiment, the cosmetic compositions according to the invention are substantially free from polymer stabilizers, in particular free from acrylic-based polymers.
Dans le cadre de la présente invention, on entend par « sensiblement exempt » une teneur maximale en composés alcoxylés et/ou en polymères à base acrylique de 0,01 % en poids (par rapport au poids total des compositions cosmétiques), qui peut être contenue comme impureté ou sous-produit dans les produits commerciaux utilisés.In the context of the present invention, the term “substantially free” is understood to mean a maximum content of alkoxylated compounds and / or of acrylic-based polymers of 0.01% by weight (relative to the total weight of the cosmetic compositions), which may be contained as an impurity or by-product in the commercial products used.
De manière particulièrement préférée, les compositions selon l’invention ne contiennent aucun composé alcoxylé et/ou polymère à base acrylique.Particularly preferably, the compositions according to the invention do not contain any alkoxylated compound and / or acrylic-based polymer.
Les compositions cosmétiques selon l’invention peuvent contenir d’autres tensioactifs en plus du/des sulfate(s) d’alkyle en C8-C30et de l’/des alkyl(oligo)glycoside(s). Cependant, la quantité totale de tensioactifs détergents ne doit de préférence pas dépasser 15 % en poids, de manière davantage préférée 14 % en poids et en particulier 12,5 % en poids (par rapport au poids total des compositions), car sinon l’équilibre entre le nettoyage, la douceur pour la peau, et les propriétés de mousse et de soin peut être altéré.The cosmetic compositions according to the invention may contain other surfactants in addition to the C 8 -C 30 alkyl sulfate (s) and to the alkyl (oligo) glycoside (s). However, the total amount of detergent surfactants should preferably not exceed 15% by weight, more preferably 14% by weight and in particular 12.5% by weight (based on the total weight of the compositions), because otherwise the balance between cleansing, skin softness, and foaming and skincare properties may be altered.
Dans un mode de réalisation préféré, des tensioactifs amphotères et/ou zwitterioniques sont utilisés comme co-tensioactifs dans les compositions cosmétiques selon l’invention.In a preferred embodiment, amphoteric and / or zwitterionic surfactants are used as cosurfactants in the cosmetic compositions according to the invention.
Des tensioactifs amphotères et/ou zwitterioniques appropriés aux fins de la présente invention sont, par exemple, un ou plusieurs composés des formules (1) à (7) ci-dessous. Dans ces formules, le radical R représente de préférence un radical alkyle ou alcényle à chaîne linéaire ou ramifié, saturé ou mono- ou polyinsaturé, ayant 7 à 23 atomes de carbone (formules (1) et (2)) ou il représente un radical alkyle ou alcényle à chaîne linéaire ou ramifié, saturé ou mono- ou polyinsaturé ayant 8 à 24 atomes de carbone (formules (3) à (7)) :Amphoteric and / or zwitterionic surfactants suitable for the purposes of the present invention are, for example, one or more compounds of formulas (1) to (7) below. In these formulas, the radical R preferably represents an alkyl or alkenyl radical with a linear or branched chain, saturated or mono- or polyunsaturated, having 7 to 23 carbon atoms (formulas (1) and (2)) or it represents a radical Straight or branched chain alkyl or alkenyl, saturated or mono- or polyunsaturated having 8 to 24 carbon atoms (formulas (3) to (7)):
Les tensioactifs amphotères préférés des formules (1) à (7) mentionnées ci-dessus contiennent, en tant que radical R, principalement un radical alkyle à chaîne droite ou ramifié, saturé, mono- ou polyinsaturé, ayant 8 à 20, de manière davantage préférée 8 à 18 et en particulier 8 à 16 atomes de carbone.Preferred amphoteric surfactants of formulas (1) to (7) mentioned above contain, as radical R, predominantly a straight or branched, saturated, mono- or polyunsaturated alkyl radical having 8 to 20, moreover preferred 8 to 18 and in particular 8 to 16 carbon atoms.
On préfère en outre les tensioactifs amphotères dans lesquels le radical R est dérivé de matière grasse de coco.Preference is also given to amphoteric surfactants in which the radical R is derived from coconut fat.
Des exemples d’agents tensioactifs amphotères et/ou zwitterioniques particulièrement préférés sont le glycinate de N-alkyl-N,N-dimethylammonium, le glycinate de cocoalkyldiméthylammonium, le glycinate de N-acyl-aminopropyl-N,N-diméthylammonium ou les 2-alkyl-3-carboxyméthyl-3-hydroxyéthylimidazolines, les groupes alkyle ou acyle présentant de préférence chacun 8 à 18 atomes de carbone, de préférence le glycinate de cocoacylaminoéthylhydroxyéthylcarboxyméthyle, le glycinate de cocoacylaminopropyl-diméthylammonium, la bétaïne de cocoamidopropyle et/ou la bétaïne de coco, en particulier la bétaïne de cocoamidopropyle.Examples of particularly preferred amphoteric and / or zwitterionic surfactants are N-alkyl-N, N-dimethylammonium glycinate, cocoalkyldimethylammonium glycinate, N-acyl-aminopropyl-N, N-dimethylammonium glycinate or 2- alkyl-3-carboxymethyl-3-hydroxyethylimidazolines, the alkyl or acyl groups each having preferably 8 to 18 carbon atoms, preferably cocoacylaminoethylhydroxyethylcarboxymethyl glycinate, cocoacylaminopropyl-dimethylammonium glycinate, cocoamidopropyl betaine or / coco, in particular cocoamidopropyl betaine.
On peut utiliser les tensioactifs amphotères et/ou zwitterioniques dans les compositions cosmétiques selon l’invention de préférence en une quantité de 0,1 à 10 % en poids, de manière davantage préférée de 0,5 à 7,5 % en poids et de manière particulièrement préférée de 1 à 5 % en poids, par rapport au poids total de la composition cosmétique.The amphoteric and / or zwitterionic surfactants can be used in the cosmetic compositions according to the invention preferably in an amount of 0.1 to 10% by weight, more preferably of 0.5 to 7.5% by weight and of particularly preferably from 1 to 5% by weight, relative to the total weight of the cosmetic composition.
Dans un mode de réalisation particulièrement préféré, les compositions cosmétiques selon l’invention contiennent au moins un tensioactif zwitterionique choisi dans le groupe constitué du glycinate de N-alkyl-N,N-diméthylammonium, du glycinate de cocoalkyldiméthylammonium, du glycinate de N-acylaminopropyl-N,N-diméthylammonium et des 2-alkyl-3-carboxyméthyl-3-hydroxyéthyl-imidazolines, les groupes alkyle ou acyle présentant de préférence 8 à 18 atomes de carbone, de préférence le glycinate de cocoacylaminoéthylhydroxyéthylcarboxyméthyl, le glycinate de cocoacylaminopropyl-diméthylammonium, la bétaïne de cocoamidopropyle et/ou la bétaïne de coco, en particulier la bétaïne de cocoamidopropyle, dans une proportion en poids de 0,01 à 10 % en poids par rapport au poids total des compositions cosmétiques.In a particularly preferred embodiment, the cosmetic compositions according to the invention contain at least one zwitterionic surfactant chosen from the group consisting of N-alkyl-N, N-dimethylammonium glycinate, cocoalkyldimethylammonium glycinate, N-acylaminopropyl glycinate -N, N-dimethylammonium and 2-alkyl-3-carboxymethyl-3-hydroxyethyl-imidazolines, the alkyl or acyl groups preferably having 8 to 18 carbon atoms, preferably cocoacylaminoethylhydroxyethylcarboxymethyl glycinate, cocoacylaminopropyl-dimethylammonium glycinate , cocoamidopropyl betaine and / or coconut betaine, in particular cocoamidopropyl betaine, in a proportion by weight of 0.01 to 10% by weight relative to the total weight of the cosmetic compositions.
Pour augmenter les propriétés de soin capillaire, il peut être avantageux que les compositions cosmétiques selon l’invention contiennent en outre au moins un principe actif de conditionnement capillaire, que l’on peut de préférence obtenir à partir de sources naturelles.In order to increase the hair care properties, it may be advantageous for the cosmetic compositions according to the invention to additionally contain at least one active hair conditioning principle, which can preferably be obtained from natural sources.
Les compositions cosmétiques selon l’invention contiennent de préférence au moins un principe actif améliorant l’hydratation de la peau ou du cuir chevelu et/ou la structure de la fibre capillaire, qui est de préférence choisi parmi les polyols (c’est-à-dire les polyalcools ou les composés polyhydroxylés physiologiquement compatibles) ayant 2 à 20 atomes de carbone et au moins deux groupes hydroxyle. Des exemples typiques sont des alcanols à chaîne droite, ramifiés ou cycliques ayant 2 à 10, de préférence 2 à 6 atomes de carbone, tels que le 1,2-propanediol, le 1,3-butylèneglycol, le dipropylèneglycol, le glycérol et/ou le diglycérol, les glycols comme les polyéthylèneglycols et/ou les polypropylèneglycols ainsi que les alcools de sucre (alditols), les sucres ou les dérivés de sucres tels que le mannitol, l’isomaltitol, le lactitol, le sorbitol, le xylitol, le fructose, le glucose, le lactose, le galactose et/ou le saccharose.The cosmetic compositions according to the invention preferably contain at least one active principle improving the hydration of the skin or the scalp and / or the structure of the hair fiber, which is preferably chosen from polyols (that is to say (ie polyalcohols or physiologically compatible polyhydroxy compounds) having 2 to 20 carbon atoms and at least two hydroxyl groups. Typical examples are straight chain, branched or cyclic alkanols having 2 to 10, preferably 2 to 6 carbon atoms, such as 1,2-propanediol, 1,3-butylene glycol, dipropylene glycol, glycerol and / or diglycerol, glycols such as polyethylene glycols and / or polypropylene glycols as well as sugar alcohols (alditols), sugars or sugar derivatives such as mannitol, isomaltitol, lactitol, sorbitol, xylitol, fructose, glucose, lactose, galactose and / or sucrose.
On préfère particulièrement les polyols en C2-C6, de préférence les alditols tels que le mannitol, l’isomaltitol, le lactitol, le sorbitol et/ou le xylitol, le 1,2-propylèneglycol, le 1,3-butylèneglycol, le dipropylèneglycol, le glycérol et/ou le diglycérol, de manière particulièrement préférée le 1,2-propylène glycol, le 1,3-butylèneglycol, le dipropylèneglycol, le glycérol et/ou le diglycérol, et on préfère en particulier le glycérol. C 2 -C 6 polyols are particularly preferred, preferably alditols such as mannitol, isomaltitol, lactitol, sorbitol and / or xylitol, 1,2-propylene glycol, 1,3-butylene glycol, dipropylene glycol, glycerol and / or diglycerol, particularly preferably 1,2-propylene glycol, 1,3-butylene glycol, dipropylene glycol, glycerol and / or diglycerol, and glycerol is particularly preferred.
Les compositions cosmétiques selon l’invention contiennent l’au moins un principe actif améliorant l’hydratation de la peau ou du cuir chevelu et/ou la structure de la fibre capillaire - de préférence le glycérol - de préférence dans une proportion en poids de 0,01 à 10 % en poids, de manière davantage préférée de 0,05 à 7,5 % en poids et en particulier de 0,1 à 5 % en poids par rapport au poids total des compositions cosmétiques.The cosmetic compositions according to the invention contain at least one active principle improving the hydration of the skin or the scalp and / or the structure of the hair fiber - preferably glycerol - preferably in a proportion by weight of 0 0.01 to 10% by weight, more preferably from 0.05 to 7.5% by weight and in particular from 0.1 to 5% by weight relative to the total weight of the cosmetic compositions.
Dans un autre mode de réalisation préféré, les compositions cosmétiques selon l’invention contiennent au moins un polyol en C2-C6, de préférence des alditols tels que le mannitol, l’isomaltitol, le lactitol, le sorbitol et/ou le xylitol, le 1,2-propylèneglycol, le 1,3-butylèneglycol, le dipropylèneglycol, le glycérol et/ou le diglycérol, de manière particulièrement préférée le 1,2-propylèneglycol, le 1,3-butylèneglycol, le dipropylèneglycol, le glycérol et/ou le diglycérol, de manière particulièrement préférée le glycérol, dans une proportion en poids de 0,01 à 10 % en poids par rapport au poids total de la composition cosmétique.In another preferred embodiment, the cosmetic compositions according to the invention contain at least one C 2 -C 6 polyol, preferably alditols such as mannitol, isomaltitol, lactitol, sorbitol and / or xylitol , 1,2-propylene glycol, 1,3-butylene glycol, dipropylene glycol, glycerol and / or diglycerol, particularly preferably 1,2-propylene glycol, 1,3-butylene glycol, dipropylene glycol, glycerol and / or diglycerol, particularly preferably glycerol, in a proportion by weight of 0.01 to 10% by weight relative to the total weight of the cosmetic composition.
Les compositions cosmétiques selon l’invention peuvent comprendre en outre d’autres principes actifs qui soutiennent ou renforcent leurs propriétés de nettoyage et de soin.The cosmetic compositions according to the invention can also comprise other active principles which support or enhance their cleaning and care properties.
On peut sélectionner les principes actifs facultatifs préférés, par exemple, dans le groupe constituéPreferred optional active ingredients can be selected, for example, from the group consisting of
- des polymères cationiques, de préférence les polymères cationiques d’origine naturelle, et/ou- cationic polymers, preferably cationic polymers of natural origin, and / or
- des huiles et/ou des beurres, de préférence les huiles et/ou les beurres naturels (végétaux), et/ou- oils and / or butters, preferably oils and / or natural (vegetable) butters, and / or
- des vitamines et/ou- vitamins and / or
- des extraits végétaux et/ou- plant extracts and / or
- des hydrolysats de protéines et/ou- protein hydrolysates and / or
- des agents antipelliculaires.- anti-dandruff agents.
Par polymères cationiques appropriés d’origine naturelle au sens de la présente invention, on entend par exemple :By appropriate cationic polymers of natural origin within the meaning of the present invention is meant for example:
- les dérivés de cellulose quaternisés, disponibles dans le commerce sous les dénominations de Celquat® et Polymer JR®,- quaternized cellulose derivatives, commercially available under the names Celquat® and Polymer JR®,
- les dérivés cationiques d’amidon, tels que ceux disponibles dans le commerce sous la dénomination Mirustyle®,- cationic starch derivatives, such as those commercially available under the name Mirustyle ® ,
- les dérivés de cellulose modifiés hydrophobiquement, par exemple les polymères cationiques commercialisés sous la dénomination commerciale SoftCat®,- hydrophobically modified cellulose derivatives, for example cationic polymers sold under the trade name SoftCat ® ,
- les alkylpolyglycosides cationiques,- cationic alkylpolyglycosides,
- le miel cationisé, par exemple le produit commercial Honeyquat®50,- cationized honey, for example the commercial product Honeyquat ® 50,
- les dérivés de guar cationiques, en particulier les produits commercialisés sous les dénominations commerciales Cosmedia®guar N-Hance®et Jaguar®.- cationic guar derivatives, in particular the products marketed under the trade names Cosmedia ® guar N-Hance ® and Jaguar ® .
- les dérivés cationiques de cassia et/ou d’inuline tels que les polymères cationiques connus sous les noms INCI Cassia Hydroxypropyltrimonium Chloride et Hydroxypropyltrimonium Inulin.- cationic cassia and / or inulin derivatives such as the cationic polymers known under the INCI names Cassia Hydroxypropyltrimonium Chloride and Hydroxypropyltrimonium Inulin.
On préfère les polymères de cellulose quaternisés, les dérivés de cellulose cationiques modifiés hydrophobiquement et/ou les dérivés de guar cationiques.Preferred are quaternized cellulose polymers, cationic hydrophobically modified cellulose derivatives and / or cationic guar derivatives.
On préfère particulièrement les polymères cationiques connus sous les noms INCI Guar Hydroxypropyltrimonium Chloride, Polyquaternium-10, Polyquaternium-67 et/ou Hydroxypropyltrimonium Hydrolyzed Corn Starch ; on préfère en particulier le Guar Hydroxypropyltrimonium Chloride.Particularly preferred are the cationic polymers known under the INCI names Guar Hydroxypropyltrimonium Chloride, Polyquaternium-10, Polyquaternium-67 and / or Hydroxypropyltrimonium Hydrolyzed Corn Starch; Guar Hydroxypropyltrimonium Chloride is particularly preferred.
Les compositions cosmétiques selon l’invention contiennent des polymères cationiques, de préférence du Guar Hydroxypropyltrimonium Chloride, de préférence en une proportion en poids de 0,01 à 2 % en poids, de manière davantage préférée de 0,02 à 1,5 % en poids et en particulier de 0,03 à 1 % par rapport au poids total des compositions cosmétiques.The cosmetic compositions according to the invention contain cationic polymers, preferably Guar Hydroxypropyltrimonium Chloride, preferably in a proportion by weight of 0.01 to 2% by weight, more preferably of 0.02 to 1.5% by weight. weight and in particular from 0.03 to 1% relative to the total weight of the cosmetic compositions.
Au sens de la présente invention, on entend de préférence par huiles « naturelles » une huile végétale, de manière particulièrement préférée une huile végétale pressée à froid.For the purposes of the present invention, the term “natural” oils is preferably understood to mean a vegetable oil, particularly preferably a cold-pressed vegetable oil.
Par « huile pressée à froid », on entend une huile obtenue par pressage à froid et/ou extraction à froid de la plante respective (ou de la partie de la plante respective) à une température de 40 °C ou moins, de préférence de 35 °C ou moins et de manière particulièrement préférée de 30 °C ou moins.By "cold pressed oil" is meant an oil obtained by cold pressing and / or cold extraction of the respective plant (or the respective plant part) at a temperature of 40 ° C or less, preferably of 35 ° C or less and particularly preferably 30 ° C or less.
Les huiles susceptibles d’être obtenues par pression à froid ou extraction à froid et qui conviennent pour une utilisation dans les agents selon l’invention sont de préférence les triglycérides et les mélanges de triglycérides tels que l’huile de pépins d’amarante, l’huile de noyau d’abricot, l’huile d’argan, l’huile d’avocat, l’huile de babassu, l’huile de bambou, l’huile de baobab, l’huile de canola, l’huile de carthame, l’huile de pépins de grenade, l’huile de rose musquée, l’huile de chanvre, l’huile de noisette, l’huile de groseille, l’huile de cassis, l’huile de jojoba, l’huile de noix de coco, l’huile de pépins de courge, l’huile de noix de macadamia, l’huile de mauve, l’huile d’amande (douce), l’huile de mangue, l’huile d’onagre, l’huile d’olive, l’huile de noix du Brésil, l’huile de fruit de la passion, l’huile de palmiste, l’huile de noyau de pêche, l’huile de ramboutan, l’huile de son de riz, l’huile de ricin, l’huile de carthame, l’huile de sasanqua, l’huile de sésame, l’huile de soja, l’huile de tournesol, l’huile d’arbre à thé (Tea Tree Oil), l’huile de pépins de raisin, l’huile de tsubaki, l’huile de noix, l’huile de germe de blé et/ou l’huile de coucou.The oils which can be obtained by cold pressing or cold extraction and which are suitable for use in the agents according to the invention are preferably triglycerides and mixtures of triglycerides such as oil of amaranth seeds, l apricot kernel oil, argan oil, avocado oil, babassu oil, bamboo oil, baobab oil, canola oil, safflower, pomegranate seed oil, rosehip oil, hemp oil, hazelnut oil, currant oil, blackcurrant oil, jojoba oil, oil coconut oil, pumpkin seed oil, macadamia nut oil, mallow oil, almond oil (sweet), mango oil, evening primrose oil, olive oil, Brazil nut oil, passion fruit oil, palm kernel oil, peach kernel oil, rambutan oil, bran oil, rice, castor oil, safflower oil, sasanqua oil, sesame oil, hu Soybean, Sunflower Oil, Tea Tree Oil, Grapeseed Oil, Tsubaki Oil, Walnut Oil, Seed Oil wheat and / or cuckoo oil.
L’huile pressée à froid ou extraite à froid est de préférence présente dans les compositions cosmétiques selon l’invention sous forme dispersée, la taille des gouttelettes de l’huile dispersée étant de 0,1 à 500 nm, de préférence de 0,5 à 300 nm.The cold-pressed or cold-extracted oil is preferably present in the cosmetic compositions according to the invention in dispersed form, the size of the droplets of the dispersed oil being from 0.1 to 500 nm, preferably from 0.5. at 300 nm.
Les compositions cosmétiques selon l’invention contiennent des huiles naturelles - de préférence des huiles naturelles pressées à froid - de préférence dans une proportion en poids de 0,01 à 2 % en poids, de manière davantage préférée de 0,025 à 1,5 % en poids et en particulier de 0,05 à 1 % en poids par rapport au poids total des compositions cosmétiques.The cosmetic compositions according to the invention contain natural oils - preferably cold pressed natural oils - preferably in a proportion by weight of 0.01 to 2% by weight, more preferably of 0.025 to 1.5% by weight. weight and in particular from 0.05 to 1% by weight relative to the total weight of the cosmetic compositions.
Par beurres végétaux appropriés, on entend de préférence le beurre de karité, le beurre de mangue, le beurre de murumuru, le beurre de cacao, le beurre de noyau d’abricot, le beurre de mafura, le beurre de bacuri, le beurre de tucuma, le beurre d’ucuuba et/ou le beurre de cupuacu. Le beurre de karité est particulièrement préféré.By suitable vegetable butters is preferably meant shea butter, mango butter, murumuru butter, cocoa butter, apricot kernel butter, mafura butter, bacuri butter, cocoa butter. tucuma, ucuuba butter and / or cupuacu butter. Shea butter is particularly preferred.
On peut utiliser les beurres végétaux dans les compositions cosmétiques selon l’invention de préférence dans une proportion en poids de 0,01 à 5 % en poids par rapport au poids total des compositions cosmétiques. Des proportions en poids de 0,025 à 4 % en poids sont davantage préférées, de 0,05 à 2 % en poids sont particulièrement préférées.The vegetable butters can be used in the cosmetic compositions according to the invention, preferably in a proportion by weight of 0.01 to 5% by weight relative to the total weight of the cosmetic compositions. Proportions by weight of 0.025 to 4% by weight are more preferred, 0.05 to 2% by weight are particularly preferred.
Par « vitamines » appropriées, on entend de préférence les vitamines, les provitamines et les précurseurs de vitamines suivants, ainsi que leurs dérivés :The term “appropriate vitamins” is preferably understood to mean the following vitamins, provitamins and vitamin precursors, as well as their derivatives:
* Vitamine A : le groupe de substances appelées vitamines A comprend le rétinol (vitamine A1) ainsi que le 3,4-didéhydrorétinol (vitamine A2). Le β-carotène est la provitamine du rétinol. Comme composant de la vitamine A, on peut citer par exemple l’acide de vitamine A et ses esters, l’aldéhyde de vitamine A ainsi que l’alcool de vitamine A et ses esters tels que le palmitate et l’acétate.* Vitamin A: The group of substances called vitamins A includes retinol (vitamin A 1 ) as well as 3,4-didehydroretinol (vitamin A 2 ). Β-carotene is the provitamin of retinol. As a component of vitamin A, there may be mentioned, for example, vitamin A acid and its esters, vitamin A aldehyde as well as vitamin A alcohol and its esters such as palmitate and acetate.
* Vitamine B : appartiennent entre autres au groupe de la vitamine B ou au complexe de la vitamine B,* Vitamin B: belong among others to the vitamin B group or the vitamin B complex,
° la vitamine B1(thiamine)° vitamin B 1 (thiamine)
° la vitamine B2(riboflavine)° vitamin B 2 (riboflavin)
° la vitamine B3. Les composés acide nicotinique et nicotinamide (niacinamide) sont souvent présentés sous cette dénomination.° vitamin B 3 . The compounds nicotinic acid and nicotinamide (niacinamide) are often presented under this name.
° la vitamine B5(acide pantothénique et panthénol). Dans ce groupe, on utilise de préférence le panthénol. Les dérivés du panthénol pouvant être utilisés sont, en particulier, les esters et les éthers du panthénol, la pantolactone et également les panthénols dérivés cationiquement. On peut citer, à titre d’exemples desdits dérivés, le triacétate de panthénol, l’éther monoéthylique de panthénol et son monoacétate, ainsi que les dérivés cationiques de panthénol.° vitamin B 5 (pantothenic acid and panthenol). In this group, panthenol is preferably used. The panthenol derivatives which can be used are, in particular, the esters and ethers of panthenol, pantolactone and also the cationically derived panthenols. As examples of said derivatives, mention may be made of panthenol triacetate, panthenol monoethyl ether and its monoacetate, as well as cationic panthenol derivatives.
° la vitamine B6(pyridoxine et pyridoxamine et pyridoxal).° vitamin B 6 (pyridoxine and pyridoxamine and pyridoxal).
* Vitamine C (acide ascorbique) : on peut préférer l’utilisation sous forme d’ester d’acide palmitique, de glucosides ou de phosphates. On peut également préférer l’utilisation en combinaison avec les tocophérols.* Vitamin C (ascorbic acid): may be preferred to use as an ester of palmitic acid, glucosides or phosphates. It may also be preferred to use it in combination with tocopherols.
* Vitamine E (tocophérols, en particulier le α-tocophérol).* Vitamin E (tocopherols, in particular α-tocopherol).
* Vitamine F : par « vitamine F », on entend généralement les acides gras essentiels, en particulier l’acide linoléique, l’acide linolénique et l’acide arachidonique.* Vitamin F: By "vitamin F" we generally mean essential fatty acids, in particular linoleic acid, linolenic acid and arachidonic acid.
* Vitamine H : Le terme « vitamine H » désigne le composé acide (3aS,4S, 6aR)-2-oxohexahydrothiénol[3,4-d]-imidazol-4-valérique, cependant appelé couramment « biotine ».* Vitamin H: The term “vitamin H” designates the acid compound (3aS, 4S, 6aR) -2-oxohexahydrothienol [3,4-d] -imidazol-4-valeric, however commonly called “biotin”.
On préfère en particulier les vitamines, les provitamines et les précurseurs de vitamines des groupes A, B, E et H. On préfère tout particulièrement le nicotinamide, la biotine, la pantolactone et/ou le panthénol ; on préfère en particulier le nicotinamide et/ou le panthénol.Particularly preferred are vitamins, provitamins and vitamin precursors of groups A, B, E and H. Particularly preferred are nicotinamide, biotin, pantolactone and / or panthenol; nicotinamide and / or panthenol are particularly preferred.
La proportion en poids de la ou des vitamine(s), du ou des dérivé(s) de vitamine et/ou du ou des précurseur(s) de vitamines dans le poids total des compositions nettoyantes cosmétiques selon l’invention est de préférence de 0,005 à 2 % en poids, de manière davantage préférée de 0,006 à 1,5 % en poids, de manière particulièrement préférée de 0,008 à 1 % en poids et en particulier de 0,01 à 0,50 % en poids.The proportion by weight of the vitamin (s), of the derivative (s) of vitamin and / or of the precursor (s) of vitamins in the total weight of the cosmetic cleaning compositions according to the invention is preferably 0.005 to 2% by weight, more preferably 0.006 to 1.5% by weight, particularly preferably 0.008 to 1% by weight and in particular from 0.01 to 0.50% by weight.
Les extraits de végétaux appropriés sont notamment les extraits de thé vert, d’écorce de chêne, d’ortie, d’hamamélis, de houblon, de henné, de camomille, de bardane, de prêle, d’aubépine, de fleurs de tilleul, d’amandier, d’aloe vera, d’aiguille de pin, de marronnier, de palmier dattier, de cannelier, de bois de santal, de genévrier, de noix de coco, de mangue, d’abricot, de citron vert, de blé, de kiwi, de melon, d’orange, de pamplemousse, de sauge, de romarin, de bouleau, de mauve, de valériane, de limnanthe, de serpolet, d’achillée, de thym, de mélisse, de bugrane, de tussilage, de guimauve, de méristem, de ginseng, de café, de cacao, de moringa, de racine de gingembre, et des extraits de plantes ayurvédiques comme par exemple Aegle Marmelos (Bilwa), Cyperus Rotundus (Nagar Motha), Emblica Officinalis (Amalki), Morida Citrifolia (Ashyuka), Tinospora Cordifolia (Guduchi), Santalum album (Chandana), Crocus Sativus (Kumkuma), Cinnamonum Zeylanicum et Nelumbo Nucifera (Kamala), des graminées telles que le blé, l’orge, le seigle, l’avoine, l’épeautre, le maïs, les différentes variétés de mil (le millet commun, l’éleusine ou le sétaire d’Italie par exemple), la canne à sucre, le ray-grass, le vulpin des prés, l’Arrhenatherum elatius, l’agrostis, la fétuque des prés, la molinie, le bambou, l’herbe à coton, les espèces du genre Pennisetum, les espèces du genre Andropogonodeae (Imperata Cylindrica également appelée Red Baron ou paillote), le Cenchrus Ciliaris, les spartines, le chiendent pied de poule, les espèces du genre Eragrostis, les espèces du genre Cymbopogon (citronnelle), les Oryzeae (riz), les espèces du genre Zizania (riz sauvage), les ammophiles, les espèces du genre Helictotrichon, les houlques, la brize, le pâturin, les espèces du genre Elimus et les échinacées, en particulier Echinacea angustifolia DC, Echinacea paradoxa (Norton), Echinacea simulata, E. atrorubens, E. tennesiensis, Echinacea strigosa (Mc Gregor), Echinacea laevigata, Echinacea purpurea (L.) Moench et Echinacea pallida (Nutt), tous types d’algues, les mousses de corail et le varech (comme l’extrait de Macrocystis pyrifera), tous types de vin et péricarpe de Litchie chinensis.Suitable plant extracts include extracts of green tea, oak bark, nettle, witch hazel, hops, henna, chamomile, burdock, horsetail, hawthorn, linden flowers , almond, aloe vera, pine needle, chestnut, date palm, cinnamon, sandalwood, juniper, coconut, mango, apricot, lime, wheat, kiwi, melon, orange, grapefruit, sage, rosemary, birch, mallow, valerian, meadowfoam, wild thyme, yarrow, thyme, lemon balm, bugrane, coltsfoot, marshmallow, meristem, ginseng, coffee, cocoa, moringa, ginger root, and Ayurvedic plant extracts such as Aegle Marmelos (Bilwa), Cyperus Rotundus (Nagar Motha), Emblica Officinalis (Amalki), Morida Citrifolia (Ashyuka), Tinospora Cordifolia (Guduchi), Santalum album (Chandana), Crocus Sativus (Kumkuma), Cinnamonum Zeylanicum and Nelumbo Nucifera (Kamala), gram such as wheat, barley, rye, oats, spelled, corn, different varieties of millet (common millet, finger millet or Italian foxtail for example), cane sugar, ryegrass, black grass, Arrhenatherum elatius, bentgrass, meadow fescue, molinia, bamboo, cotton grass, species of the genus Pennisetum, species of the genus Andropogonodeae ( Imperata Cylindrica also called Red Baron or straw hut), Cenchrus Ciliaris, spartines, houndstooth quackgrass, species of the genus Eragrostis, species of the genus Cymbopogon (lemongrass), Oryzeae (rice), species of the genus Zizania ( wild rice), ammophiles, species of the genus Helictotrichon, swells, brize, bluegrass, species of the genus Elimus and coneflowers, in particular Echinacea angustifolia DC, Echinacea paradoxa (Norton), Echinacea simulata, E. atrorubens, E. tennesiensis, Echinacea strigosa (Mc Gregor), Echinacea laevigata, Echinacea purpurea (L.) Moench and Echinacea pallida (Nutt), all types of algae, coral mosses and kelp (such as Macrocystis pyrifera extract), all types of wine and Litchie chinensis pericarp.
On peut obtenir des extraits appropriés à partir des fruits, des graines, des fleurs, des racines, des feuilles et/ou des écorces des plantes mentionnées ci-dessus ou à partir des plantes entières (algues, varech).Suitable extracts can be obtained from the fruits, seeds, flowers, roots, leaves and / or bark of the above-mentioned plants or from whole plants (algae, kelp).
On peut utiliser selon l’invention les extraits de végétaux soit sous une forme pure, soit sous une forme diluée. Lorsqu’ils sont utilisés sous forme diluée, ils contiennent généralement environ 2 à 80 % en poids de substance active ainsi que, en tant que solvant, l’agent d’extraction ou le mélange d’agents d’extraction utilisé pour leur obtention. L’eau et/ou les alcools sont généralement des agents d’extraction appropriés.Plant extracts can be used according to the invention either in a pure form or in a diluted form. When used in diluted form, they generally contain about 2 to 80% by weight of active substance as well as, as solvent, the extractant or the mixture of extractants used to obtain them. Water and / or alcohols are generally suitable extractants.
On peut utiliser l’extrait ou les extraits de végétaux dans les compositions cosmétiques selon l’invention, de préférence dans des quantités totales allant de 0,001 à 1 % en poids, de préférence de 0,05 à 0,75 % en poids et en particulier de 0,1 à 0,5 % en poids, les quantités indiquées se rapportant au poids des compositions cosmétiques.The plant extract or extracts can be used in the cosmetic compositions according to the invention, preferably in total amounts ranging from 0.001 to 1% by weight, preferably from 0.05 to 0.75% by weight and by weight. in particular from 0.1 to 0.5% by weight, the amounts indicated relating to the weight of the cosmetic compositions.
Par « hydrolysats de protéines appropriés », on entend les mélanges de produits pouvant être obtenus par dégradation par catalyse acide, alcaline ou enzymatique de protéines.The term “suitable protein hydrolysates” is understood to mean mixtures of products which can be obtained by degradation by acid, alkaline or enzymatic catalysis of proteins.
On peut utiliser des hydrolysats de protéines d’origine végétale, animale et/ou marine.Protein hydrolysates of plant, animal and / or marine origin can be used.
Les hydrolysats de protéine d’origine animale sont par exemple les hydrolysats de protéine d’élastine, de collagène, de kératine, de soie et de protéine de lait, qui peuvent également se présenter sous la forme de sels. De tels produits sont par exemple vendus sous les dénominations commerciales Dehylan® (Cognis), Promois® (Interorgana), Collapuron® (Cognis), Nutrilan® (Cognis), Gelita-Sol® (Deutsche Gelatine Fabriken Stoess & Co), Lexein® (Inolex) et Kerasol® (Croda).Examples of protein hydrolysates of animal origin are elastin, collagen, keratin, silk and milk protein hydrolysates, which can also be in the form of salts. Such products are for example sold under the trade names Dehylan® (Cognis), Promois® (Interorgana), Collapuron® (Cognis), Nutrilan® (Cognis), Gelita-Sol® (Deutsche Gelatine Fabriken Stoess & Co), Lexein® (Inolex) and Kerasol® (Croda).
On préfère les hydrolysats de protéines d’origine végétale, par exemple les hydrolysats de soja, d’amande, de riz, de pois, de pomme de terre et de blé. De tels produits sont par exemple disponibles sous les dénominations commerciales Gluadin® (Cognis), DiaMin® (Diamalt), Lexein® (Inolex) et Crotein® (Croda).Preferred are protein hydrolysates of vegetable origin, for example hydrolysates of soybean, almond, rice, pea, potato and wheat. Such products are for example available under the trade names Gluadin® (Cognis), DiaMin® (Diamalt), Lexein® (Inolex) and Crotein® (Croda).
On peut également utiliser les hydrolysats de protéines cationiques, l’hydrolysat de protéine de base pouvant être d’origine animale, par exemple issu du collagène, du lait ou de la kératine, d’origine végétale, par exemple issu du blé, du maïs, du riz, de la pomme de terre, du soja ou des amandes, d’origine marine, par exemple issu du collagène de poisson ou d’algues, ou issu des hydrolysats de protéines dérivés des biotechnologies. On peut obtenir les hydrolysats de protéines sous-jacent aux dérivés cationiques à partir des protéines correspondantes par hydrolyse chimique, en particulier alcaline ou acide, par hydrolyse enzymatique et/ou par une combinaison des deux types d’hydrolyse. L’hydrolyse de protéines donne généralement un hydrolysat de protéines ayant une distribution de masse moléculaire d’environ 100 daltons à plusieurs milliers de daltons. On préfère les hydrolysats de protéines cationiques dont la teneur en protéines de base présente une masse moléculaire de 100 à 25 000 daltons, de préférence de 250 à 5 000 daltons. De plus, par acides aminés quaternaires et leurs mélanges, on entend des hydrolysats de protéines cationiques. La quaternisation des hydrolysats de protéines ou des acides aminés est souvent effectuée grâce à des sels d’ammonium quaternaires tels que les halogénures de N,N-diméthyle-N-(n-alkyle)-N-(2-hydroxy-3-chloro-n-propyle)-ammonium. De plus, on peut également transformer les hydrolysats de protéines cationiques en dérivés. Des exemples classiques d’hydrolysats et de dérivés de protéines cationiques sont les produits disponibles dans le commerce et connus sous les noms INCI : Cocodimonium Hydroxypropyl Hydrolyzed Collagen, Cocodimopnium Hydroxypropyl Hydrolyzed Casein, Cocodimonium Hydroxypropyl Hydrolyzed Collagen, Cocodimonium Hydroxypropyl Hydrolyzed Hair Keratin, Cocodimonium Hydroxypropyl Hydrolyzed Keratin, Cocodimonium Hydroxypropyl Hydrolyzed Rice Protein, Cocodimonium Hydroxypropyl Hydrolyzed Silk, Cocodimonium Hydroxypropyl Hydrolyzed Soy Protein, Cocodimonium Hydroxypropyl Hydrolyzed Wheat Protein, Cocodimonium Hydroxypropyl Silk Amino Acids, Hydroxypropyl Arginine Lauryl/Myristyl Ether HCl, Hydroxypropyltrimonium Gelatin, Hydroxypropyltrimonium Hydrolyzed Casein, Hydroxypropyltrimonium Hydrolyzed Collagen, Hydroxypropyltrimonium Hydrolyzed Conchiolin Protein, Hydroxypropyltrimonium Hydrolyzed keratin, Hydroxypropyltrimonium Hydrolyzed Rice Bran Protein, Hydroxyproypltrimonium Hydrolyzed Silk, Hydroxypropyltrimonium Hydrolyzed Soy Protein, Hydroxypropyl Hydrolyzed Vegetable Protein, Hydroxypropyltrimonium Hydrolyzed Wheat Protein, Hydroxypropyltrimonium Hydrolyzed Wheat Protein/Siloxysilicate, Laurdimonium Hydroxypropyl Hydrolyzed Soy Protein, Laurdimonium Hydroxypropyl Hydrolyzed Wheat Protein, Laurdimonium Hydroxypropyl Hydrolyzed Wheat Protein/Siloxysilicate, Lauryldimonium Hydroxypropyl Hydrolyzed Casein, Lauryldimonium Hydroxypropyl Hydrolyzed Collagen, Lauryldimonium Hydroxypropyl Hydrolyzed Keratin, Lauryldimonium Hydroxypropyl Hydrolyzed Silk, Lauryldimonium Hydroxypropyl Hydrolyzed Soy Protein, Steardimonium Hydroxypropyl Hydrolyzed Casein, Steardimonium Hydroxypropyl Hydrolyzed Collagen, Steardimonium Hydroxypropyl Hydrolyzed Keratin, Steardimonium Hydroxypropyl Hydrolyzed Rice Protein, Steardimonium Hydroxypropyl Hydrolyzed Silk, Steardimonium Hydroxypropyl Hydrolyzed Soy Protein, Steardimonium Hydroxypropyl Hydrolyzed Vegetable Protein, Steardimonium Hydroxypropyl Hydrolyzed Wheat Protein, Steartrimonium Hydroxyethyl Hydrolyzed Collagen, Quaternium-76 Hydrolyzed Collagen, Quaternium-79 Hydrolyzed Collagen, Quaternium-79 Hydrolyzed Keratin, Quaternium-79 Hydrolyzed Milk Protein, Quaternium-79 Hydrolyzed Silk, Quaternium-79 Hydrolyzed Soy Protein, Quaternium-79 Hydrolyzed Wheat Protein.It is also possible to use hydrolysates of cationic proteins, the basic protein hydrolyzate possibly being of animal origin, for example obtained from collagen, milk or keratin, of plant origin, for example obtained from wheat, corn. , rice, potato, soya or almonds, of marine origin, for example derived from fish or algae collagen, or derived from protein hydrolysates derived from biotechnologies. The protein hydrolysates underlying the cationic derivatives can be obtained from the corresponding proteins by chemical hydrolysis, in particular alkaline or acidic, by enzymatic hydrolysis and / or by a combination of the two types of hydrolysis. Protein hydrolysis typically results in a protein hydrolyzate with a molecular weight distribution of from about 100 daltons to several thousand daltons. Preferred are cationic protein hydrolysates in which the basic protein content has a molecular weight of 100 to 25,000 daltons, preferably 250 to 5,000 daltons. In addition, the term “quaternary amino acids and their mixtures” is understood to mean hydrolysates of cationic proteins. Quaternization of protein hydrolysates or amino acids is often carried out using quaternary ammonium salts such as the halides of N, N-dimethyl-N- (n-alkyl) -N- (2-hydroxy-3-chloro -n-propyl) -ammonium. In addition, it is also possible to transform the hydrolysates of cationic proteins into derivatives. Classic examples of hydrolysates and cationic protein derivatives are the products available commercially and known under the INCI names: Cocodimonium Hydroxypropyl Hydrolyzed Collagen, Cocodimopnium Hydroxypropyl Hydrolyzed Casein, Cocodimonium Hydroxypropyl Hydrolyzed Collagen, Cocodimonium Hydroxypropyl Hydroxypropyl Hydroxypropyl Hair Keratin, Keratin, Cocodimonium Hydroxypropyl Hydrolyzed Rice Protein, Cocodimonium Hydroxypropyl Hydrolyzed Silk, Cocodimonium Hydroxypropyl Hydrolyzed Soy Protein, Cocodimonium Hydroxypropyl Hydrolyzed Wheat Protein, Cocodimonium Hydroxypropyl Silk Amino Acids, Hydroxypropyl arginine lauryl / myristyl Ether HCl, hydroxypropyltrimonium Gelatin, hydroxypropyltrimonium Hydrolyzed Casein, hydroxypropyltrimonium Hydrolyzed Collagen, Hydroxypropyltrimonium Hydrolyzed Conchiolin Protein, Hydroxypropyltrimonium Hydrolyzed keratin, Hydroxypropyltrimonium Hydrolyzed Rice Bran Protein, Hydroxyproypltrimonium Hydrolyzed Silk, Hydroxypropyltrimonium Hydrolyzed Soy Protein, Hydroxypropyl Hydrolyzed Vegetable Protein, Hydroxypropyltrimonium Hydrolyzed Wheat Protein, Hydroxypropyltrimonium Hydrolyzed Wheat Protein / siloxysilicate, Laurdimonium Hydroxypropyl Hydrolyzed Soy Protein, Laurdimonium Hydroxypropyl Hydrolyzed Wheat Protein, Laurdimonium Hydroxypropyl Hydrolyzed Wheat Protein / siloxysilicate, Lauryldimonium Hydroxypropyl Hydrolyzed Casein, Lauryldimonium Hydroxypropyl Hydrolyzed Collagen, Lauryldimonium Hydroxypropyl Hydrolyzed Keratin, Lauryldimonium Hydroxypropyl Hydrolyzed Silk, Lauryldimonium Hydroxypropyl Hydrolyzed Soy Protein, Steardimonium Hydroxypropyl Hydrolyzed Casein, Steardimonium Hydroxypropyl Hydrolyzed Collagen, Steardimonium Hydroxypropyl Hydrolyzed Keratin, Steardimonium Hydroxypropyl Hydrolyzed Rice Protein, Steardimonium Hydroxypropyl Hydrolyzed Silk, Steardimonium Hydroxypropyl Hydrolyzed Soy Protein, Steardimonium Hydroxypropyl Hydrolyzed Vegetable Protein, Steardimonium Hydroxypropy l Hydrolyzed Wheat Protein, Steartrimonium Hydroxyethyl Hydrolyzed Collagen, Quaternium-76 Hydrolyzed Collagen, Quaternium-79 Hydrolyzed Collagen, Quaternium-79 Hydrolyzed Keratin, Quaternium-79 Hydrolyzed Milk Protein, Quaternium-79 Hydrolyzed Silk, Quaternium Soy-79- Hydrolyzed Silk, Quaternium Soyote-79- 79- Hydrolyote Protein 79 Hydrolyzed Wheat Protein.
La proportion en poids du ou des hydrolysat(s) de protéines par rapport au poids total des compositions cosmétiques est de manière préférée de 0,01 à 5 % en poids, de manière davantage préférée de 0,025 à 3 % en poids et en particulier de 0,05 à 2 % en poids.The proportion by weight of the protein hydrolyzate (s) relative to the total weight of the cosmetic compositions is preferably from 0.01 to 5% by weight, more preferably from 0.025 to 3% by weight and in particular of 0.05 to 2% by weight.
Au sens de la présente invention, les agents antipelliculaires appropriés sont les piroctones, l’olamine, le climbazole, le zinc, la pyrithione, le kétoconazole, l’acide salicylique, le soufre, le sulfure de sélénium, les préparations de goudron, les dérivés d’acide undécénoïque, les extraits de racine de bardane, les extraits de peuplier, les extraits d’ortie, les extraits de coquille de noix, les extraits de bouleau, les extraits d’écorce de saule, les extraits de romarin, les extraits d’arnica et/ou le caprylate de propanediol.For the purposes of the present invention, suitable anti-dandruff agents are piroctones, olamine, climbazole, zinc, pyrithione, ketoconazole, salicylic acid, sulfur, selenium sulphide, tar preparations, undecenoic acid derivatives, burdock root extracts, poplar extracts, nettle extracts, walnut shell extracts, birch extracts, willow bark extracts, rosemary extracts, extracts of arnica and / or propanediol caprylate.
On préfère utiliser dans les compositions cosmétiques selon l’invention des principes actifs naturels antipelliculaires tels que les extraits végétaux mentionnés ci-dessus et/ou des principes actifs antipelliculaires disponibles à partir de sources naturelles telles que le caprylate de propanediol.It is preferred to use in the cosmetic compositions according to the invention natural anti-dandruff active ingredients such as the plant extracts mentioned above and / or anti-dandruff active ingredients available from natural sources such as propanediol caprylate.
La proportion en poids d’agents antipelliculaires dans le poids total des compositions cosmétiques selon l’invention est de préférence de 0,01 à 5 % en poids, de manière davantage préférée de 0,025 à 4 % en poids et de manière particulièrement préférée de 0,05 à 3 % en poids.The proportion by weight of anti-dandruff agents in the total weight of the cosmetic compositions according to the invention is preferably from 0.01 to 5% by weight, more preferably from 0.025 to 4% by weight and particularly preferably from 0 0.05 to 3% by weight.
Selon un autre mode de réalisation préféré de la présente invention, la proportion en poids, par rapport au poids total de la composition cosmétique, des ingrédients de la composition cosmétique qui sont sensiblement d’origine naturelle est supérieure ou égale à 90 % en poids, de manière particulièrement préférée est égale à 92,5 % en poids et en particulier est supérieure ou égale à 95 % en poids. Il convient de considérer un ingrédient conforme à la norme ISO 16128 ou à la norme COSMOS comme « essentiellement d’origine naturelle ».According to another preferred embodiment of the present invention, the proportion by weight, relative to the total weight of the cosmetic composition, of the ingredients of the cosmetic composition which are substantially of natural origin is greater than or equal to 90% by weight, particularly preferably is equal to 92.5% by weight and in particular is greater than or equal to 95% by weight. An ingredient conforming to ISO 16128 or COSMOS should be considered as "predominantly of natural origin".
D’autres principes actifs, adjuvants et additifs qui peuvent de préférence être contenus dans les compositions cosmétiques selon l’invention sont par exemple :Other active ingredients, adjuvants and additives which may preferably be contained in the cosmetic compositions according to the invention are, for example:
- les parfums,- the perfumes,
- les filtres UV,- UV filters,
- les cyclodextrines,- cyclodextrins,
- les colorants (naturels) pour colorer l’agent,- dyes (natural) to color the agent,
- les principes actifs tels que le bisabolol et/ou l’allantoïne,- active ingredients such as bisabolol and / or allantoin,
- les agents de chélation tels que l’EDTA, le NTA, l’acide β-alanine diacétique et les acides phosphoniques,- chelating agents such as EDTA, NTA, β-alanine diacetic acid and phosphonic acids,
- les céramides. Par céramides, on entend la N-acylsphingosine (amides d’acides gras de sphingosine) ou les analogues synthétiques de ces lipides (appelés pseudo-céramides),- ceramides. By ceramides is meant N-acylsphingosine (sphingosine fatty acid amides) or synthetic analogues of these lipids (called pseudo-ceramides),
- les antioxydants,- antioxidants,
- les agents conservateurs, tels que le benzoate de sodium ou l’acide salicylique,- preservatives, such as sodium benzoate or salicylic acid,
- les agents d’ajustement du pH tels que l’acide citrique et/ou l’acide lactique,- pH adjusting agents such as citric acid and / or lactic acid,
- les régulateurs de viscosité tels que les sels (NaCl).- viscosity regulators such as salts (NaCl).
Un deuxième objet de l’invention est l’utilisation, en particulier sous forme de shampooing, d’une composition cosmétique selon l’invention pour le nettoyage et le soin des cheveux humains.A second object of the invention is the use, in particular in the form of a shampoo, of a cosmetic composition according to the invention for cleaning and caring for human hair.
En ce qui concerne d’autres modes de réalisation préférés de l’utilisation selon l’invention, ce qui a été dit au sujet des compositions selon l’invention s’applique.With regard to other preferred embodiments of the use according to the invention, what has been said about the compositions according to the invention applies.
Les exemples suivants sont destinés à illustrer l’objet de la présente invention sans la limiter à ceux-ci.The following examples are intended to illustrate the object of the present invention without limiting it thereto.
Exemples :Examples:
Les compositions cosmétiques selon l’invention suivantes ont été préparées (les quantités indiquées sont exprimées en [% en poids]) :The following cosmetic compositions according to the invention were prepared (the amounts indicated are expressed in [% by weight]):
On a préparé un shampooing de référence, comprenant (en [% en poids) :A reference shampoo was prepared, comprising (in [% by weight):
- 7,5 % en poids de sulfate de coco,- 7.5% by weight of coconut sulphate,
- 7,5 % en poids de glucoside de coco,- 7.5% by weight of coconut glucoside,
- 0,3 % en poids de Guar Hydroxypropyltrimonium Chloride,- 0.3% by weight of Guar Hydroxypropyltrimonium Chloride,
- de petites quantités- small quantities
° d’acide citrique° citric acid
° de chlorure de sodium,° sodium chloride,
° de benzoate de sodium° sodium benzoate
- de l’eau (complément jusqu’à 100)- water (complement up to 100)
La composition 3 selon l’invention et la composition de référence ont été soumises à un test de demi-face, dans lequel on a constaté que les cheveux traités avec la composition 3 peuvent être mieux démêlés à l’état humide et sec et présentent plus de douceur, de souplesse et d’élasticité.Composition 3 according to the invention and the reference composition were subjected to a half-face test, in which it was observed that the hair treated with composition 3 can be better disentangled in the wet and dry state and exhibit more of softness, suppleness and elasticity.
Claims (10)
a) au moins un alkylsulfate en C8-30,
b) au moins un alkyl(oligo)glycoside et
c) de la triméthylglycine.Cosmetic composition for cleaning and caring for keratin fibers, in particular human hair, containing:
a) at least one C 8-30 alkyl sulphate,
b) at least one alkyl (oligo) glycoside and
c) trimethylglycine.
- 1,00 à 15 % en poids d’au moins un alkylsulfate en C8-30,
- 0,10 à 15 % en poids d’au moins un alkyl(oligo)glycoside,
- 0,01 à 5 % en poids de triméthylglycine.Cosmetic composition according to claim 1 containing (relative to the total weight of the composition)
- 1.00 to 15% by weight of at least one C 8-30 alkyl sulphate,
- 0.10 to 15% by weight of at least one alkyl (oligo) glycoside,
- 0.01 to 5% by weight of trimethylglycine.
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DE102020206286.2A DE102020206286A1 (en) | 2020-05-19 | 2020-05-19 | Cleaning compositions with a high proportion of natural components |
DE102020206286.2 | 2020-05-19 |
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CN107454837B (en) * | 2016-09-12 | 2019-08-20 | 拉芳家化股份有限公司 | A kind of shampoo composite of the complexing agent of moisturizing containing hair |
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2020
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