FR3088325B1 - Derives 1,3-oxathiolane-2-thione et leurs utilisations - Google Patents

Derives 1,3-oxathiolane-2-thione et leurs utilisations Download PDF

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Publication number
FR3088325B1
FR3088325B1 FR1860359A FR1860359A FR3088325B1 FR 3088325 B1 FR3088325 B1 FR 3088325B1 FR 1860359 A FR1860359 A FR 1860359A FR 1860359 A FR1860359 A FR 1860359A FR 3088325 B1 FR3088325 B1 FR 3088325B1
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FR
France
Prior art keywords
oxathiolane
thione derivatives
thione
derivatives
relates
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
FR1860359A
Other languages
English (en)
French (fr)
Other versions
FR3088325A1 (fr
Inventor
Boris Colin
Guillaume Michaud
Stephane Fouquay
Frederic Simon
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bostik SA
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Bostik SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Application filed by Bostik SA filed Critical Bostik SA
Priority to FR1860359A priority Critical patent/FR3088325B1/fr
Priority to PCT/FR2019/052622 priority patent/WO2020094974A1/fr
Priority to JP2021524274A priority patent/JP7594526B2/ja
Priority to EP19818219.8A priority patent/EP3877375A1/fr
Priority to US17/292,110 priority patent/US20210395439A1/en
Priority to CN201980073673.0A priority patent/CN112969691B/zh
Publication of FR3088325A1 publication Critical patent/FR3088325A1/fr
Application granted granted Critical
Publication of FR3088325B1 publication Critical patent/FR3088325B1/fr
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72Polyisocyanates or polyisothiocyanates
    • C08G18/74Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/75Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic
    • C08G18/751Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring
    • C08G18/752Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group
    • C08G18/753Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate group
    • C08G18/755Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate group and at least one isocyanate or isothiocyanate group linked to a secondary carbon atom of the cycloaliphatic ring, e.g. isophorone diisocyanate
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D327/00Heterocyclic compounds containing rings having oxygen and sulfur atoms as the only ring hetero atoms
    • C07D327/02Heterocyclic compounds containing rings having oxygen and sulfur atoms as the only ring hetero atoms one oxygen atom and one sulfur atom
    • C07D327/04Five-membered rings
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02Silicon compounds
    • C07F7/08Compounds having one or more C—Si linkages
    • C07F7/18Compounds having one or more C—Si linkages as well as one or more C—O—Si linkages
    • C07F7/1804Compounds having Si-O-C linkages
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02Silicon compounds
    • C07F7/08Compounds having one or more C—Si linkages
    • C07F7/18Compounds having one or more C—Si linkages as well as one or more C—O—Si linkages
    • C07F7/1804Compounds having Si-O-C linkages
    • C07F7/1872Preparation; Treatments not provided for in C07F7/20
    • C07F7/1892Preparation; Treatments not provided for in C07F7/20 by reactions not provided for in C07F7/1876 - C07F7/1888
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08Processes
    • C08G18/10Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08Processes
    • C08G18/16Catalysts
    • C08G18/22Catalysts containing metal compounds
    • C08G18/227Catalysts containing metal compounds of antimony, bismuth or arsenic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08Processes
    • C08G18/16Catalysts
    • C08G18/22Catalysts containing metal compounds
    • C08G18/24Catalysts containing metal compounds of tin
    • C08G18/242Catalysts containing metal compounds of tin organometallic compounds containing tin-carbon bonds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/2805Compounds having only one group containing active hydrogen
    • C08G18/288Compounds containing at least one heteroatom other than oxygen or nitrogen
    • C08G18/289Compounds containing at least one heteroatom other than oxygen or nitrogen containing silicon
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30Low-molecular-weight compounds
    • C08G18/38Low-molecular-weight compounds having heteroatoms other than oxygen
    • C08G18/3855Low-molecular-weight compounds having heteroatoms other than oxygen having sulfur
    • C08G18/3876Low-molecular-weight compounds having heteroatoms other than oxygen having sulfur containing mercapto groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/48Polyethers
    • C08G18/4825Polyethers containing two hydroxy groups
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Heterocyclic Compounds Containing Sulfur Atoms (AREA)
  • Plural Heterocyclic Compounds (AREA)
FR1860359A 2018-11-09 2018-11-09 Derives 1,3-oxathiolane-2-thione et leurs utilisations Active FR3088325B1 (fr)

Priority Applications (6)

Application Number Priority Date Filing Date Title
FR1860359A FR3088325B1 (fr) 2018-11-09 2018-11-09 Derives 1,3-oxathiolane-2-thione et leurs utilisations
PCT/FR2019/052622 WO2020094974A1 (fr) 2018-11-09 2019-11-06 Dérivés 1,3-oxathiolane-2-thione et leurs utilisations
JP2021524274A JP7594526B2 (ja) 2018-11-09 2019-11-06 1,3-オキサチオラン-2-チオン誘導体及びその使用
EP19818219.8A EP3877375A1 (fr) 2018-11-09 2019-11-06 Dérivés 1,3-oxathiolane-2-thione et leurs utilisations
US17/292,110 US20210395439A1 (en) 2018-11-09 2019-11-06 1,3-oxathiolane-2-thione derivatives and uses thereof
CN201980073673.0A CN112969691B (zh) 2018-11-09 2019-11-06 1,3-氧硫杂环戊烷-2-硫酮衍生物及其用途

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR1860359A FR3088325B1 (fr) 2018-11-09 2018-11-09 Derives 1,3-oxathiolane-2-thione et leurs utilisations

Publications (2)

Publication Number Publication Date
FR3088325A1 FR3088325A1 (fr) 2020-05-15
FR3088325B1 true FR3088325B1 (fr) 2021-10-15

Family

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Application Number Title Priority Date Filing Date
FR1860359A Active FR3088325B1 (fr) 2018-11-09 2018-11-09 Derives 1,3-oxathiolane-2-thione et leurs utilisations

Country Status (6)

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US (1) US20210395439A1 (https=)
EP (1) EP3877375A1 (https=)
JP (1) JP7594526B2 (https=)
CN (1) CN112969691B (https=)
FR (1) FR3088325B1 (https=)
WO (1) WO2020094974A1 (https=)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102776100B1 (ko) * 2019-02-08 2025-03-07 바스프 에스이 우레탄 기 및 규소 원자를 포함하는 경화 중합체의 제조

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4618461A (en) * 1983-07-25 1986-10-21 The Dow Chemical Company O,O'-, O,S'- or S,S'-dithiodialkylene-bis(mono- or dihydrocarbyl carbamothioates) and S,S'-dithiodialkylene-bis(mono- or dihydrocarbyl carbamodithioates) and method of preparation thereof
US5866651A (en) * 1996-10-31 1999-02-02 Minnesota Mining And Manufacturing Company Hydroxycarbamoylalkoxysilane-based poly(ether-urethane) sealants having improved paint adhesion and laminates prepared therefrom
US5997954A (en) * 1998-07-15 1999-12-07 Dow Corning Corporation Method of rendering substrates water repellent using hyperbranched polymers containing silicon atoms
EP1506964A1 (en) * 2003-08-15 2005-02-16 Henkel Kommanditgesellschaft auf Aktien Cyclic dithiocarbonates, their preparation and application
EP1506976A1 (en) * 2003-08-15 2005-02-16 Henkel Kommanditgesellschaft auf Aktien Siloxane derivatives of 1,3-oxathiolane-2-thiones, their preparation and use thereof
ES2720191T3 (es) * 2012-09-04 2019-07-18 Covestro Deutschland Ag Isocianatosilanos con estructura tiouretano
EP2805985A1 (de) * 2013-05-22 2014-11-26 Sika Technology AG Hydroxysilan und Silangruppen-haltiges Polymer
US10179885B2 (en) 2014-03-27 2019-01-15 Dow Global Technologies Llc Dispersant suitable for lubricant formulations
JP6296876B2 (ja) * 2014-03-31 2018-03-20 株式会社松風 新規長鎖シランカップリング剤およびそれを含む歯科用組成物
US10030122B2 (en) * 2015-02-09 2018-07-24 Wacker Chemical Corporation Curable compositions
CN107955571A (zh) * 2017-12-11 2018-04-24 浙江工业大学 一种低粘度的硅烷改性聚醚基胶及其制备方法

Also Published As

Publication number Publication date
WO2020094974A1 (fr) 2020-05-14
JP2022506713A (ja) 2022-01-17
CN112969691A (zh) 2021-06-15
EP3877375A1 (fr) 2021-09-15
JP7594526B2 (ja) 2024-12-04
CN112969691B (zh) 2024-08-09
US20210395439A1 (en) 2021-12-23
FR3088325A1 (fr) 2020-05-15

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FR3088325B1 (fr) Derives 1,3-oxathiolane-2-thione et leurs utilisations

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