FR3096512B1 - Electrolyte a base de sels de lithium - Google Patents

Electrolyte a base de sels de lithium Download PDF

Info

Publication number
FR3096512B1
FR3096512B1 FR1905387A FR1905387A FR3096512B1 FR 3096512 B1 FR3096512 B1 FR 3096512B1 FR 1905387 A FR1905387 A FR 1905387A FR 1905387 A FR1905387 A FR 1905387A FR 3096512 B1 FR3096512 B1 FR 3096512B1
Authority
FR
France
Prior art keywords
lithium salts
electrolyte based
lithium
relates
present
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
FR1905387A
Other languages
English (en)
Other versions
FR3096512A1 (fr
Inventor
Gregory Schmidt
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Arkema France SA
Original Assignee
Arkema France SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to FR1905387A priority Critical patent/FR3096512B1/fr
Application filed by Arkema France SA filed Critical Arkema France SA
Priority to EP20737250.9A priority patent/EP3973587A1/fr
Priority to KR1020217041751A priority patent/KR20220010030A/ko
Priority to CN202080036394.XA priority patent/CN113826255A/zh
Priority to JP2021568895A priority patent/JP2022533402A/ja
Priority to PCT/FR2020/050829 priority patent/WO2020234538A1/fr
Priority to US17/594,258 priority patent/US20220166066A1/en
Publication of FR3096512A1 publication Critical patent/FR3096512A1/fr
Application granted granted Critical
Publication of FR3096512B1 publication Critical patent/FR3096512B1/fr
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
    • H01M10/0566—Liquid materials
    • H01M10/0567—Liquid materials characterised by the additives
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
    • H01M10/0566—Liquid materials
    • H01M10/0568—Liquid materials characterised by the solutes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
    • H01M10/0566—Liquid materials
    • H01M10/0569—Liquid materials characterised by the solvents
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/42—Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
    • H01M10/4235—Safety or regulating additives or arrangements in electrodes, separators or electrolyte
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
    • H01M4/381—Alkaline or alkaline earth metals elements
    • H01M4/382—Lithium
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2220/00—Batteries for particular applications
    • H01M2220/20—Batteries in motive systems, e.g. vehicle, ship, plane
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2220/00—Batteries for particular applications
    • H01M2220/30—Batteries in portable systems, e.g. mobile phone, laptop
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00—Electrolytes
    • H01M2300/0017—Non-aqueous electrolytes
    • H01M2300/0025—Organic electrolyte
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • General Physics & Mathematics (AREA)
  • Inorganic Chemistry (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Physics & Mathematics (AREA)
  • Materials Engineering (AREA)
  • Secondary Cells (AREA)
  • Battery Electrode And Active Subsutance (AREA)

Abstract

ELECTROLYTE A BASE DE SELS DE LITHIUM La présente invention concerne une composition d’électrolyte comprenant : - le 2-trifluorométhyl-4,5-dicyano-imidazolate de lithium, - le bis(fluorosulfonyl)imidure de lithium, - le nitrate de lithium, et - au moins un additif (A) permettant la formation d’une couche de passivation SEI,et - au moins un solvant non-aqueux. La présente invention concerne également ses utilisations dans une batterie Li-ion. Figure : non
FR1905387A 2019-05-22 2019-05-22 Electrolyte a base de sels de lithium Expired - Fee Related FR3096512B1 (fr)

Priority Applications (7)

Application Number Priority Date Filing Date Title
FR1905387A FR3096512B1 (fr) 2019-05-22 2019-05-22 Electrolyte a base de sels de lithium
KR1020217041751A KR20220010030A (ko) 2019-05-22 2020-05-19 리튬 염의 혼합물을 함유하는 전해질 조성물
CN202080036394.XA CN113826255A (zh) 2019-05-22 2020-05-19 含有锂盐的混合物的电解质组合物
JP2021568895A JP2022533402A (ja) 2019-05-22 2020-05-19 リチウム塩の混合物を含有する電解質組成物
EP20737250.9A EP3973587A1 (fr) 2019-05-22 2020-05-19 Composition d'electrolyte comprenant un mélange de sels de lithium
PCT/FR2020/050829 WO2020234538A1 (fr) 2019-05-22 2020-05-19 Composition d'electrolyte comprenant un mélange de sels de lithium
US17/594,258 US20220166066A1 (en) 2019-05-22 2020-05-19 Electrolyte composition containing a mixture of lithium salts

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1905387A FR3096512B1 (fr) 2019-05-22 2019-05-22 Electrolyte a base de sels de lithium
FR1905387 2019-05-22

Publications (2)

Publication Number Publication Date
FR3096512A1 FR3096512A1 (fr) 2020-11-27
FR3096512B1 true FR3096512B1 (fr) 2021-11-05

Family

ID=67742780

Family Applications (1)

Application Number Title Priority Date Filing Date
FR1905387A Expired - Fee Related FR3096512B1 (fr) 2019-05-22 2019-05-22 Electrolyte a base de sels de lithium

Country Status (7)

Country Link
US (1) US20220166066A1 (fr)
EP (1) EP3973587A1 (fr)
JP (1) JP2022533402A (fr)
KR (1) KR20220010030A (fr)
CN (1) CN113826255A (fr)
FR (1) FR3096512B1 (fr)
WO (1) WO2020234538A1 (fr)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2022024568A1 (fr) * 2020-07-30 2022-02-03 パナソニックＩｐマネジメント株式会社 Batterie secondaire au lithium
CN113013486A (zh) * 2021-02-25 2021-06-22 珠海冠宇电池股份有限公司 一种电解液及包括该电解液的锂离子电池
KR20230157395A (ko) * 2021-03-16 2023-11-16 일렉트로바야 인코포레이티드 재충전가능 고체-상태 리튬 이온 배터리
US12438195B2 (en) 2021-07-29 2025-10-07 Lg Energy Solution, Ltd. Non-aqueous electrolyte, and lithium secondary battery comprising the same
CN113823840A (zh) * 2021-10-29 2021-12-21 中南大学 一种锂金属负极用电解液
JP2024544468A (ja) * 2021-11-10 2024-12-03 エレクトロバヤ インコーポレイテッド リチウムイオン伝導性セパレータ膜
CN114284558B (zh) * 2021-12-29 2023-05-05 惠州亿纬锂能股份有限公司 一种锂离子电池电解液及锂离子电池
US20250158122A1 (en) * 2022-01-28 2025-05-15 Panasonic Energy Co., Ltd. Non-aqueous electrolyte secondary battery
CN117525598A (zh) * 2022-07-29 2024-02-06 鸿海精密工业股份有限公司 难燃电解质及其制备方法以及锂离子电池
CN115602926B (zh) * 2022-12-16 2023-04-28 河北省科学院能源研究所 一种耐高温电解液及其制备方法和应用
GB2642943A (en) * 2024-06-11 2026-02-04 Dyson Technology Ltd Electrolyte composition
GB2641750A (en) * 2024-06-11 2025-12-17 Dyson Technology Ltd Electrolyte composition

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5970752B2 (ja) * 2011-07-04 2016-08-17 日本電気株式会社 二次電池の製造方法
FR2982610B1 (fr) 2011-11-14 2016-01-08 Arkema France Procede de preparation de sel d'anion pentacylique
FR2983466B1 (fr) * 2011-12-06 2014-08-08 Arkema France Utilisation de melanges de sels de lithium comme electrolytes de batteries li-ion
FR2991323B1 (fr) * 2012-06-04 2014-06-13 Arkema France Sel d'anions bicycliques aromatiques pour batteries li-ion
DE102013210631A1 (de) * 2013-06-07 2014-12-11 Volkswagen Aktiengesellschaft Neue Elektrolytzusammensetzung für Hochenergieanoden
FR3020060B1 (fr) 2014-04-18 2016-04-01 Arkema France Preparation d'imides contenant un groupement fluorosulfonyle
US9627716B2 (en) * 2014-12-16 2017-04-18 GM Global Technology Operations LLC Electrolyte and lithium based batteries
WO2017049471A1 (fr) * 2015-09-23 2017-03-30 Basf Corporation Électrolyte pour piles lithium-ion du type lto
KR102050836B1 (ko) * 2015-12-08 2019-12-03 주식회사 엘지화학 리튬이차전지용 전해질 및 이를 포함하는 리튬이차전지
KR101994879B1 (ko) * 2016-01-12 2019-07-01 주식회사 엘지화학 리튬-황 전지용 비수계 전해액 및 이를 포함하는 리튬-황 전지
US10347943B2 (en) * 2016-09-14 2019-07-09 Uchicago Argonne, Llc Fluoro-substituted ethers and compositions
CN106505249B (zh) * 2016-12-15 2021-01-05 东莞市杉杉电池材料有限公司 一种锂离子电池电解液及含该电解液的锂离子电池
FR3064822B1 (fr) * 2017-04-04 2019-06-07 Arkema France Melange de sels de lithium et ses utilisations comme electrolyte de batterie
FR3069959B1 (fr) * 2017-08-07 2019-08-23 Arkema France Melange de sels de lithium et ses utilisations comme electrolyte de batterie
KR102183664B1 (ko) * 2017-09-21 2020-11-26 주식회사 엘지화학 리튬 이차 전지용 전해액 및 이를 포함하는 리튬-이차 전지
CN107834073B (zh) * 2017-11-02 2021-02-09 南京航空航天大学 一种锂金属电池负极枝晶抑制剂及其使用方法

Also Published As

Publication number Publication date
CN113826255A (zh) 2021-12-21
EP3973587A1 (fr) 2022-03-30
US20220166066A1 (en) 2022-05-26
KR20220010030A (ko) 2022-01-25
WO2020234538A1 (fr) 2020-11-26
JP2022533402A (ja) 2022-07-22
FR3096512A1 (fr) 2020-11-27

Similar Documents

Publication Publication Date Title
FR3096512B1 (fr) Electrolyte a base de sels de lithium
Zhang et al. The electrolyte comprising more robust water and superhalides transforms Zn‐metal anode reversibly and dendrite‐free
Li et al. 40 years of low‐temperature electrolytes for rechargeable lithium batteries
Su et al. Cyclic carbonate for highly stable cycling of high voltage lithium metal batteries
Esser et al. A perspective on organic electrode materials and technologies for next generation batteries
Schedlbauer et al. Lithium difluoro (oxalato) borate: A promising salt for lithium metal based secondary batteries?
Lin et al. High temperature electrical energy storage: advances, challenges, and frontiers
Zhao et al. High‐performance lithium‐iodine flow battery
WO2018218057A3 (fr) Composés conducteur d'ions et utilisations associées
Wang et al. Mixtures of unsaturated imidazolium based ionic liquid and organic carbonate as electrolyte for Li-ion batteries
JP6520064B2 (ja) 非水電解液電池用電解液及びリチウム非水電解液電池
Li et al. Competitive Li+ Coordination in Ionogel Electrolytes for Enhanced Li‐Ion Transport Kinetics
WO2010012179A9 (fr) Electrolyte pour batteries au lithium, batteries au lithium et procédé de production associé
TW200713666A (en) Overcharge protection for electrochemical cells
US20180175470A1 (en) Lithium-bromine rechargeable electrochemical system and applications thereof
WO2010058993A3 (fr) Batterie secondaire lithium aux caractéristiques améliorées
US10505219B2 (en) Artificial SEI transplantation
WO2013087348A3 (fr) Séparateur d'élément lithium-soufre comportant une couche barrière polysulfure
WO2005121413A3 (fr) Batterie a electrolyte de sel fondu et a cathode contenant du phosphore
EP4235898A3 (fr) Électrolyte pour pile à électrolyte non aqueux, et pile à électrolyte non aqueux dans laquelle celui-ci est utilisé
BRPI1016053A8 (pt) Método e aparelho de comunicação
CY1118959T1 (el) Μεθοδος για την κατασκευη μπαταριων ιοντων λιθιου μεγαλου σχηματος
JP2014515168A (ja) リチウム空気バッテリセル
KR20160136344A (ko) 금속 기반 배터리의 덴드라이트 억제 전해질
TW200729587A (en) Additives for non-aqueous electrolyte and lithium secondary battery using the same

Legal Events

Date Code Title Description
PLFP Fee payment

Year of fee payment: 2

PLSC Publication of the preliminary search report

Effective date: 20201127

PLFP Fee payment

Year of fee payment: 3

PLFP Fee payment

Year of fee payment: 4

PLFP Fee payment

Year of fee payment: 5

PLFP Fee payment

Year of fee payment: 6

ST Notification of lapse

Effective date: 20260106