FR3091275B1 - Systeme et procede de stockage et de restitution de dihydrogene - Google Patents

Systeme et procede de stockage et de restitution de dihydrogene Download PDF

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Publication number
FR3091275B1
FR3091275B1 FR1874424A FR1874424A FR3091275B1 FR 3091275 B1 FR3091275 B1 FR 3091275B1 FR 1874424 A FR1874424 A FR 1874424A FR 1874424 A FR1874424 A FR 1874424A FR 3091275 B1 FR3091275 B1 FR 3091275B1
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dihydrogen
hydrogenation
storage
module
carbonyl group
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FR1874424A
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FR3091275A1 (fr
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Jacques Alagy
Pierre Jean Louis Trambouze
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Alagy Annie
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Alagy Annie
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Priority to FR1874424A priority Critical patent/FR3091275B1/fr
Priority to EP19850850.9A priority patent/EP3906214A1/fr
Priority to PCT/FR2019/053315 priority patent/WO2020141282A1/fr
Publication of FR3091275A1 publication Critical patent/FR3091275A1/fr
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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/22—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/0005—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes
    • C01B3/001—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes characterised by the uptaking medium; Treatment thereof
    • C01B3/0015—Organic compounds; Solutions thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/143—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of ketones
    • C07C29/145—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of ketones with hydrogen or hydrogen-containing gases
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/002—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by dehydrogenation
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0266—Processes for making hydrogen or synthesis gas containing a decomposition step
    • C01B2203/0277—Processes for making hydrogen or synthesis gas containing a decomposition step containing a catalytic decomposition step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1217—Alcohols
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/32—Hydrogen storage
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency
    • Y02P20/133—Renewable energy sources, e.g. sunlight

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Catalysts (AREA)

Abstract

- Système et procédé de stockage et de restitution de dihydrogène. - L’invention concerne un système de stockage et de restitution de dihydrogène (1), comprenant au moins : un module d’hydrogénation (6), au sein duquel du dihydrogène (H2) réagit, par hydrogénation catalytique, avec un substrat de base (SB), à structure hydrocarbonée aliphatique comportant au moins un premier groupement carbonyle de type cétone, pour former un substrat hydrogéné (SH), par hydrogénation dudit premier groupement carbonyle en un premier groupement hydroxyle, et un module de déshydrogénation (10), au sein duquel le substrat hydrogéné (SH) issu du module d’hydrogénation (6) subit une réaction de déshydrogénation catalytique pour régénérer lesdits substrat de base (SB) et dihydrogène (H2), tous deux à l’état gazeux, par déshydrogénation dudit premier groupement hydroxyle en ledit premier groupement carbonyle. - L’invention est particulièrement adaptée au stockage de dihydrogène en tant que vecteur d’énergie. - Figure pour l’abrégé : Figure 1.
FR1874424A 2018-12-31 2018-12-31 Systeme et procede de stockage et de restitution de dihydrogene Active FR3091275B1 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
FR1874424A FR3091275B1 (fr) 2018-12-31 2018-12-31 Systeme et procede de stockage et de restitution de dihydrogene
EP19850850.9A EP3906214A1 (fr) 2018-12-31 2019-12-30 Systeme et procede de stockage et de restitution de dihydrogene
PCT/FR2019/053315 WO2020141282A1 (fr) 2018-12-31 2019-12-30 Systeme et procede de stockage et de restitution de dihydrogene

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR1874424A FR3091275B1 (fr) 2018-12-31 2018-12-31 Systeme et procede de stockage et de restitution de dihydrogene

Publications (2)

Publication Number Publication Date
FR3091275A1 FR3091275A1 (fr) 2020-07-03
FR3091275B1 true FR3091275B1 (fr) 2022-07-22

Family

ID=67001937

Family Applications (1)

Application Number Title Priority Date Filing Date
FR1874424A Active FR3091275B1 (fr) 2018-12-31 2018-12-31 Systeme et procede de stockage et de restitution de dihydrogene

Country Status (3)

Country Link
EP (1) EP3906214A1 (fr)
FR (1) FR3091275B1 (fr)
WO (1) WO2020141282A1 (fr)

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10055717A1 (de) * 2000-11-10 2002-05-29 Jens Burfeind Verfahren zum Transport und zur Lagerung von Wasserstoff in chemisch fixierter Form
US7485161B2 (en) * 2005-01-04 2009-02-03 Air Products And Chemicals, Inc. Dehydrogenation of liquid fuel in microchannel catalytic reactor
US8338055B2 (en) * 2007-04-04 2012-12-25 General Electric Company System and method for electrochemical energy conversion and storage
JP5544630B2 (ja) * 2010-03-04 2014-07-09 国立大学法人大阪大学 単核金属錯体、水素化還元触媒、脱水素用触媒、水素化還元生成物の製造方法、水素（ｈ２）の製造方法および脱水素反応生成物の製造方法
WO2013125020A1 (fr) * 2012-02-23 2013-08-29 関東化学株式会社 Catalyseur de déshydrogénation, et procédé de production d'un composé carbonyle et d'hydrogène à l'aide dudit catalyseur
DE102012216669A1 (de) * 2012-09-18 2014-03-20 H2-Industries AG Anordnung und Verfahren zur Energieversorgung von Schiffen

Also Published As

Publication number Publication date
FR3091275A1 (fr) 2020-07-03
WO2020141282A1 (fr) 2020-07-09
EP3906214A1 (fr) 2021-11-10

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