FR3096369B1 - Procédé de polymérisation d’une composition en présence de copolymère à blocs - Google Patents

Procédé de polymérisation d’une composition en présence de copolymère à blocs Download PDF

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Publication number
FR3096369B1
FR3096369B1 FR1905519A FR1905519A FR3096369B1 FR 3096369 B1 FR3096369 B1 FR 3096369B1 FR 1905519 A FR1905519 A FR 1905519A FR 1905519 A FR1905519 A FR 1905519A FR 3096369 B1 FR3096369 B1 FR 3096369B1
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FR
France
Prior art keywords
polymerizing
composition
block copolymer
relates
present
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
FR1905519A
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English (en)
Other versions
FR3096369A1 (fr
Inventor
Sylvain Bourrigaud
Anne-Laure Brocas
Sylvie Cazaumayou
Andujar Laura Garcia
Maud Save
Christophe Derail
Laurent Rubatat
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Centre National de la Recherche Scientifique CNRS
Arkema France SA
Universite de Pau et des Pays de lAdour
Original Assignee
Centre National de la Recherche Scientifique CNRS
Arkema France SA
Universite de Pau et des Pays de lAdour
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to FR1905519A priority Critical patent/FR3096369B1/fr
Application filed by Centre National de la Recherche Scientifique CNRS, Arkema France SA, Universite de Pau et des Pays de lAdour filed Critical Centre National de la Recherche Scientifique CNRS
Priority to US17/612,839 priority patent/US20220275136A1/en
Priority to EP20737517.1A priority patent/EP3976351A1/fr
Priority to KR1020217040977A priority patent/KR20220047213A/ko
Priority to CN202080038511.6A priority patent/CN114127142A/zh
Priority to PCT/FR2020/050827 priority patent/WO2020240115A1/fr
Priority to JP2021569547A priority patent/JP2022534234A/ja
Publication of FR3096369A1 publication Critical patent/FR3096369A1/fr
Application granted granted Critical
Publication of FR3096369B1 publication Critical patent/FR3096369B1/fr
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F287/00Macromolecular compounds obtained by polymerising monomers on to block polymers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C64/00Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
    • B29C64/10Processes of additive manufacturing
    • B29C64/106Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material
    • B29C64/118Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using filamentary material being melted, e.g. fused deposition modelling [FDM]
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C64/00Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
    • B29C64/10Processes of additive manufacturing
    • B29C64/106Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material
    • B29C64/124Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified
    • B29C64/129Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified characterised by the energy source therefor, e.g. by global irradiation combined with a mask
    • B29C64/135Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified characterised by the energy source therefor, e.g. by global irradiation combined with a mask the energy source being concentrated, e.g. scanning lasers or focused light sources
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C64/00Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
    • B29C64/30Auxiliary operations or equipment
    • B29C64/307Handling of material to be used in additive manufacturing
    • B29C64/314Preparation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B33ADDITIVE MANUFACTURING TECHNOLOGY
    • B33YADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
    • B33Y10/00Processes of additive manufacturing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B33ADDITIVE MANUFACTURING TECHNOLOGY
    • B33YADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
    • B33Y70/00Materials specially adapted for additive manufacturing
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/02Polymerisation in bulk
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/38Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10Esters
    • C08F220/12Esters of monohydric alcohols or phenols
    • C08F220/14Methyl esters, e.g. methyl (meth)acrylate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2438/00Living radical polymerisation
    • C08F2438/02Stable Free Radical Polymerisation [SFRP]; Nitroxide Mediated Polymerisation [NMP] for, e.g. using 2,2,6,6-tetramethylpiperidine-1-oxyl [TEMPO]

Abstract

Procédé de polymérisation d’une composition en présence de copolymère à blocs La présente invention concerne un procédé de polymérisation d’une composition en présence d’au moins un copolymère à blocs, ainsi que les produits obtenus par ce procédé de polymérisation. La présente invention concerne également l’utilisation des produits obtenus à l’aide du procédé de polymérisation objet de l’invention.
FR1905519A 2019-05-24 2019-05-24 Procédé de polymérisation d’une composition en présence de copolymère à blocs Expired - Fee Related FR3096369B1 (fr)

Priority Applications (7)

Application Number Priority Date Filing Date Title
FR1905519A FR3096369B1 (fr) 2019-05-24 2019-05-24 Procédé de polymérisation d’une composition en présence de copolymère à blocs
EP20737517.1A EP3976351A1 (fr) 2019-05-24 2020-05-19 Procede de polymerisation d'une composition en presence de copolymere a blocs
KR1020217040977A KR20220047213A (ko) 2019-05-24 2020-05-19 블록 공중합체의 존재 하의 조성물의 중합 방법
CN202080038511.6A CN114127142A (zh) 2019-05-24 2020-05-19 在嵌段共聚物的存在下使组合物聚合的方法
US17/612,839 US20220275136A1 (en) 2019-05-24 2020-05-19 Process for polymerizing a composition in the presence of a block copolymer
PCT/FR2020/050827 WO2020240115A1 (fr) 2019-05-24 2020-05-19 Procede de polymerisation d'une composition en presence de copolymere a blocs
JP2021569547A JP2022534234A (ja) 2019-05-24 2020-05-19 ブロックコポリマーの存在下で組成物を重合する方法

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1905519 2019-05-24
FR1905519A FR3096369B1 (fr) 2019-05-24 2019-05-24 Procédé de polymérisation d’une composition en présence de copolymère à blocs

Publications (2)

Publication Number Publication Date
FR3096369A1 FR3096369A1 (fr) 2020-11-27
FR3096369B1 true FR3096369B1 (fr) 2022-01-14

Family

ID=68987738

Family Applications (1)

Application Number Title Priority Date Filing Date
FR1905519A Expired - Fee Related FR3096369B1 (fr) 2019-05-24 2019-05-24 Procédé de polymérisation d’une composition en présence de copolymère à blocs

Country Status (7)

Country Link
US (1) US20220275136A1 (fr)
EP (1) EP3976351A1 (fr)
JP (1) JP2022534234A (fr)
KR (1) KR20220047213A (fr)
CN (1) CN114127142A (fr)
FR (1) FR3096369B1 (fr)
WO (1) WO2020240115A1 (fr)

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4598123A (en) * 1983-07-14 1986-07-01 Unites States Steel Corporation Impact modified methyl methacrylate polymer
DE19523585A1 (de) * 1995-06-29 1997-01-02 Basf Ag Schlagzähe Formmasse aus Styrolpolymeren
KR100551524B1 (ko) * 2002-01-22 2006-02-13 아르끄마 니트록사이드 존재하에 조절된 라디칼 중합에 의해 수득된 블락 코폴리머를 함유하며 충격 강화된 물질의 제조 및 사용 방법
FR2861394B1 (fr) 2003-10-24 2006-01-20 Arkema Procede de preparation de polyalcoaxymines utilisables comme amorceurs pour la polymerisation radicalaire de (co)polymeres vivants polyfonctionnels
FR2879205B1 (fr) * 2004-12-10 2007-09-21 Arkema Sa Procede de preparation de plaques renforcees a l'impact par polymerisation radiculaire controlee
JP2009270020A (ja) * 2008-05-08 2009-11-19 Kaneka Corp 樹脂粉体の製造方法
FR2969633B1 (fr) * 2010-12-23 2015-02-06 Arkema France Composition pour des plaques coulees nanostructurees reticulees
WO2012144735A2 (fr) * 2011-04-22 2012-10-26 Lg Chem, Ltd. Nouveau copolymère diblocs, son procédé de préparation, et procédé de formation d'un nanomotif à l'aide de celui-ci
JP5554368B2 (ja) * 2012-04-27 2014-07-23 富士フイルム株式会社 レーザー彫刻用樹脂組成物、レーザー彫刻用フレキソ印刷版原版及びその製造方法、並びに、フレキソ印刷版及びその製版方法
JP5554367B2 (ja) * 2012-04-27 2014-07-23 富士フイルム株式会社 レーザー彫刻用樹脂組成物、レーザー彫刻用フレキソ印刷版原版及びその製造方法、並びに、フレキソ印刷版及びその製版方法
FR3029921B1 (fr) * 2014-12-16 2018-06-29 Arkema France Procede de controle de la synthese d'un copolymere a blocs contenant au moins un bloc apolaire et au moins un bloc polaire et utilisation d'un tel copolymere a blocs dans des applications de nano-lithographie par auto-assemblage direct.

Also Published As

Publication number Publication date
WO2020240115A1 (fr) 2020-12-03
JP2022534234A (ja) 2022-07-28
KR20220047213A (ko) 2022-04-15
FR3096369A1 (fr) 2020-11-27
US20220275136A1 (en) 2022-09-01
EP3976351A1 (fr) 2022-04-06
CN114127142A (zh) 2022-03-01

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